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Cereal + legume rotation is an integrated system that facilitates soil fertility and sustainable agricultural production. However, research on the management compatibility affecting soil physico-chemical properties yields overall agro-ecosystem sustainability, but profitability is lacking, especially under straw retention and potential reductions in fertilizer application. An 11-year field experiment investigated three treatments: no straw retention + traditional mineral fertilization (TNS), straw retention + traditional mineral fertilization (TS), and straw retention + reduced mineral fertilization (DS). Compared with TNS, TS significantly improved soil physico-chemical properties, including macro-aggregates (R > 0.25 mm), porosity, field water capacity (FWC), soil organic carbon (SOC) storage, total nitrogen storage, microbial biomass carbon (MBC), and microbial biomass nitrogen (MBN) by 17.3%, 3.2%, 13.0%, 5.5%, 3.2%, 15.5%, and 13.8%, respectively. TS also significantly increased total (wheat + soybean) yields (TYs), economic profits, and emergy sustainability index (ESI) by 15.8%, 25.0%, 3.7 times that of TNS, respectively. Surprisingly, compared with TS, DS further significantly improved R > 0.25 mm, porosity, FWC, SOC storage, MBC, MBN, TY, economic profits, and ESI by 11.4%, 1.5%, 6.1%, 3.0%, 10.6%, 7.2%, 5.7%, 11.1%, and 36.5%, respectively. Overall, retaining straw with reduced fertilization enhances soil properties, yields, and emergy sustainability in wheat–soybean rotation systems. [ABSTRACT FROM AUTHOR]

The development of cost-efficient electrocatalysts for oxygen evolution reaction (OER) with high efficiency is crucial to widespread applications of water splitting for hydrogen production. In this work, porous three-dimensional (3D) amorphous NiFe nanoaggregates composed of interconnected nanograins were synthesized by a cyanogel-based wet chemical reduction method using the NiCl2/Na4Fe(CN)6 cyanogel as the precursor and NaBH4 as the reducing agent. The influence of the incorporated Fe amount was carefully studied by slightly changing the feeding molar ratios of the Ni/Fe atoms in the precursors. The intrinsic 3D backbone structure of the cyanogel resulted in crystal nuclei tending to generate along with the backbones, which is key to the formation of NiFe nanoaggregates with a porous 3D interconnected structure. The synthesized NiFe nanoaggregates with a 3D interconnected structure and high porosity, as well as the incorporation of Fe, are in favor of high surface area, more active sites, and abundant oxygen vacancies, leading to superior activity and stability of OER in alkaline electrolytes with a low overpotential of 0.35 V at 10 mA cm−2, a high current density of 24.8 mA cm−2 at 1.65 V, a small Tafel slope of 76.9 mV dec−1, and attractive durability in 1 M KOH solution. [ABSTRACT FROM AUTHOR]

Green manure crops intercropping is an effective agricultural practice to alleviate water and nutrient deficit by improving soil properties in the Loess Plateau of China. However, green manure crops intercropping could cause water and nutrient competition, but the effects of different green manure crops intercropping on soil water and nutrient status are rarely evaluated. Thus, we conducted a field experiment to investigate the responses of soil moisture, nitrogen, and yield to green manure crops intercropping. Three intercropping patterns, apple–ryegrass (AR), apple–spring rape (AS), and apple–alfalfa (AA), were set up with a blank control (CK), which employed clean tillage in the inter-row and row. All treatments had no significant difference on evapotranspiration. At maturity, AR, AS, and AA treatments reduced soil organic matter content by 4.2%, 6.5%, and 18.8%, and total nitrogen content by 0.01%, 1.3%, and 20.3%, relative to CK, respectively. The water competition degree in AR, AS, and AA were 38.4%, 48.8%, and 64.6%, respectively. Ryegrass, spring rape, and alfalfa's nitrogen use efficiency were 19.71%, 29.24%, and 39.42%, respectively. AR and AS treatments increased the apple yield by 11.7% and 5.7%, and water-use efficiency (WUE) by 14.4% and 7.5%, relative to CK, respectively. AA treatment reduced the apple yield by 6.9% and WUE by 6.8%, relative to CK. All treatments had no significant difference on apple quality. Therefore, in normal water years, we suggest adapting the ryegrass–apple tree intercropping pattern for apple production on the Plateau Loess, China. [ABSTRACT FROM AUTHOR]

Despite the powerful potentials of digital twins as regards achieving sustainable operations and supply chain management, there is currently very little research on using digital twins for industrial symbiosis, and even less research investigating user needs. Therefore, it is necessary to conduct sufficient research on the market and user needs before setting the framework of digital twins for industrial symbiosis. We interviewed six companies in the Norwegian wood industry that could potentially share one symbiosis network. Based on the interviews, we analyzed the needs of potential digital twins for industrial symbiosis, aiming to understand the user's point of view on digital twins for industrial symbiosis. The research is expected to provide intellectual support for future digital twins' design from the user perspective. This paper not only promotes the design of digital twins for industrial symbiosis from the user perspective, but also provides an analytical framework for the user perspective analysis before the development of digital twins-based supply chain collaboration in the industrial symbiosis network. [ABSTRACT FROM AUTHOR]

The disaster of loess slope seriously threatened the safety of people and property. Enzyme Induced Calcite Precipitation (EICP) was demonstrated as an environmentally friendly soil improvement method. However, few studies have focused on the improvement effect of EICP on loess slopes. In this study, a series of tests were conducted to investigate the effect of EICP and added either basalt fiber (BF) to the loess or polyvinyl acetate emulsion (PVAC) to the solution on the erosion resistance of loess slopes. The results showed that all of the EICP, EICP-BF, and EICP-PVAC treatments could improve surface strength (SS). The addition of 50 g/L PVAC achieved high SS because the network structure formed by PVAC promoted the affixation of CaCO3. The thickness of the crust layer decreased with the increasing BF content or PVAC concentration. With the increasing number of EICP treatment cycles, the CaCO3 content increased progressively, but the increase rate decreased. For rainfall erosion, the time until erosion occurred was delayed and the stability was improved for loess slopes treated with EICP, EICP-BF, and EICP-PVAC. The high erosion resistance of loess slopes treated with EICP-0.5% BF, EICP-30 g/L PVAC, and EICP-50 g/L PVAC was attributed to the stable spatial structure formed by CaCO3 precipitation and the additional cementation provided by high BF content and PVAC concentration. The addition of 0.5% BF effectively inhibited the development of surface cracks in loess slope after dry–wet cycles. With the increasing number of dry–wet cycles, the accumulative loess loss weight of slopes treated with various methods increased gradually. Among all treatment methods, the number of dry–wet cycles had less effect on EICP-30 g/L PVAC treated loess slopes. This study provided guidance for loess slopes prevention. [ABSTRACT FROM AUTHOR]

It is important to develop cost-efficient electrocatalysts used in the oxygen reduction reaction (ORR) for widespread applications in fuel cells. Palladium (Pd) is a promising catalyst, due to its more abundant reserves and lower price than platinum (Pt), and doping an earth-abundant 3d-transition metal M into Pd to form Pd–M bimetallic alloys may not only further reduce the use of expensive Pd but also promote the electrocatalytic performance of ORR, owing to the synergistic effect between Pd and M. Here we report a cyanogel-derived synthesis of PdFe alloys with porous nanostructure via a simple coinstantaneous reduction reaction by using K2PdIICl4/K4FeII(CN)6 cyanogel as precursor. The synthesized PdFe alloys possess hydrangea-like morphology and porous nanostructure, which are beneficial to the electrochemical performance in ORR. The onset potential of the porous PdFe nanohydrangeas is determined to be 0.988 V, which is much more positive than that of commercial Pt/C catalyst (0.976 V) and Pd black catalyst (0.964 V). Resulting from the unique structural advantages and synergetic effect between bimetals, the synthesized PdFe nanohydrangeas with porous structure have outstanding electrocatalytic activity and stability for ORR, compared with the commercial Pd black and Pt/C. [ABSTRACT FROM AUTHOR]