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Cost-effective bismuth (Bi) boasts a high theoretical capacity and exceptional selectivity towards Cl- ion storage, making it a promising material for desalination batteries (DBs). However, the substantial volume expansion and low conductivity severely hinder the cycling performance of Bi-based DBs. In this study, a carbon-layer-coated Bi nanocomposite (Bi@C) was synthesized by pyrolyzing a metal–organic framework (Bi-MOF) containing Bi using a straightforward method. The results show that the Bi@C synthesized under the condition of annealing at 700 °C for 2 h has the optimum properties. The Bi@C has good multiplication performance, and the desalination capacity is 106.1 mg/g at a high current density of 1000 mA/g. And the material exhibited a high desalination capacity of 141.9 mg/g at a current density of 500 mA/g and retained 66.9% of its capacity after 200 cycles. In addition, the Bi@C can operate at a wide range of NaCl concentrations from 0.05 to 2 mol/L. The desalination mechanism analysis of the Bi@C revealed that the carbon coating provides space for Bi particles to expand in volume, thereby mitigating the issues of electrode material powdering and shedding. Meanwhile, the porous carbon skeleton establishes electron and ion channels to enhance the electrode material's conductivity. This research offers a promising strategy for the application of chloride-storage electrode materials in electrochemical desalination systems. [ABSTRACT FROM AUTHOR]

Challenges are always proposed when pursuing more energy and resource recovery from waste activated sludge via the anaerobic digestion (AD) process. Recently, microbial electrolysis has been integrated with AD and has been proven to enhance sludge conversion and system stability. This study investigated the effect of organic load on fermentation and biogas production in a bioelectrolysis-assisted AD reactor. Four different organic loads of alkaline waste sludge from 6 g/L to 14 g/L were investigated for their effects on the methanogenesis rate, substrate metabolism, electrochemical performance, and contribution. The results showed that the integrated system had a stronger tolerance to organic loads than the traditional anaerobic system. When the sludge concentration reached 14 g/L, the methanogenic rate, total methane yield, and SS removal rate significantly increased, reaching 47.1 mL/d, 96.2 mL/gVSS, and 71.6%, which were 1.27, 2.08, and 1.28 times those of the control, respectively. A high organic load was beneficial to the overall methanogenic rate but prolonged the fermentation period. Under a low organic load, the energy efficiency of the system deteriorated because the power loss increased and the electrochemical contribution rate was less than 50%. This result suggests that the integrated system can work and improve the overall energy yield from a high organic load of wasted sludge digestion. [ABSTRACT FROM AUTHOR]

The interdependency of electric and natural gas systems is becoming stronger. The challenge of how to meet various energy demands in an integrated energy system (IES) with minimal cost has drawn considerable attention. The optimal scheduling of IESs is an ideal method to solve this problem. In this study, a day-ahead optimal scheduling model for IES that included an electrical system, a natural gas system, and an energy hub (EH), was established. The proposed EH contained detailed models of the fuel cell (FC) and power to gas (P2G) system. Considering that the optimal scheduling of an IES is a non-convex complex optimal problem, a piecewise self-adaptive particle swarm optimization (PCAPSO) algorithm based on multistage chaotic mapping was proposed to solve it. The objective was to minimize the operating cost of the IES. Three operation scenarios were designed to analyze the operation characteristics of the system under different coupling conditions. The simulation results showed that the PCAPSO algorithm improved the convergence rate and stability compared to the original PSO. An analysis of the results demonstrated the economics of an IES with the proposed EHs and the advantage of cooperation between the FC and P2G system. [ABSTRACT FROM AUTHOR]

The seed is the pharmaceutical and breeding organ of Cassia obtusifolia, a well-known medical herb containing aurantio-obtusin (a kind of anthraquinone), food, and landscape. In order to understand the molecular mechanism of the biosynthesis of aurantio-obtusin, seed formation and development, and stress response of C. obtusifolia, it is necessary to understand the genomics information. Although previous seed transcriptome of C. obtusifolia has been carried out by short-read next-generation sequencing (NGS) technology, the vast majority of the resulting unigenes did not represent full-length cDNA sequences and supply enough gene expression profile information of the various organs or tissues. In this study, fifteen cDNA libraries, which were constructed from the seed, root, stem, leaf, and flower (three repetitions with each organ) of C. obtusifolia, were sequenced using hybrid approach combining single-molecule real-time (SMRT) and NGS platform. More than 4,315,774 long reads with 9.66 Gb sequencing data and 361,427,021 short reads with 108.13 Gb sequencing data were generated by SMRT and NGS platform, respectively. 67,222 consensus isoforms were clustered from the reads and 81.73% (61,016) of which were longer than 1000 bp. Furthermore, the 67,222 consensus isoforms represented 58,106 nonredundant transcripts, 98.25% (57,092) of which were annotated and 25,573 of which were assigned to specific metabolic pathways by KEGG. CoDXS and CoDXR genes were directly used for functional characterization to validate the accuracy of sequences obtained from transcriptome. A total of 658 seed-specific transcripts indicated their special roles in physiological processes in seed. Analysis of transcripts which were involved in the early stage of anthraquinone biosynthesis suggested that the aurantio-obtusin in C. obtusifolia was mainly generated from isochorismate and Mevalonate/methylerythritol phosphate (MVA/MEP) pathway, and three reactions catalyzed by Menaquinone-specific isochorismate synthase (ICS), 1-deoxy-d-xylulose-5-phosphate synthase (DXS) and isopentenyl diphosphate (IPPS) might be the limited steps. Several seed-specific CYPs, SAM-dependent methyltransferase, and UDP-glycosyltransferase (UDPG) supplied promising candidate genes in the late stage of anthraquinone biosynthesis. In addition, four seed-specific transcriptional factors including three MYB Transcription Factor (MYB) and one MADS-box Transcription Factor (MADS) transcriptional factors) and alternative splicing might be involved with seed formation and development. Meanwhile, most members of Hsp20 genes showed high expression level in seed and flower; seven of which might have chaperon activities under various abiotic stresses. Finally, the expressional patterns of genes with particular interests showed similar trends in both transcriptome assay and qRT-PCR. In conclusion, this is the first full-length transcriptome sequencing reported in Caesalpiniaceae family, and thus providing a more complete insight into aurantio-obtusin biosynthesis, seed formation and development, and stress response as well in C. obtusifolia. [ABSTRACT FROM AUTHOR]