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Electric potential produced in deformed piezoelectric nanostructures is of significance for both fundamental study and practical applications. To reveal the piezoelectric property of ZnO nanohelices, the piezoelectric potential in single-crystal nanohelices was simulated by finite element method calculations. For a nanohelix with a length of 1200 nm, a mean coil radius of 150 nm, five active coils, and a hexagonal coiled wire with a side length 100 nm, a compressing force of 100 nN results in a potential of 1.85 V. This potential is significantly higher than the potential produced in a straight nanowire with the same length and applied force. Maintaining the length and increasing the number of coils or mean coil radius leads to higher piezoelectric potential in the nanohelix. Appling a force along the axial direction produces higher piezoelectric potential than in other directions. Adding lateral forces to an existing axial force can change the piezoelectric potential distribution in the nanohelix, while the maximum piezoelectric potential remains largely unchanged in some cases. This research demonstrates the promising potential of ZnO nanohelices for applications in sensors, micro-electromechanical systems (MEMS) devices, nanorobotics, and energy sciences. [ABSTRACT FROM AUTHOR]

Artificial photosynthesis is the imitation of natural photosynthesis, which promises an efficient way to use solar energy to synthesize organic matters, in which the key step is the coenzyme regeneration (NADH/NADPH). To achieve an efficient regeneration rate, various photocatalysts have been developed, such as g-C3N4 and mesoporous carbon nitride (mpg-C3N4). Generally, efficiency determination of different photocatalysts requires laborious experiments, high consumption of reagents, and a considerable amount of time. Here, based on the one-step artificial photosystem I method, we processed the analytical experiment in a very simple PDMS well (20 µL, a drop) to achieve a rapid screening of photocatalysts. For comparison, we used two types of graphitic carbon nitrides, few-layer g-C3N4 and mpg-C3N4. Compared with the slurry systems, firstly, the regeneration rate of mpg-C3N4 drop-reactor system is 4.3 times and 7.1 times those of the few-layer g-C3N4-slurry system and mpg-C3N4-slurry system, respectively. Secondly, this one-drop method reduces the typical verification time from 90 min to 5 min and lowers the liquid volume from 20 mL to 20 µL. Thirdly, this operation is a pump-free and soft lithography technique-free process. The miniaturization of the photocatalytic reaction in the PDMS well improves the regeneration rates, saves samples, and achieves high-throughput screening of multiple photocatalysts. [ABSTRACT FROM AUTHOR]