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As protective coatings for the thermal parts of aero-engines, AlCoCrFeNi coatings have good application prospects. In this study, atmospheric plasma spraying (APS) was used to prepare AlCoCrFeNi high-entropy coatings (HECs), which were oxidized from 650 °C to 1000 °C. The mechanism of the oxide layer formation and the internal phase transition were systematically investigated. The results show that a mixed oxide scale with a laminated structure was formed at the initial stage of oxidation. The redistribution of elements and phase transition occurred in the HECs' matrix; the BCC/B2 structure transformed to Al-Ni ordered B2 phase and Fe-Cr disordered A2 phase. [ABSTRACT FROM AUTHOR]

MCrAlYHf bond coats are employed in jet and aircraft engines, stationary gas turbines, and power plants, which require strong resistance to oxidation at high temperatures. This study investigated the oxidation behavior of a free-standing CoNiCrAlYHf coating with varying surface roughness. The surface roughness was analyzed using a contact profilometer and SEM. Oxidation tests were conducted in an air furnace at 1050 °C to examine the oxidation kinetics. X-ray diffraction, focused ion beam, scanning electron microscopy, and scanning transmission electron microscopy were employed to characterize the surface oxides. The results show that the sample with Ra = 0.130 µm demonstrates better oxidation resistance compared to Ra = 7.572 µm and other surfaces with higher roughness in this study. Reducing surface roughness led to a decrease in the thickness of oxide scales, while the smoothest surface exhibited increased growth of internal HfO2. The β-phase on the surface with Ra = 130 µm demonstrated faster growth of Al2O3 compared to the γ-phase. An empirical model was suggested to explain the impact of surface roughness on oxidation behavior based on the correlation between the surface roughness level and oxidation rates. [ABSTRACT FROM AUTHOR]

The oxidation resistance of the MCrAlY binding coat is due to the formation of protective Al2O3 oxide scale at high temperature. The oxidation behavior of NiCrAlYHf alloy in 1100 °C air and air-water vapor atmosphere was studied. The effect of water vapor on the microstructure and distribution of reactive elements was discussed. The results showed that the oxide scale in air has a double layer structure composed of columnar and equiaxed crystals, while the oxide scale in water vapor contains fine alumina grains, which provides more channels for the diffusion of reactive elements. In addition, The Cr element in the oxide scale is mainly concentrated in the outer equiaxed crystal zone, and the Hf oxide is mainly concentrated in the columnar crystal boundary. In air-water vapor atmosphere, the Cr element is uniformly distributed in the oxide scale. [ABSTRACT FROM AUTHOR]

Temperature and atmosphere have a significant effect on the oxidation of MCrAlY (M = Ni, Co) bond coating. The initial growth behavior of the NiCrAlHf bond coat alloy was investigated at 1100 °C under different atmospheric conditions and using heating methods. A thick Al2O3 oxide layer and large HfO2 particles were observed, perhaps due to metastable oxide growth at low temperatures when using stepped heating. However, in air and water vapor atmospheres, the oxide scale was thinner and the HfO2 precipitates were smaller in stepped heating than in constant heating. The size and distribution of the HfO2 particles might have induced different microstructures, particularly voids within the oxide scale. [ABSTRACT FROM AUTHOR]