Search

The accurate extraction of urban residential space (URS) is of great significance for recognizing the spatial structure of urban function, understanding the complex urban operating system, and scientific allocation and management of urban resources. The traditional URS identification process is generally conducted through statistical analysis or a manual field survey. Currently, there are also superpixel segmentation and wavelet transform (WT) processes to extract urban spatial information, but these methods have shortcomings in extraction efficiency and accuracy. The superpixel wavelet fusion (SWF) method proposed in this paper is a convenient method to extract URS by integrating multi-source data such as Point of Interest (POI) data, Nighttime Light (NTL) data, LandScan (LDS) data, and High-resolution Image (HRI) data. This method fully considers the distribution law of image information in HRI and imparts the spatial information of URS into the WT so as to obtain the recognition results of URS based on multi-source data fusion under the perception of spatial structure. The steps of this study are as follows: Firstly, the SLIC algorithm is used to segment HRI in the Guangdong–Hong Kong–Macao Greater Bay Area (GBA) urban agglomeration. Then, the discrete cosine wavelet transform (DCWT) is applied to POI–NTL, POI–LDS, and POI–NTL–LDS data sets, and the SWF is carried out based on different superpixel scale perspectives. Finally, the OSTU adaptive threshold algorithm is used to extract URS. The results show that the extraction accuracy of the NLT–POI data set is 81.52%, that of the LDS–POI data set is 77.70%, and that of the NLT–LDS–POI data set is 90.40%. The method proposed in this paper not only improves the accuracy of the extraction of URS, but also has good practical value for the optimal layout of residential space and regional planning of urban agglomerations. [ABSTRACT FROM AUTHOR]

Accurately identifying the expansion characteristics and driving mechanisms at different development stages of urban agglomerations is crucial for their coordinated development. Using the Central Yunnan Urban Agglomeration as a case study, we employ a data fusion approach to fuse nighttime light data with LandScan data and utilize the U-net neural network to systematically analyze the expansion characteristics and driving mechanisms of the urban agglomeration. The results indicate that, from 2008 to 2013, the Central Yunnan Urban Agglomeration was in an initial expansion stage, primarily driven by economic development levels and population size. From 2013 to 2018, the agglomeration entered an accelerated expansion stage, driven mainly by industrial structure transformation and the population agglomeration effect. From 2018 to 2023, the agglomeration experienced a steady expansion stage, with industrial structure upgrading and government support as the primary driving forces. Furthermore, we found that, over time, the influence of economic development levels and population size as driving forces gradually weakened, while the impact of industrial structure and government support significantly increased. Through the fusion of multi-source data and analysis of driving mechanisms at different developmental stages, we comprehensively revealed the development trajectory of the Central Yunnan Urban Agglomeration and provided valuable insights for future urban agglomeration development planning and policymaking. [ABSTRACT FROM AUTHOR]

The Indian meal moth, Plodia interpunctella, poses a significant threat to global agricultural products. Although pheromone-based technologies show promise for P. interpunctella management, limitations such as single-sex targeting necessitate exploring complementary strategies. Vegetable-based oils represent a potential alternative but their efficacy, sex-specificity, and interaction with sex pheromones remain unclear. To address these questions, we first examined the attraction of P. interpunctella female and male adults to 10 commercially available vegetable oils in semi-field conditions. Sesame, olive, and blended oils were the most attractive, capturing significantly more adults compared to other oils. We then evaluated the effectiveness of these three attractive oils and their combinations with P. interpunctella sex pheromones in a grain warehouse. Traps baited with these oils captured significantly more females and males compared to control traps without attractants; however, the addition of sex pheromones did not improve male capture and significantly reduced female capture, suggesting an inhibitory effect. Finally, we demonstrated that female mating status (mated vs. virgin) did not influence the attractiveness of traps baited with these effective oils. Our findings highlight the potential of standalone traps baited with blended, olive, or sesame oil as a practical, economic, and effective management strategy for P. interpunctella in storage facilities. [ABSTRACT FROM AUTHOR]

Simple Summary: The European native spider mite Tetranychus ludeni Zacher (Acari: Tetranychidae) is an invasive species which attacks many economically important crops. Investigations into how different factors affect its dispersal probability and distance help better understand its population management and enable researchers to perform invasion evaluations. Here, we tested the effect of age and density on dispersal probability and distance. We show that older females that are capable of producing more eggs within 24 h were more likely to disperse and moved longer distances than younger ones with fewer eggs. Older females spread most of their eggs out of their natal habitats and over longer distances, which reduced competition and increased offspring fitness. Our results also indicate that females exhibited significantly increased dispersal probability and distance with an increase in population density to avoid crowding. The synchronization of dispersal and reproduction, along with the positive density-dependent dispersal strategy, may facilitate the habitat colonization and invasion speed of T. ludeni. The dispersal strategies of a species can affect its invasion success. Investigations into the dispersal strategies of invasive species in relation to different factors help improve our understanding of invasion mechanisms and provide knowledge for population management and invasion evaluation. Tetranychus ludeni Zacher (Acari: Tetranychidae) is an invasive species which is native to Europe but is now cosmopolitan. Here, we examined the effects of age and density on dispersal in mated females. Our results show that older females that are capable of producing more eggs within 24 h were more likely to disperse and moved longer distances than younger ones with fewer eggs. Older females spread most of their eggs out of their natal habitats and over longer distances, which reduced competition and increased offspring fitness. Females exhibited significantly increased dispersal probability and distances with an increase in population density to avoid crowding. The synchronization of dispersal and reproduction, along with the positive density-dependent dispersal strategy, may facilitate the habitat colonization and invasion speed of T. ludeni. [ABSTRACT FROM AUTHOR]

Land-use conflicts (LUCs) are pivotal in assessing human–land interaction, reflecting the intricate interplay between natural and anthropogenic drivers. However, existing studies often overlook nuanced non-linear responses and critical threshold recognition, focusing solely on linear correlations between isolated factors and LUCs. This study, situated in Xinjiang, China's arid and semiarid region, introduces a novel analytical framework and threshold application model for LUCs. Integrating land-use and socioeconomic data, we quantified LUCs using Fragstats, correlation analysis, and restricted cubic spline (RCS) regression. Exploring non-linear dynamics between LUCs and 14 potential drivers, including natural and anthropogenic factors, we identified critical thresholds. LUC zones were delineated using a four-quadrant method, allowing tailored mitigation strategies. Our findings reveal Xinjiang's distinct LUC spatial pattern, with intense conflicts surrounding mountainous areas and milder conflicts in basin regions, showing marked diminishment from 2000 to 2020. RCS effectively identifies LUC thresholds, indicating persisting severity pre- or post-specific thresholds. Xinjiang's LUCs are categorized into key control areas, urgent regulation zones, elastic development territories, and moderate optimization regions, each with significant regional disparities. Tailored optimization suggestions mitigate linear analysis limitations, providing a fresh perspective on land zoning optimization. This research supports comprehensive land management and planning in Xinjiang, China. [ABSTRACT FROM AUTHOR]

The anomalous Hall effect and spin–orbit torque of TbCo-based multilayer films have been methodically studied in recent years. Many properties of the films can be obtained by the anomalous Hall resistance loops of the samples. We report on the effects of a structure composed of two heavy metals as the buffer layers on the anomalous Hall resistance loops of TbCo-based multilayers at different temperatures. The results showed that the coercivity increases dramatically with decreasing temperature, and the samples without perpendicular magnetic anisotropy at room temperature showed perpendicular magnetic anisotropy at low temperatures. We quantified the spin–orbit torque efficiency and Dzyaloshinskii–Moriya interaction effective field size of the films W/Pt/TbCo/Pt at room temperature by measuring the loop shift of anomalous Hall resistance. The results showed that the study of anomalous Hall resistance loops plays an important role in the study of spintronics, which can not only show the basic properties of the sample, but can also obtain other information about the sample through the shift of the loops. [ABSTRACT FROM AUTHOR]

The tertiary industry has become the main driving force for China's economic development, and the adjustment and optimization of its structure are important prerequisites for achieving high-quality economic development. Existing studies have mostly focused on the spatial layout and influencing factors of the tertiary industry, with insufficient exploration of its internal structure. In this study, the PRD urban agglomeration is selected as the study area. On the basis of classifying the tertiary industry, the Dagum Gini coefficient, kernel density estimation, and local spatial autocorrelation are used to explore the spatial differentiation of various tertiary industries. The influencing factors are analyzed using geographical detectors, and suggestions for future development strategies are proposed. The results show that in terms of regional differentiation, the agglomeration of various tertiary industries in Guangzhou and Shenzhen is the most significant, but there is insufficient spillover to surrounding cities. In terms of development structure, the level of agglomeration of the consumptive tertiary industry is higher, the public tertiary industry tends to be more evenly distributed, and the productive tertiary industry is relatively dispersed. In terms of influencing factors, the interaction between population and employment dominates the spatial differentiation and evolution of the tertiary industry in the PRD urban agglomeration. Therefore, in the future, the tertiary industry in PRD urban agglomeration should promote the optimization of industrial structure and regional coordinated development under the guidance of the government. [ABSTRACT FROM AUTHOR]

Bismuth vanadate (BVO) is regarded as an exceptional photoanode material for photoelectrochemical (PEC) water splitting, but it is restricted by the severe photocorrosion and slow water oxidation kinetics. Herein, a synergistic strategy combined with a Co3(HPO4)2(OH)2 (CoPH) cocatalyst and an Al2O3 (ALO) passivation layer was proposed for enhanced PEC performance. The CoPH/ALO/BVO photoanode exhibits an impressive photocurrent density of 4.9 mA cm−2 at 1.23 VRHE and an applied bias photon-to-current efficiency (ABPE) of 1.47% at 0.76 VRHE. This outstanding PEC performance can be ascribed to the suppressed surface charge recombination, facilitated interfacial charge transfer, and accelerated water oxidation kinetics with the introduction of the CoPH cocatalyst and ALO passivation layer. This work provides a novel and synergistic approach to design an efficient and stable photoanode for PEC applications by combining an oxygen evolution cocatalyst and a passivation layer. [ABSTRACT FROM AUTHOR]

The article "Catalysis in Energy and the Environment: Opportunities and Challenges" discusses the importance of renewable energy sources and the role of catalysis in developing advanced technologies. It presents research papers on the synthesis and mechanisms of photo-/electrocatalysts and their applications in energy conversion and storage. The article aims to contribute to the field of "catalysis for energy and the environment" with its collection of insightful articles. The article "Efficient and Selective Adsorption of Cationic Dye Malachite Green by Kiwi-Peel-Based Biosorbents" explores the use of kiwi-peel-based biosorbents for removing the cationic dye Malachite Green from wastewater. The study suggests that kiwi-peel-based biosorbents have high adsorption capacity and selectivity for the dye, making them a promising solution for environmental applications. However, it is important to note that the opinions and data presented in the article are those of the individual authors and contributors, not of MDPI or the editor. [Extracted from the article]

Simple Summary: We proposed a pragmatic method for quantifying the grazing density (GD) and herding proximities (HP) based on unmanned aerial vehicles. We further tested its feasibility at three typical household pastures on the Qinghai-Tibetan Plateau, China. The proposed method is ideal for studying animal behavior and determining the correlation between the distribution of pastoral livestock and resource usability. Grazing management is one of the most widely practiced land uses globally. Quantifying the spatiotemporal distribution of livestock is critical for effective management of livestock-grassland grazing ecosystem. However, to date, there are few convincing solutions for livestock dynamic monitor and key parameters quantification under actual grazing situations. In this study, we proposed a pragmatic method for quantifying the grazing density (GD) and herding proximities (HP) based on unmanned aerial vehicles (UAVs). We further tested its feasibility at three typical household pastures on the Qinghai-Tibetan Plateau, China. We found that: (1) yak herds grazing followed a rotational grazing pattern spontaneously within the pastures, (2) Dispersion Index of yak herds varied as an M-shaped curve within one day, and it was the lowest in July and August, and (3) the average distance between the yak herd and the campsites in the cold season was significantly shorter than that in the warm season. In this study, we developed a method to characterize the dynamic GD and HP of yak herds precisely and effectively. This method is ideal for studying animal behavior and determining the correlation between the distribution of pastoral livestock and resource usability, delivering critical information for the development of grassland ecosystem and the implementation of sustainable grassland management. [ABSTRACT FROM AUTHOR]

Three-dimensional porous carbon materials with moderate heteroatom-doping have been extensively investigated as promising electrode materials for energy storage. In this study, we fabricated a 3D cross-linked chitosan-dicyandiamide-VOSO4 hydrogel using a polymerization process. After pyrolysis at high temperature, 3D porous VOx/N-doped carbon nanosheet hybrids (3D VNCN) were obtained. The unique 3D porous skeleton, abundant doping elements, and presence of VOx 3D VNCN pyrolyzed at 800 °C (3D VNCN-800) ensured excellent electrochemical performance. The 3D VNCN-800 electrode exhibits a maximum specific capacitance of 408.1 F·g−1 at 1 A·g−1 current density and an admirable cycling stability with 96.8% capacitance retention after 5000 cycles. Moreover, an assembled symmetrical supercapacitor based on the 3D VNCN-800 electrode delivers a maximum energy density of 15.6 Wh·Kg−1 at a power density of 600 W·Kg−1. Our study demonstrates a potential guideline for the fabrication of porous carbon materials with 3D structure and abundant heteroatom-doping. [ABSTRACT FROM AUTHOR]

Ex situ conservation involves the maintenance and reproduction of species in areas outside their natural habitats. Seed banking is a well-established ex situ approach used for plant conservation. Seed banking consists of collecting, drying, and storing seeds to preserve genetic diversity. The main limitation of this technique is that the seed must be desiccation tolerant. Seed storage behaviour can vary among species, and for some species, drying without loss of viability is not possible, meaning storage under conventional seed banking conditions (sub-zero temperatures and low relative humidity) is not possible. Understanding seed storage behaviour is an essential prerequisite for establishing whether conventional seed banking is an option for seed conservation. This study investigated the desiccation tolerance and sensitivity of mature seeds of two native New Zealand species of Pittosporum (P. eugenioides and P. crassifolium) from two geographic locations (Palmerston North and Wellington), with the aim of understanding their seed storage behaviour and thereby improving conservation outcomes. The variables measured were seed moisture content, viability, germination, and desiccation responses. We developed sorption isotherm for both species to support the future development of storage protocols. Our results show that both P. eugenioides and P. crassifolium display non-orthodox behaviour, i.e., are desiccation sensitive and cannot be stored under conventional seed banking conditions, but also suggest that seed desiccation responses vary with the geographical origin of the seeds. This study highlights the importance of exploring seed storage behaviour using different populations to optimize ex situ conservation strategies aimed at preserving the genetic diversity of New Zealand's threatened and endangered species. [ABSTRACT FROM AUTHOR]

Enhancing spatial quality is an important aspect of future studies on the development of traditional villages. From the perspective of spatial vitality, the degree of revitalization and utilization of traditional villages can be visually reflected and thus, corresponding development strategies can be provided. However, existing studies on traditional villages have paid little attention to the relationship between spatial vitality and development. Therefore, this study evaluates the spatial vitality of traditional villages in Yunnan Province based on Sina Weibo sign-in data, analyzes its relationship with spatial distribution characteristics, and finally, proposes development strategies based on different types of traditional villages. The study results show that first, the Sina Weibo sign-in data can well reflect the spatial vitality of traditional villages. Second, there is a significant difference between the spatial vitality of traditional villages and the spatial distribution characteristics, and we summarize the four types of traditional villages based on this difference. Overall, from the perspective of spatial vitality of traditional villages, this study provides differentiated ideas for the protection, spatial enhancement, and development of traditional villages on the one hand, and on the other hand, it also provides feasible references for rural revitalization planning in Yunnan. [ABSTRACT FROM AUTHOR]

The development of low-cost and high-performance bifunctional electrocatalysts for overall water splitting is still challenging. Herein, we employed a facile electrodeposition method to prepare bifunctional cobalt phosphide for overall water splitting. The needle-like cobalt phosphide (Co-P-1) nanoarray is uniformly distributed on nickel foam. Co-P-1 exhibits excellent electrocatalytic activity for hydrogen evolution reaction (HER, 85 mV at 10 mA/cm2, 60 mV/dec) and oxygen evolution reaction (OER, 294 mV at 50 mA/cm2, 60 mV/dec). The cell-voltage of 1.60 V is found to achieve the current density of 10 mA/cm2 for overall water splitting in the two-electrode system, comparable to that of previously reported Pt/C/NF||RuO2/NF. The excellent electrocatalytic performance can be attributed to the needle-like structure with more active sites, accelerated charge transfer and evolved bubbles' release. This work can provide new approach to the development of a bifunctional electrocatalyst for overall water splitting. [ABSTRACT FROM AUTHOR]

Lithium batteries incorporating LiFePO4 (LFP) as the cathode material have gained significant attention in recent research. However, the limited electronic and ionic conductivity of LFP poses challenges to its cycling performance and overall efficiency. In this study, we address these issues by synthesizing a series of LiFePO4/carbon (LFP/C) composites through low-temperature carbonization coating of LFP in the presence of Coke as the carbon source. The resulting lithium batteries utilizing LFP/C as the cathode material exhibited impressive discharge specific capacities of 148.35 mA·h/g and 126.74 mA·h/g at 0.1 C and 1 C rates, respectively. Even after 200 cycles of charging and discharging, the capacities remained remarkably high, with values of 93.74% and 97.05% retention, showcasing excellent cycling stability. Notably, the LFP/C composite displayed exceptional rate capability, and capacity retention of 99.27% after cycling at different multiplication rates. These findings underscore the efficacy of in situ low-temperature carbonization capping of LFP with Coke in significantly improving both the cycling stability and rate capability of lithium batteries. [ABSTRACT FROM AUTHOR]

Although high-quality tourism destinations directly determine the tourism experiences of tourists and the management focuses of tourism management departments, existing studies have paid little attention to the relationship between tourism destinations of differing quality and tourist experiences. This study analyzed the spatiotemporal distribution of tourists and the quality of tourism destinations in Urumqi based on Tencent migration big data and Weibo sign-in big data and ultimately determined whether there are spatial correlations between the two. The results show that there are large differences in quality between different tourist destinations, and although the spatial and temporal distribution of tourists is not strongly correlated with the quality of tourist destinations, we can divide tourist destinations into four categories based on the correlations between the two (e.g., high-quality tourist destinations with a low number of tourists). The results of this study provide tourists with examples of high-quality tourist destinations, thus improving their holiday experiences, and they also provide a basis by which tourism management departments can manage and develop tourist destinations. The results of this study can also be extended to other regions and play a positive role in promoting the development of the tourism industry. [ABSTRACT FROM AUTHOR]

Simple Summary: The apple leaf-curling midge is an invasive pest of apple. The pest can pupate on fruit and contaminate fresh fruit for export, causing biosecurity problems to many uninvaded regions such as Australia, California, China, India, Japan, and Taiwan. To generate critical knowledge for effective pest risk analysis, forecast and control of this pest, we tested the effects of five temperatures and five daylengths on its development and survival and developed a thermal model for the prediction of the number of generations per year under different climate conditions. We show that temperature but not daylength influenced its development and survival. The lower pupation and emergence rates at ≥25 °C may reduce the probability of its population build-up in regions where the average maximum temperature during the summer is over 25 °C. The model developed in this study can accurately predict the number of generations per year and the time of adult emergence in each generation under different thermal locations. The apple leaf-curling midge, Dasineura mali Kieffer (Diptera: Cecidomyiidae), is an invasive pest of apple, and can contaminate fresh fruit for export, causing biosecurity problems. To provide crucial information for its pest risk analysis, forecast, and management, we investigated the effects of temperatures (5, 10, 15, 20 and 25 °C) and daylengths (10, 11, 12, 13, 14 and 15 h) on its development and survival. The midge eggs failed to hatch at 5 °C and larvae could not complete development at 10 °C. Pupation and emergence rates were significantly higher at 20 °C than at 15 °C and 25 °C. Daylength had no effect on these parameters. The low temperature threshold and thermal requirement to complete development from eggs to adults were 3.7 °C and 627 degree-days, respectively. The midge had a significantly lower thermal requirement for the completion of its lifecycle at 20 °C (614.5 degree-days) than at 15 °C (650.1 degree-days) and 25 °C (634.8 degree-days). The thermal model developed in this study provided accurate predictions of the number of D. mali generations and adult emergence time in each generation in different regions of New Zealand. We suggest that the model could be used to predict population dynamics of this pest in other parts of the world. [ABSTRACT FROM AUTHOR]

With the acceleration of industrialization, the removal of refractory organic dyes from water and how to promote its practical application remains a challenge. Herein, we synthesized an FeCo-LDH/LI-NDG composite electrode material by a simple laser-induced technique on polyimide films, which could electrocatalytically activate peroxymonosulfate (PMS) to completely degrade MB in about 6 min. The reaction rate constant (kobs) was 0.461 min−1. It was faster than most of the currently reported electrocatalysts. The reaction system demonstrated good interference resistance and catalytic effectiveness in the pH range of 3 to 9. According to the chemical quenching and electron paramagnetic resonance (EPR) experiments, the non-radical pathway of 1O2 and the radical pathways of SO4·−, ·OH and O2·− were involved in the reaction synergistically, with 1O2 playing the dominant role. 1O2 was produced through the dual pathway of PMS electron loss at the anode and O2·− intermediate transformation at the cathode. The two activation methods of electro-activation and catalytic activation of PMS had synergistic effects to achieve high efficiency in the whole process of production, reaction and recovery, providing new ideas to advance practical applications. [ABSTRACT FROM AUTHOR]

China's urban agglomerations (UAs) are striving to build a new development pattern oriented towards the new era and new stage, and the population distribution is facing new problems of synergy with the layout of labor factor productivity and regional coordinated development. Therefore, this study couples UAs with population distribution, using data from three population censuses and nighttime light data in 2000, 2010, and 2020, to measure the population agglomeration patterns of Chinese UAs using population agglomeration indicators and to explore the influencing factors and spatial stratification heterogeneity characteristics by constructing an econometric model. The results show that: (1) the population agglomeration patterns of Chinese UAs can be classified into four major categories: weakly polycentric, weakly monocentric, strongly monocentric, and strongly polycentric UAs, and China's UAs are in a low-level stage dominated by weakly polycentric UAs at present. (2) In terms of influencing factors, 15 indicators, such as economic development and social conditions, are important factors affecting the population agglomeration patterns of the four UAs, but their effects vary greatly due to specific patterns. (3) For specific agglomeration models, the total passenger volume has always been the strongest positive influencing factor for weakly polycentric UAs; the industry location entropy index, scale of fiscal expenditure, and total passenger volume in municipal districts are relatively strong positive effects to weakly monocentric UAs, the per capita GDP and urbanization rate are relatively strong positive effects to strongly monocentric UAs, and the urbanization rate is always the strongest positive effect to strongly polycentric UAs. The refined analysis of population migration in Chinese UAs in this study enriches the theoretical results related to population migration in Chinese UAs to a certain extent and provides a feasible basis for the development of new development patterns in Chinese UAs and the formulation of regional population policies in the new stage. Meanwhile, this study divided the polycentric attributes of different UAs, which provide a reference for the theoretical development of polycentric spatial structure of UAs. [ABSTRACT FROM AUTHOR]

Traditional graphite anode material typically shows a low theoretical capacity and easy lithium decomposition. Molybdenum disulfide is one of the promising anode materials for advanced lithium-ion batteries, which possess low cost, unique two-dimensional layered structure, and high theoretical capacity. However, the low reversible capacity and the cycling-capacity retention rate induced by its poor conductivity and volume expansion during cycling blocks further application. In this paper, a collaborative control strategy of monodisperse MoS2/graphite composites was utilized and studied in detail. MoS2/graphite nanocomposites with different ratios (MoS2:graphite = 20%:80%, 40%:60%, 60%:40%, and 80%:20%) were prepared by mechanical ball-milling and low-temperature annealing. The graphite sheets were uniformly dispersed between the MoS2 sheets by the ball-milling process, which effectively reduced the agglomeration of MoS2 and simultaneously improved the electrical conductivity of the composite. It was found that the capacity of MoS2/graphite composites kept increasing along with the increasing percentage of MoS2 and possessed the highest initial discharge capacity (832.70 mAh/g) when MoS2:graphite = 80%:20%. This facile strategy is easy to implement, is low-cost, and is cosmically produced, which is suitable for the development and manufacture of advance lithium-ion batteries. [ABSTRACT FROM AUTHOR]

Nighttime light (NTL) is a critical indicator of urban vitality and development. Using NTL as a representation of urban vitality and development, the study explores how different fresh-made beverage shops, namely boba and coffee shops, proxy various facets of urban vitality and development in four megacities in China. Existing studies mostly discuss urban vitality as a broad concept and seldom investigate the diverse urban vitality and development represented by different indicators. This study selects Beijing, Shanghai, Guangzhou, and Shenzhen as case study regions and explores (1) their urban vitality pattern represented by NTL. (2) the heterogeneous spatial distribution of boba and coffee shops; (3) how boba and coffee shops represent urban vitality differently; and (4) how boba and coffee shops portray the economy and population growth aspect of urban development differently. We acquired NTL data from remote sensing images to measure urban vitality and development. Cross-sectionally, the majority of urban vitality and development represented by NTL concentrates in urban centers. The distribution of coffee shops assimilates the spatial pattern of urban vitality represented by NTL while boba shops have a greater spatial extent in metropolitan fringes. Longitudinally, from 2012 to 2020, the global and local bivariate Moran's I analysis between NTL and beverage shops shows that the coffee shops capture urban vitality and development better than boba shops in Beijing, while the pattern is reversed in Guangzhou and Shenzhen. Examining the evolving spatial dynamics between beverage shops' growth and urban development using bivariate Moran's I and Getis–Ord Gi/Mann–Kendall emerging hot spot analysis, we found that the locations with the most intense economic growth have seen the most spatial expansion of coffee shops. In contrast, those with the fastest population growth have seen the greatest spatial development of boba businesses. These results indicate that coffee shops represent the economic aspect of urban vitality while boba shops emphasize the population growth aspects. By examining the dynamic spatio–temporal relationship between small beverage shops and urban vitality and development represented by NTL data, this study broadens the usage of remote sensing data in urban studies and expands on previous research and offers insights for urban planners and geographers to reference when choosing indicators of urban vitality and growth. [ABSTRACT FROM AUTHOR]

Simple Summary: In this study, we tested the pathogenicity of Beauveria bassiana PfBb on the important agricultural pest Spodoptera frugiperda (Lepidoptera: Noctuidae) by determining the relative activities of protective enzymes and detoxifying enzymes in different larval instars. Our results show that the B. bassiana PfBb strain could infect all six larval instars of S. frugiperda, and its virulence to S. frugiperda larvae gradually increased with an increase in spore concentration. Furthermore, the activities of protective enzymes (i.e., catalase, peroxidase, and superoxide dismutase) and detoxifying enzymes (i.e., glutathione S-transferases, carboxylesterase, and cytochrome P450) in S. frugiperda larvae of the first three instars infected with B. bassiana PfBb changed significantly with infection time, but such variations were not obvious in the fifth and sixth instars. These findings laid the foundation for further research on the mechanism by which B. bassiana controls S. frugiperda. Exploring the pathogenicity of a new fungus strain to non-target host pests can provide essential information on a large scale for potential application in pest control. In this study, we tested the pathogenicity of Beauveria bassiana PfBb on the important agricultural pest Spodoptera frugiperda (Lepidoptera: Noctuidae) by determining the relative activities of protective enzymes and detoxifying enzymes in different larval instars. Our results show that the B. bassiana PfBb strain could infect all six larval instars of S. frugiperda, and its virulence to S. frugiperda larvae gradually increased with an increase in spore concentration. Seven days after inoculation, the LC50 of B. bassiana PfBb was 7.7 × 105, 5.5 × 106, 2.2 × 107, 3.1 × 108, 9.6 × 108, and 2.5 × 1011 spores/mL for first to sixth instars of S. frugiperda, respectively, and the LC50 and LC90 of B. bassiana PfBb for each S. frugiperda instar decreased with infection time, indicating a significant dose effect. Furthermore, the virulence of B. bassiana PfBb to S. frugiperda larvae gradually decreased with an increase in larval instar. The activities of protective enzymes (i.e., catalase, peroxidase, and superoxide dismutase) and detoxifying enzymes (i.e., glutathione S-transferases, carboxylesterase, and cytochrome P450) in S. frugiperda larvae of the first three instars infected with B. bassiana PfBb changed significantly with infection time, but such variations were not obvious in the fifth and sixth instars. Additionally, after being infected with B. bassiana PfBb, the activities of protective enzymes and detoxification enzymes in S. frugiperda larvae usually lasted from 12 to 48 h, which was significantly longer than the control. These results indicate that the pathogenicity of B. bassiana PfBb on the non-target host S. frugiperda was significant but depended on the instar stage. Therefore, the findings of this study suggest that B. bassiana PfBb can be used as a bio-insecticide to control young larvae of S. frugiperda in an integrated pest management program. [ABSTRACT FROM AUTHOR]

Metal-based enzyme mimics are considered to be acceptable agents in terms of their biomedical and biological properties; among them, iron oxides (Fe3O4) are treated as basement in fabricating heterogeneous composites through variable valency integrations. In this work, we have established a facile approach for constructing Fe3O4@Ag composite through assembling Fe3O4 and Ag together via polyethyleneimine ethylenediamine (PEI) linkages. The obtained Fe3O4@PEI@Ag structure conveys several hundred nanometers (~150 nm). The absorption peak at 652 nm is utilized for confirming the peroxidase-like activity of Fe3O4@PEI@Ag structure by catalyzing 3,3′,5,5′-tetramethylbenzidine (TMB) in the presence of H2O2. The Michaelis–Menten parameters (Km) of 1.192 mM and 0.302 mM show the higher catalytic activity and strong affinity toward H2O2 and TMB, respectively. The maximum velocity (Vmax) value of 1.299 × 10−7 M∙s−1 and 1.163 × 10−7 M∙s−1 confirm the efficiency of Fe3O4@PEI@Ag structure. The biocompatibility illustrates almost 100% cell viability. Being treated as one simple colorimetric sensor, it shows relative selectivity and sensitivity toward the detection of glucose based on glucose oxidase. By using indocyanine green (ICG) molecule as an additional factor, a remarkable temperature elevation is observed in Fe3O4@PEI@Ag@ICG with increments of 21.6 °C, and the absorption peak is nearby 870 nm. This implies that the multifunctional Fe3O4@PEI@Ag structure could be an alternative substrate for formatting acceptable agents in biomedicine and biotechnology with enzymatic and photothermal properties. [ABSTRACT FROM AUTHOR]

Nighttime light (NTL) data have become increasingly practical and are now widely used in studies on urbanization, energy consumption, population estimation, socio-economic evaluation, etc. Based on NTL data and the basic tourism economy (TE) data from 31 provinces of China in 2019, this paper adopted a geographic concentration index, inconsistency index, spatial agglomeration coupling index, global and Local Moran's index and geographical detector to explore the spatial relationship between NTL and TE. The results of the study were as follows. Firstly, there is a high spatial correlation between NTL and TE. Secondly, the concentration degree, as well as the concentrated distribution area of NTL and TE, are very similar, roughly showing a higher concentration in East and South-Central China. Thirdly, NTL and TE show a type of coordinated development in East and North China, and a TE surpassing NTL in Southwest and South-Central China. The spatial agglomeration coupling index is higher in North China, South-Central China and the coastal regions of East China, and relatively lower in Southwest and Northwest China. Furthermore, in the spatial agglomeration distribution of NTL and TE, there is an obvious high–high and low–low agglomeration. Finally, the geographical detector analysis showed that the driving factor of tourism economy level (TEL) also has a great influence on NTL. The spatial distribution of NTL and TE is integrated to reasonably allocate tourism resources for different areas and promote the sustainable development of NTL and TE among regions. [ABSTRACT FROM AUTHOR]

Identifying and evaluating polycentric urban spatial structure is essential for understanding and optimizing current urban development. In order to accurately identify the urban centers of the Guangdong–Hong Kong–Macao Greater Bay Area (GBA), this study firstly fused nighttime light data, POI data, and population migration data based on wavelet transform, then identified the polycentric spatial structure of the GBA by carrying out cluster and outlier analysis, and evaluated the level of different urban centers byconducting geographical weighted regression analysis. Using data fusion, we identified 4579.81 km² of the urban poly-center area in the GBA, with an identification accuracy of 93.22%. Although the number and spatial extent of the identified urban poly-centers are consistent with the GBA development plan outline, the poly-center level evaluation results are inconsistent with the development plan, which shows there are great differences in actual development levels among different cities in the GBA. By identifying and grading the polycentric spatial structure of the GBA, this study accurately analyzed the current spatial distribution and could provide policy implications for the GBA's future development and planning. [ABSTRACT FROM AUTHOR]

The rapid development of the urban city has led to great changes in the urban spatial structure. Thus, analyses of polycentric urban spatial structures are important for understanding these kinds of structures. In order to accurately evaluate the polycentric spatial structure of urban agglomerations and judge the differences between the actual development situation and overall planning of urban agglomerations, this study proposes a new method to identify the polycentric spatial structure of urban agglomerations in the Pearl River Delta based on the fusion of nighttime light (NTL) data, point of interest (POI) data, and Tencent migration data (TMG). In the first step, the NTL, POI, and TMG data are fused via wavelet transform; in the second step, Anselin local Moran's I (LMI) and geographically weighted regression (GWR) were used to identify the main centers and subcenters, respectively. In the third step, the accuracy of the results of this study was further verified and discussed in the context of overall planning. The results show that the accuracy of urban polycenter identification via LMI and GWR after data fusion was 92.84%, and the Kappa value was 0.8971, which was higher than the results of polycenter identification via the traditional relative threshold. After comparing the identification results with the overall planning, firstly, we see that the fusion of multi-source big data can help to accurately evaluate the polycentric spatial structure within the urban agglomeration. Secondly, the fusion of dynamic data and static data can help identify the polycentric spatial structure of urban space more accurately. Therefore, this study can provide a new design for urban polycentric spatial structures, and further provide a reliable reference for the spatial optimization of urban agglomeration and the formulation of regional spatial development policies. [ABSTRACT FROM AUTHOR]

With the development of society, an increasing number of educational institutions have adopted field environmental education activities rather than classroom education. Field education can not only enhance students' environmental awareness but also enable them to fully understand environmental protection knowledge. Ecological protection areas are important bases for educational institutions to organize students to implement field environmental education. Focusing on Zhuhai City, this study explored spatial relationships between educational institutions and ecological protection zones using Kernel density estimation, the two-step floating catchment area method, and Thiessen polygons. Specific actions included measuring transportation accessibility and dividing the service scopes of ecological protection zones to provide field environmental education for educational institutions. These actions provided a helpful reference for educational institutions to conduct field environmental education activities effectively. The results showed the following: (1) Schools in Zhuhai City were mainly located in subdistricts and presented a spatial layout of "one primary and two secondary." Students were mainly concentrated in villages and towns and presented a spatial layout of "one core and two centers." Ecological protection zones were scattered in the township area; their spatial relationships with educational institutions were scattered. Meanwhile, their spatial relationship with the number of students was relatively concentrated. (2) In terms of the accessibility of educational institutions to ecological protection zones, the educational institutions in the northeast of Xiangzhou District and the middle of Doumen District had higher accessibility, while the educational institutions in the middle and south of Zhuhai City had lower accessibility, and the educational institutions in the middle of Xiangzhou District had the lowest accessibility. (3) Based on accessibility, the service scopes of field environmental education activities in ecological protection zones were divided into 15 blocks. Here, the educational institutions located in Xiangzhou District, the western part of Jinwan District, and western, middle, and eastern parts of Doumen District had relatively strong spatial dispersions with the ecological protection zones within their blocks, while the educational institutions located in the central and eastern parts of Jinwan District and northern and southern parts of Doumen District had relatively weak spatial dispersions with the ecological protection zones within their blocks. [ABSTRACT FROM AUTHOR]

Simple Summary: Animals adjust their resource allocation strategies to maximize their reproductive benefit under dynamic socio-sexual environments. For example, male insect adults increase their testicular investment with the perceived increase of rivals to gain a competitive advantage in fathering offspring. To date, it is not clear whether insect pupae, which do not feed and crawl, can fine-tune their investment in sperm and testis size according to their social-sexual settings. This knowledge is vital to understanding how male insects respond to their surroundings experienced at different life stages. Using a moth which produces both fertile and unfertile sperm, we demonstrated for the first time that after detecting cues from conspecific pupae regardless of sex, male pupae increased production of both types of sperm at the same rate but kept testis size unchanged. Because most morphological traits are formed during the larval stage in insects, testis size may be fixed after pupation, allowing little room for the pupae to adjust testis size with social changes. Like adults, male pupae with fully grown testes have sufficient resources to produce more sperm of both types according to the perceived increase of sperm competition risk. Theoretic and empirical studies show that social surroundings experienced by male insects during their larval or adult stage can influence their testicular investment in diverse ways. Although insect pupae do not feed and crawl, they can communicate using sex-specific and/or non-sex specific cues. Yet, it is unknown, in any insect, whether and how male pupae can fine-tune their resource allocation to sperm production and testis size in response to socio-sexual environments. We investigated this question using a moth, Ephestia kuehniella, which produces fertile eupyrene sperm and unfertile apyrene sperm. We held male pupae individually or in groups with different sex ratios, and dissected adults upon eclosion, measured their testis size, and counted both types of sperm. We demonstrated that after exposure to conspecific pupal cues regardless of sex, male pupae increased production of eupyrenes and apyrenes at the same rate but kept testis size unchanged. We suggest that testis size is fixed after pupation because most morphological traits are formed during the larval stage, allowing little room for pupae to adjust testis size. Like adults, male pupae with fully grown testes have sufficient resources to produce more sperm of both types according to the perceived increase in sperm competition risk. [ABSTRACT FROM AUTHOR]

The accurate delineation of urban agglomeration boundary is conductive to not only the better understanding of the development relationship between cities in urban agglomeration but also to the guidance of regional functions as well as the formulation of regional management policies. At the same time, the fusion of land relations and urban internal relations can greatly improve the accuracy of the delineation of urban agglomeration boundary. Still, for all that, previous studies delineated the boundary only from the perspective of land relations. In this study, firstly, wavelet transform is used to fuse Night-time Light data (NTL), POI (Point of Interest) data and Tencent Migration data, respectively. Then, the image is segmented by multiresolution segmentation to delineate the urban agglomeration boundary of GBA. Finally, the results are verified. The results show that the accuracy of urban agglomeration boundary delineated by NTL data is 85.57%, with the Kappa value as 0.6256, respectively. While, after fusing POI data, the accuracy is 88.97%, with the Kappa value as 0.7011, respectively. What is more, the accuracy of delineating urban agglomeration boundary by continuous fusion of population movement data reaches 93.60%, and that of Kappa value as 0.8155. Therefore, it can be concluded that compared with delineating the boundary of urban agglomeration only based on land relations, the fusion of population movement data of urban agglomerations by wavelet transform strengthens the interconnection between cities in urban agglomeration and contributes to the accurate division of urban agglomeration boundaries. What is more, such accurate delineation not only has important practical value for optimizing the spatial structure of urban agglomerations, but also assists in the formulation of regional management and development planning policies. [ABSTRACT FROM AUTHOR]

Urban built-up areas are not only the embodiment of urban expansion but also the main space carrier of urban activities. Accurate extraction of urban built-up areas is of great practical significance for measuring the urbanization process and judging the urban environment. It is difficult to identify urban built-up areas objectively and accurately with single data. Therefore, to evaluate urban built-up areas more accurately, this study uses the new method of fusing wavelet transforms and images on the basis of utilization of the POI data of March 2019 and the Luojia1-A data from October 2018 to March 2019. to identify urban built-up areas. The identified urban built-up areas are mainly concentrated in the areas with higher urbanization level and night light value, such as the northeast of Dianchi Lake and the eastern bank around the Dianchi Lake. It is shown in the accuracy verification result that the classification accuracy identified by night-light data of urban build-up area accounts for 84.00% of the total area with the F1 score 0.5487 and the Classification accuracy identified by the fusion of night-light data and POI data of urban build-up area accounts for 96.27% of the total area with the F1 score 0.8343. It is indicated that the built-up areas identified after image fusion are significantly improved with more realistic extraction results. In addition, point of interest (POI) data can better account for the deficiency in nighttime light (NTL) data extraction of urban built-up areas in the urban spatial structure, making the extraction results more objective and accurate. The method proposed in this study can extract urban built-up areas more conveniently and accurately, which is of great practical significance for urbanization monitoring and sustainable urban planning and construction. [ABSTRACT FROM AUTHOR]

In order to relieve grazing pressure, drought-tolerant grass species are widely cultivated in arid regions. However, soil N emission is largely neglected while pursuing forage yield. We carried out a randomized block study to investigate whether and how the C3 and C4 grass species differ in soil N emission in a typical salinized field with temperate continental arid climate in the northwest inland regions, China. We quantified soil N2O flux from two C3 (barley and rye) and two C4 grass species [corngrass and sorghum hybrid sudangrass (SHS)] in fields during the growing season (from May to September) by using the static box method, and then determined the relationships between soil N2O fluxes and forage yield and soil properties. Results show that soil available nitrogen, soil temperature, pH, soil organic carbon, and total nitrogen were correlated, but soil water was anti-correlated with soil N2O fluxes. In addition, N2O flux increased significantly faster with soil temperature in C4 than in C3 grass fields. Although the lower total N2O emission fluxes were detected for C3 species, the lower yield-scaled N2O was detected for C4 species. Our study provided insights into the determination of grass species and the understanding of mechanisms regulating N2O fluxes in C3 and C4 species in the continental arid regions. [ABSTRACT FROM AUTHOR]