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Since the first publications related to microstructured optical fibers (MOFs), the development of optical fiber sensors (OFS) based on them has attracted the interest of many research groups because of the market niches that can take advantage of their specific features. Due to their unique structure based on a certain distribution of air holes, MOFs are especially useful for sensing applications: on one hand, the increased coupling of guided modes into the cladding or the holes enhances significantly the interaction with sensing films deposited there; on the other hand, MOF air holes enhance the direct interaction between the light and the analytes that get into in these cavities. Consequently, the sensitivity when detecting liquids, gasses or volatile organic compounds (VOCs) is significantly improved. This paper is focused on the reported sensors that have been developed with MOFs which are applied to detection of gases and VOCs, highlighting the advantages that this type of fiber offers. This work was carried out with the financial support of MINECO (Spain) through TEC2016-79367-C2-2-R (AEI/FEDER, UE) as well as Public University of Navarre PhD grants program. This work was carried out with the financial support of MINECO (Spain) through TEC2016-79367-C2-2-R (AEI/FEDER, UE). more...

Lossy mode resonance based sensors have been extensively studied in recent years. The versatility of the lossy mode resonance phenomenon has led to the development of sensors based on different configurations that make use of a wide range of materials. The coating material is one of the key elements in the performance of a refractometer. This review paper intends to provide a global view of the wide range of coating materials available for the development of lossy mode resonance based refractometers. This research was funded by the Spanish Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER) (TEC2016-78047-R), the Public University of Navarra (PJUPNA26), and the Spanish Ministry of Universities (FPU15/05663). more...

[EN] The research presented was conducted to quantify the effects of butterfly and gate valves located upstream water meters with diameters larger than 50 mm. Errors caused by these valves can have an enormous financial impact taking into consideration that a small percentage of variation in the error of a large meter is typically related to a significant volume of water. The uncertainty on the economic impact that a valve installed upstream of a medium size water meter leads to many water utilities to oversize the meter chambers in order to mitigate the potential negative errors. Most manufacturers approve their meters for a specific flow disturbance sensitivity class according to the standard ISO 4064-1:2018. Under this classification, a correct operation of the meters requires a certain length of straight section of pipe upstream the meter. However, this classification of the meters cannot consider all types of flow perturbances. For this study, two types of valves, butterfly and gate, were tested upstream ten brand-new water meters from six different manufacturers constructed in four different metering technologies: single-jet, Woltmann, electromagnetic and ultrasonic. In each meter unit was tested at five flow rates, from minimum to the overload flow rates. The tests were conducted with valves set in different orientations, closing degrees, and upstream distances from the water meters under study. The research shows that the valves used can produce significant deviations in the measuring errors with respect the errors found for undistorted working conditions., A. would like to thank Fernando Legarda for the original idea and support to install the test bench. Also, would like to thank Cesar Samperio and Iker Bidaurratzaga from Amvisa, Koldo Urkullu and Juan Luis Mozo from Udal Sareak, Unai Lerma and Joaquin Soler from CABB and Francesc Gavara from FACSA for providing the water meters required to carry out this research and their support during the whole process. I.A. and I.B. would like to thank also to the Basque Government research group IT1314-19. more...

Intensity-based optical fiber sensors are one of the most studied sensor approaches thanks to their simplicity and low cost. Nevertheless, their main issue is their lack of robustness since any light source fluctuation, or unexpected optical setup variation is directly transferred to the output signal, which, significantly reduces their reliability. In this work, a simple and robust hydrogen peroxide (H2O2) optical fiber sensor is proposed based on the Localized Surface Plasmon Resonance (LSPR) sensitivity of silver and gold metallic nanoparticles. The precise and robust detection of H2O2 concentrations in the ppm range is very interesting for the scientific community, as it is a pathological precursor in a wide variety of damage mechanisms where its presence can be used to diagnose important diseases such as Parkinson&rsquo, s disease, diabetes, asthma, or even Alzheimer&rsquo, s disease). In this work, the sensing principle is based the oxidation of the silver nanoparticles due the action of the hydrogen peroxide, and consequently the reduction of the efficiency of the plasmonic coupling. At the same time, gold nanoparticles show a high chemical stability, and therefore provide a stable LSPR absorption band. This provides a stable real-time reference that can be extracted from the spectral response of the optical fiber sensor, giving a reliable reading of the hydrogen peroxide concentration. more...

Due to the risks that water contamination implies for human health and environmental protection, monitoring the quality of water is a major concern of the present era. Therefore, in recent years several efforts have been dedicated to the development of fast, sensitive, and selective sensors for the detection of heavy metal ions. In particular, fluorescent sensors have gained in popularity due to their interesting features, such as high specificity, sensitivity, and reversibility. Thus, this review is devoted to the recent advances in fluorescent sensors for the monitoring of these contaminants, and special focus is placed on those devices based on fluorescent aptasensors, quantum dots, and organic dyes. This work was supported by the Spanish State Research Agency (AEI) and the Spanish Ministry of Economy and Competitiveness through the TEC2016-79367-C2-2-R project. Nerea de Acha would also like to acknowledge her pre-doctoral fellowship (reference BES-2014-069692) funded by the Spanish Ministry of Economy and Competitiveness through the TEC2013-43679-R project. more...

The ability to tune the composition of nanostructured thin films is a hot topic for the design of functional coatings with advanced properties for sensing applications. The control of the structure at the nanoscale level enables an improvement of intrinsic properties (optical, chemical or physical) in comparison with the traditional bulk materials. In this sense, among all the known nanofabrication techniques, the layer-by-layer (LbL) nano-assembly method is a flexible, easily-scalable and versatile approach which makes possible precise control of the coating thickness, composition and structure. The development of sensitive nanocoatings has shown an exceptional growth in optical fiber sensing applications due to their self-assembling ability with oppositely charged components in order to obtain a multilayer structure. This nanoassembly technique is a powerful tool for the incorporation of a wide variety of species (polyelectrolytes, metal/metal oxide nanoparticles, hybrid particles, luminescent materials, dyes or biomolecules) in the resultant multilayer structure for the design of high-performance optical fiber sensors. In this work we present a review of applications related to optical fiber sensors based on advanced LbL coatings in two related research areas of great interest for the scientific community, namely chemical sensing (pH, gases and volatile organic compounds detection) as well as biological/biochemical sensing (proteins, immunoglobulins, antibodies or DNA detection). This work was supported by the Spanish State Research Agency (AEI) and European Regional Development Fund (ERDF-FEDER), TEC2016-79367-C2-2-R. more...

Trabajo presentado en la Eurosensors 2017 Conference. París, 3–6 de septiembre de 2017. An optical fiber sensor for ethanol detection in exhaled breath has been developed. It has been fabricated by functionalizing a Long Period Grating with a metal-organic framework, ZIF-8. The sensor’s response was tested by exposure to exhaled breath of a person before and after the ingestion of alcoholic drinks, showing a higher wavelength difference between the resonance bands in the second case. Further work will analyze cross-sensitivity towards temperature, relative humidity and carbon dioxide. The authors would like to acknowledge Spanish Ministry of Economy and Competitiveness for the financial support through TEC2016-78047-R project. more...

Trabajo presentado en la Eurosensors 2017 Conference. París, 3–6 de septiembre de 2017. An optical fibre refractometer has been developed by etching and deposition of a thin film of indium tin oxide (ITO) on a single-mode-multimode-single-mode (SMS) fibre structure. The interference between modes in this structure is sensitive to the refractive index changes of the surrounding medium, achieving sensitivities of up to 7000 nm/RIU in the 1.333–1.338 RIU range. A salinity sensor has been implemented as a practical application of this proposed structure. Fast Fourier transform (FFT) analysis and tracking of an interference dip were used to monitor the interference between modes obtaining sensitivities of 0.99 nm/PSU and 0.025 rad/PSU, respectively. This work was supported in part by the Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER) (TEC2016-78047-R) and by the Government of Navarre through its projects with references: 2016/PI008, 2016/PC025 and 2016/PC026. As well, it was partially supported by the Colombian Administrative Department of Science, Technology and Innovation - Colciencias, through the Program for national doctorates, calling 617 of 2013. more...

Trabajo presentado en la Eurosensors 2017 Conference. París, 3–6 de septiembre de 2017. In this paper, we experimentally compare several core structures of Microstructured Optical Fibers (MOFs) for low-finesse Fabry-Pérot (FP) sensors. These sensors are designed for Volatile Organic Compounds (VOCs) measurements. We deposit Indium Tin Oxide (ITO) thin films by sputtering on the MOFs and different optical phase responses of the FP were measured for saturated atmospheres of ethanol. The sensitivity of the developed sensors is demonstrated to depend on the geometry and the dimensions of the MOF-cores. The sensors show recovery times under 100 s and the baselines are fully recovered after exposure to VOC. This work was supported by the research grant TEC2016-79367-C2-2-R and TEC 2016-76021-C2-1-R (AEI/FEDER, UE) as well as Public University of Navarre program PhD grants. more...

The refractive index of sputtered indium oxide nanocoatings has been altered just by changing the sputtering parameters, such as pressure. These induced changes have been exploited for the generation of a grating on the end facet of an optical fiber towards the development of wavelength-modulated optical fiber humidity sensors. A theoretical analysis has also been performed in order to study the different parameters involved in the fabrication of this optical structure and how they would affect the sensitivity of these devices. Experimental and theoretical results are in good agreement. A sensitivity of 150 pm/%RH was obtained for relative humidity changes from 20% to 60%. This kind of humidity sensors shows a maximum hysteresis of 1.3% relative humidity. This work was supported by the Spanish Economy and Competitiveness Ministry (TEC2016-79367-C2-2-R). Joaquín Ascorbe would like to thank the Public University of Navarra for the pre-doctoral fellowship. more...

A fiber optic sensor for Volatile Organic Compounds (VOCs) detection has been developed and characterized for some organic gasses. The sensor is based on a novel vapochromic material, which is able to change its optical properties in presence of organic vapors in a reversely way. A nano Fabry Perot is constructed onto a cleaved ended optical fiber pigtail by Electrostatic Self Assembly method (ESA), doping this structure with the vapochromic material. Employing a reflection scheme, a change in the intensity modulated reflected signal at 850 nm have been registered. The response of the sensor has been evaluated for five different VOCs, and a deeper study has been made for vapors of three different alcohols. This work was supported by Spanish Ministerio de Ciencia y Tecnología and FEDER Research Grants CICYT-TIC 2003-000909 and CICYT-TEC 2004-05936-C02-01/MIC. more...