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Teacher-endorsed supporting behaviors present themselves as key influencers of student adaptive academic and social functions. The objective of this paper was twofold. First, this study sought to test a model in which student-perceived autonomy support was associated with group cohesion, considering the mediating role of basic psychological needs satisfaction and intrinsic motivation. Second, the current study examined the dimensionality of the model across five Western countries, namely Spain, Portugal, Brazil, Chile, and Mexico. A convenience sample of 3033 college students ( M age = 21.51 ± SD = 3.71) were recruited for the analysis. The results revealed that perceived autonomy support was positively associated with needs satisfaction, being consequently associated with intrinsic motivation and, ultimately, with group cohesion. Additionally, a multigroup analysis revealed that the model was invariant across college students from the different countries. The current results are discussed around the promotion of teacher uses of autonomy-supportive behaviors fostering adaptive outcomes in students regarding positive social relations and that the cultures of Ibero-American countries are equivalent in this process., Competing Interests: The authors declare no conflicts of interest.

Adolescents' academic performance and the way it is related to their subjective wellbeing are issues of great interest across educational systems. The purpose of this study was to ascertain how satisfaction with high school subjects can predict school satisfaction and academic performance in Mexican students. The sample consisted of 457 high school students in the Baja California and Nuevo León states in Mexico (247 boys, 210 girls); their mean age being 14.10 (SD = 0.84). We used a questionnaire featuring a subject satisfaction scale, an intrinsic school satisfaction scale, and one related to academic grades. We used descriptive analyses, correlations, and structural regression models. In terms of results, the high satisfaction and academic performance levels in physical education, Spanish and English are worth highlighting. Geography and history are the most relevant predictors of academic grades, while Spanish predicts school satisfaction and physical education predicts boredom. In conclusion, satisfaction with mathematics, Spanish, and English are strong predictors of satisfaction (SATF), and the latter in turn predicts Mexican high school students' academic performance.

The authors have found two errors in the paper published in Materials [...].

Profiling and parallel computing techniques in a cluster of six embedded systems with multiprocessors are introduced herein to implement a chaotic cryptosystem for digital color images. The proposed encryption method is based on stream encryption using a pseudo-random number generator with high-precision arithmetic and data processing in parallel with collective communication. The profiling and parallel computing techniques allow discovery of the optimal number of processors that are necessary to improve the efficiency of the cryptosystem. That is, the processing speed improves the time for generating chaotic sequences and execution of the encryption algorithm. In addition, the high numerical precision reduces the digital degradation in a chaotic system and increases the security levels of the cryptosystem. The security analysis confirms that the proposed cryptosystem is secure and robust against different attacks that have been widely reported in the literature. Accordingly, we highlight that the proposed encryption method is potentially feasible to be implemented in practical applications, such as modern telecommunication devices employing multiprocessors, e.g., smart phones, tablets, and in any embedded system with multi-core hardware.

Modelling gully erosion in urban areas is challenging due to difficulties with equifinality and parameter identification, which complicates quantification of management impacts on runoff and sediment production. We calibrated a model (AnnAGNPS) of an ephemeral gully network that formed on unpaved roads following a storm event in an urban watershed (0.2 km 2 ) in Tijuana, Mexico. Latin hypercube sampling was used to create 500 parameter ensembles. Modelled sediment load was most sensitive to the Soil Conservation Service (SCS) curve number, tillage depth (Td), and critical shear stress (τ c ). Twenty-one parameter ensembles gave acceptable error (behavioural models), though changes in parameters governing runoff generation (SCS curve number, Manning's n) were compensated by changes in parameters describing soil properties (T D , τ c , resulting in uncertainty in the optimal parameter values. The most suitable parameter combinations or "behavioural models" were used to evaluate uncertainty under management scenarios. Paving the roads increased runoff by 146-227%, increased peak discharge by 178-575%, and decreased sediment load by 90-94% depending on the ensemble. The method can be used in other watersheds to simulate runoff and gully erosion, to quantify the uncertainty of model-estimated impacts of management activities on runoff and erosion, and to suggest critical field measurements to reduce uncertainties in complex urban environments., Competing Interests: Conflicts of Interest: The authors declare no conflict of interest.

A novel peptide, RsXXIVA, was isolated from the venom duct of Conus regularis, a worm-hunting species collected in the Sea of Cortez, México. Its primary structure was determined by mass spectrometry and confirmed by automated Edman degradation. This conotoxin contains 40 amino acids and exhibits a novel arrangement of eight cysteine residues (C-C-C-C-CC-CC). Surprisingly, two loops of the novel peptide are highly identical to the amino acids sequence of ω-MVIIA. The total length and disulfide pairing of both peptides are quite different, although the two most important residues for the described function of ω-MVIIA (Lys2 and Tyr13) are also present in the peptide reported here. Electrophysiological analysis using superior cervical ganglion (SCG) neurons indicates that RsXXIVA inhibits CaV2.2 channel current in a dose-dependent manner with an EC50 of 2.8 μM, whose effect is partially reversed after washing. Furthermore, RsXXIVA was tested in hot-plate assays to measure the potential anti-nociceptive effect to an acute thermal stimulus, showing an analgesic effect in acute thermal pain at 30 and 45 min post-injection. Also, the toxin shows an anti-nociceptive effect in a formalin chronic pain test. However, the low affinity for CaV2.2 suggests that the primary target of the peptide could be different from that of ω-MVIIA.