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This paper develops a technology for manufacturing a biocomposite using post-production wood waste as filler, but also as an alternative material that can substitute traditional composites. Three types of post-production wood waste, i.e., ash wood chips, oak chips and medium-density wood fiberboard (MDF), were used in this study. Three different biocomposites were produced for each of these materials, differing in the content of waste to polymer. The biodegradable and compostable bioplastic Mater-Bi (CF05S) was obtained using the pioneering proprietary technologies of Novamont company using starches, cellulose, vegetable oils and their combinations. Mater-Bi was used as the matrix of the composite, which, due to its chemical composition, allows the production of fully biodegradable composites. The physicochemical properties, such as static tensile, impact, water absorption and hardness, were investigated. The results provide the basis for a detailed analysis of the properties of the biocomposites and made it possible to accurately determine their properties. The results show that the optimal solution is the Mater-Bi biocomposite with 20 wt.% oak filler content, which shows the most favorable adhesion strength and water absorption. The research conducted here is in the context of issues related to sustainability and a circular economy, through waste management, as well as through the production of biodegradable construction products. [ABSTRACT FROM AUTHOR]

The aim of this research was to obtain new polymer composites with a silicone rubber matrix, having favorable mechanical and functional properties. They contained admixtures in the amount of 10% by weight of expanded graphite (EG) or birch bark (BB). Additionally, some composites contained magnetic particles in the form of carbonyl iron in the amount of 20% by weight. The tensile strength, water absorption, frost resistance, surface contact angle, and free surface energy were examined. Microscopic images were taken using the SEM method and the content of some elements in selected microareas was determined using the EDXS method. In the study, a constant magnetic field with magnetic induction B was used, by means of which the properties and structure of polymer composites were modified. Scientific research in the field of polymers is the driving force behind the progress of civilization. Smart materials are able to respond to external stimuli, such as magnetic fields, with significant changes in their properties. The magnetic field affects not only chemical reactions, but also the crystallographic structure and physicochemical properties of the final products. Owing to their unique properties, such materials can be used in the space industry, automotive industry, or electrical engineering. [ABSTRACT FROM AUTHOR]

Aluminum metal matrix composites (Al MMCs) are a class of materials characterized by being light in weight and high hardness. Due to these properties, Al MMCs have various applications in the automobile, aeronautical and marine industries. Ceramic-reinforced Al MMCs in the form of sinters are known for having excellent abrasive properties, which makes them an attractive material in certain fields of technology. The biggest problem in their production process is their low ability to infiltrate ceramics with alloys and consequently the difficulty of filling a ceramic preform. The castability of such composites has not yet been researched in detail. The aim of this study was to create aluminum metal matrix composite castings based on aluminum alloys (AlSi11) reinforced with an Al2O3 sinter preform using a Castability Trials spiral mold, and then to determine the degree of saturation with the liquid metal of the produced ceramic shaped body (Castability Trials spiral). For the selected AlSi11 alloy, the liquidus (Tl) and solidus (Ts) temperatures were determined by performing thermal-derivation analysis during cooling, which is Tl—579.3 °C and Ts—573.9 °C. The resultant pressure necessary for the infiltration process was estimated for the reinforcement capillaries with the following dimensions: 10, 15, 20, 25, 30 and 35 microns. The following values were used to determine the capillary pressure (Pk): surface tension of the alloy—σ = 840 mN/m; the extreme wetting angle of the reinforcement by the metal—θ = 136°. It has been experimentally confirmed that for the vacuum saturation process, the estimated resultant pressure enables saturation of reinforcement with capillaries larger than 25 microns, provided that the alloy temperature does not drop lower than the infiltration temperature. After the experiment, the time and route of the liquid metal flow in the spiral were determined. On the basis of the obtained values, a simulation was developed and initial assumptions such as saturation time, alloy temperature, reinforcement and mold temperature were verified. The energy balance showed that the saturation limit temperature was Tk = 580.7 °C for the reinforcement temperature of 575 °C. In contrast to the above, the assumption that the temperature of the metal after equalizing the temperature of the composite components must be higher than the liquidus temperature (Tliq = 579.3 °C) for the aluminum alloy used must be fulfilled. After the experiment, the time and path of the liquid metal flow in the spiral were determined. Then, on the basis of the obtained values, a simulation was developed, and the initial assumptions (saturation time and temperature) were verified. [ABSTRACT FROM AUTHOR]

Radiation is an example of one of the techniques used for pasteurization and sterilization in various packaging systems. There is a high demand for the evaluation of the possible degradation of new composites, especially based on natural raw materials. The results of experimental research that evaluated the impact of radiation technology on biodegradable and compostable packaging materials up to 40 kGy have been presented. Two commercially available flexible composite films based on aliphatic–aromatic copolyesters (AA) were selected for the study, including one film with chitosan and starch (AA-CH-S) and the other with thermoplastic starch (AA-S). The materials were subjected to the influence of ionizing radiation from 10 to 40 kGy and then tests were carried out to check their usability as packaging material for the food industry. The results showed that the mechanical properties of AA-S films improved due to the radiation-induced cross-linking processes, while in the case of AA-CH-S films, a considerable decrease in the elongation at break was observed. The results also showed a decrease in the WVTR in the case of AA-S and no changes in barrier properties in the case of AA-CH-S. Both materials revealed no changes in the odor analyzed by sensory analysis. In the case of the AA-S films, the higher the radiation dose, the faster the biodegradation rate. In the case of the AA-CH-S film, the radiation did not affect biodegradation. The performed research enables the evaluation of the materials intended for direct contact with food. AA-CH-S was associated with unsatisfactory parameters (exceeding the overall migration limit and revealing color change during storage) while AA-S showed compliance at the level of tests carried out. The study showed that the AA-CH-S composite did not show a synergistic effect due to the presence of chitosan. [ABSTRACT FROM AUTHOR]

The effects of octakis[(3-glycidoxypropyl)dimethylsiloxy]octasilsesquioxane (GPOSS) on the crystallinity, crystal structure, morphology, and mechanical properties of polyoxymethylene (POM) and POM/GPOSS composites were investigated. The POM/GPOSS composites with varying concentrations of GPOSS nanoparticles (0.05-0.25 wt %) were prepared viamelt blending. The structure of POM/GPOSS composites was characterized by differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD), and polarized light microscopy (PLM). The mechanical properties were determined by standardized tensile tests. The morphology and dispersion of GPOSS nanoparticles in the POMmatrix were investigated with scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. It was observed that the dispersion of the GPOSS nanoparticles was uniform. Based on DSC studies, it was found that the melting temperature, lamellar thickness, and the degree of crystallinity of the POM/GPOSS composites increased. The POM/GPOSS composites showed an increased Young's modulus and tensile strength. Finally, compared with the pure POM, the addition of GPOSS reduced the spherulites' size and improved the crystallinity of the POM, which demonstrates that the nucleation effect of GPOSS is favorable for the mechanical properties of POM. [ABSTRACT FROM AUTHOR]

This paper presents the contemporary problems of polymer waste recycling, mainly recycling cables from end-of-life vehicles. The authors developed a new material based on mixed polymer waste (ASR) modified with a ductile polymer, mainly recycled low-density polyethylene (rLDPE), to produce moisture-resistant boards with beneficial mechanical properties. The ASR-based compositions without and with homogenization process—including physical, chemical, and shear-assisted compatibilization—were successfully applied and verified by evaluating final recycled product properties. The results showed that recycled polyethylene (rLDPE) was effective as a modifier increasing tensile modulus and flexural strength compare to an ASR mixture. It was found that the adding 5 wt % of polyethylene-grafted maleic anhydride (PE-g-MAH) as a compatibilizer to the ASR mixture significantly increases the homogenization of the components in the ASR matrix. The optimal solution for management cable waste is the manufacture of ASR composites with homogenization using an internal mixer the adding 20 wt % of rLDPE and 5 wt % of PE-g-MAH to the mixed plastics cable waste. The results obtained demonstrate that the hot-pressing with the pre-blending with rLDPE and compatibilizer of the ASR based waste provides a high gain in mechanical and usage properties, enabling the circular economy of plastics from automotive cables. [ABSTRACT FROM AUTHOR]

The aim of this study was to develop a polyethylene/polyamide (R-PE/R-PA) regranulated product made from post-consumer wastes grafted with polyethylene-graft-maleic anhydride (PE-g-MAH) by reactive extrusion in a twin-screw extruder equipped with an external mixing zone. The compatibility effect of PE-g-MAH used as a modifier in R-PE/R-PA blends was evaluated by means of differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA), while the analysis of the chemical structure of this blend was carried out by Fourier transform infrared spectroscopy (FT-IR). The thermal properties, complex viscosity, and selected usage properties of R-PE/R-PA blends compatibilized with PE-g-MAH, i.e., density and water absorption, were evaluated. The morphology of the blends with and without the compatibilizer was observed by scanning electron microscopy. The R-PE/R-PA/MAH blend shows heterogenic structure, which is a result of the chemical reaction in reactive extrusion between functional groups of PE-g-MAH used as modifier and the end groups of R-PA6. The results show that the R-PE/R-PA blend with increased PE-g-MAH content showed increased hardness, stiffness, and ultimate tensile strength due to the increased degree of crystallinity. The increase in crystallinity is proportional to the improvement of the mechanical properties. Moreover, it is shown that 1 wt.% PE-g-MAH added to the R-PE/R-PA waste blend increases the interfacial interactions and compatibility between R-PE and R-PA, resulting in decreased polyamide particle size. Finally, the results show that it is possible to produce good quality regranulated products with advantageous properties and structure from immiscible polymer waste for industrial applications. [ABSTRACT FROM AUTHOR]

The paper presents the procedure of generating geometrical features on the contours of non-circular pulleys through the selection of materials and technological parameters for easy and efficient production of these parts. Based on the models designed in the computer aided design (CAD) system, several prototype non-standard pulleys were made, which were assessed for functional characteristics and correct operation of non-linear gears. The effect of additive technology on the geometric specification of non-circular pulleys was also assessed. The results showed that thanks to the use of additive methods, the need for costly manufacturing of such wheels with subtractive methods was eliminated. Additionally, it is not necessary to design specialized cutting tools or to use conventional or numerically controlled machine tools to manufacture these wheels. The test results showed that in case of selective laser sintering (SLS) the highest accuracy of mapping (0.01 mm) of geometrical features of the surface was obtained. This result is confirmed by the assessment of the morphology of the surface of the teeth of gears made with this technique, characterized by a uniform structure of the working surface of the wheel while maintaining a high tolerance of the outer profile of gear for selective laser sintering at the level of ±0.03 mm. Research has shown that most of the additive methods used to manufacture non-circular pulleys meet the required geometrical features and due to the short production time of these pulleys, these methods also facilitate quick verification of the designed pulley geometry. [ABSTRACT FROM AUTHOR]

The aim of this study was to investigate and analyze the impact of selected parameters during the tribocharging process of shredded poly(ethylene terephthalate) (PET) and high-density polyethylene (PE-HD) plastics on accumulated electric charge and electrostatic separation effectiveness. The accumulation of electric charge on surfaces of polymer particles as a result of their circular motion forced by the airflow cyclone container was investigated. The impact of the container material, time of tribocharging and the airflow intensity were experimentally examined. A container in which the particles of the considered polymers are electrified with opposite charges was selected. A high ability to accumulate surface charge on small particles of both polymers was demonstrated. The electrified mixed PET/PE-HD was subjected to a separation process. An electrostatic separator designed and constructed by the authors was used for to the separation. In turn, to assess the effectiveness of this separation, a dedicated vision system was used. Based on the result of the carried out tests, it has been assumed that the proposed approach's effectiveness has been demonstrated by means of empirical validation. [ABSTRACT FROM AUTHOR]

The work presented here describes the first results of an effective method of assessing the quality of electrostatic separation of mixtures of polymer materials. The motivation for the research was to find an effective method of mechanical separation of plastic materials and a quick assessment of the effectiveness of the method itself. The proposed method is based on the application of a dedicated vision system developed for needs of research on electrostatic separation. The effectiveness of the elaborated system has been demonstrated by evaluating the quality of the separation of mixtures of poly (methyl methacrylate) (PMMA) and polystyrene (PS). The obtained results show that the developed vision system can be successfully employed in the research on plastic separation, providing a fast and accurate method of assessing the purity and effectiveness of the separation process. [ABSTRACT FROM AUTHOR]

The article presents the potential impact of flat drive and transport belts on people's safety during a fire. The analysis distinguished belts made of classically used fabric–rubber composite materials reinforced with cord and currently used multilayer polymer composites. Moreover, the products' multilayers during the thermal decomposition and combustion can be a source of emissions for unpredictable and toxic substances with different concentrations and compositions. In the evaluation of the compared belts, a testing methodology was used to determine the toxicometric indicators (WLC50SM) on the basis of which it was possible to determine the toxicity of thermal decomposition and combustion products in agreement with the standards in force in several countries of the EU and Russia. The analysis was carried out on the basis of the registration of emissions of chemical compounds during the thermal decomposition and combustion of polymer materials at three different temperatures. Moreover, the degradation kinetics of the polymeric belts by using the thermogravimetric (TGA) technique was evaluated. Test results have shown that products of thermal decomposition resulting from the neoprene (NE22), leder leder (LL2), thermoplastic connection (TC), and extra high top cower (XH) belts can be characterized as moderately toxic or toxic. Their toxicity significantly increases with the increasing temperature of thermal decomposition or combustion, especially above 450 °C. The results showed that the belts made of several layers of polyamide can be considered the least toxic in fire conditions. The TGA results showed that NBR/PA/PA/NBR belt made with two layers of polyamide and the acrylonitrile–butadiene rubber has the highest thermal stability in comparison to other belts. [ABSTRACT FROM AUTHOR]

This paper presented a new approach to decision making support of defects assessment in metal matrix composites (MMC). It is a continuation of the authors' papers in terms of a uniform method of casting defects assessment. The idea of this paper was to design an open-access application (follow-up system called Open Atlas of Casting Defects (OACD)) in the area of industry and science. This a new solution makes it possible to quickly identify defect types considering the new classification of casting defects. This classification complements a classical approach by adding a casting defect group called structure defects, which is especially important for metal matrix composites. In the paper, an application structure, and the possibility of its use in casting defects assessment were introduced. [ABSTRACT FROM AUTHOR]

In this paper, the influence of bentonite (BNT) on rheological properties, linear shrinkage, hardness, and structure of polyethylene wax (PE-wax) used in the lost-wax casting process are studied. Experiments were conducted with PE-wax with different contents of bentonite (from 0.1 to 5 wt.%). The structural changes of modified polyethylene wax were evaluated using differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The addition of bentonite in a concentration range between 0 and 0.8 wt.% into PE-wax caused a decrease of the linear shrinkage and the hardness of PE-wax/BNT blends. Modified polyethylene wax containing greater than 1 wt.% of the filler showed an increase in viscosity. The DSC-based investigations confirmed good miscibility and a uniform structure of PE-wax with BNT. Moreover, an increase in melting temperature onset and its enthalpy observed for filler PE-wax material showed an influence of bentonite on the crystalline structure of the polymeric matrix. SEM observations of the fractured surfaces confirmed the homogeneous structure of blends with contents up to 0.8 wt.% BNT. In the case of higher filler concentrations, the presence of more numerous and large clusters of filler in the polymer matrix was observed due to the increase in the viscosity of the PE-wax/BNT melt composition during mixing. The PE-wax blend with 0.4 wt.% BNT gives better results of reduced linear shrinkage and lower hardness than unmodified material. Lastly, a new developed material (PE-wax/0.4 BNT) was subjected to technological tests, consisting of the preparation of the mold and manufacture of a high-quality aluminum cast, using the lost-wax method. [ABSTRACT FROM AUTHOR]

This article proposes thermography as a non-contact diagnostic tool for assessing drive reliability. The application of this technique during the operation of the belt transmission with a heat-welded thermoplastic polyurethane V-belt was presented. The V-belt temperature changes depending on the braking torque load at different values of the rotational speed of the active pulley, which were adopted as diagnostic characteristics. In this paper, the surface morphology of the polyurethane (PU) belts was assessed on the basis of microscopic and hardness tests. A surface roughness tester was used to evaluate the surface wear. The surface morphology and topography of the materials was determined by scanning electron microscopy (SEM) and optical microscopy. It was found that the most favorable operating conditions occurred when the temperature values of active and passive connectors were similar and the temperature difference between them was small. The mechanical and structure results indicate that the wear of the PU belt was slight, which provided stability and operational reliability for V-belt transmission. The microscopic images lacked clear traces of cracks and scratches on the surface, which was confirmed by the SEM observations. [ABSTRACT FROM AUTHOR]