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Raman spectroscopy plays a pivotal role in spectroscopic investigations. The small Raman scattering cross-section of numerous analytes, however, requires enhancement of the signal through specific structuring of the electromagnetic and morphological properties of the underlying surface. This enhancement technique is known as surface-enhanced Raman spectroscopy (SERS). Despite the existence of various proposed alternatives, the approach involving Fabry–Pérot cavities, which constitutes a straightforward method to enhance the electromagnetic field around the analyte, has not been extensively utilized. This is because, for the analyte to experience the maximum electric field, it needs to be embedded within the cavity. Consequently, the top mirror of the cavity will eventually shield it from the external laser source. Recently, an open-cavity configuration has been demonstrated to exhibit properties similar to the classic Fabry–Pérot configuration, with the added advantage of maintaining direct accessibility for the laser source. This paper showcases how such a simple yet innovative configuration can be effectively utilized to achieve remarkable Raman enhancement. The simple structure, coupled with its inexpensive nature and versatility in material selection and scalability, makes it an ideal choice for various analytes and integration into diverse Raman apparatus setups. [ABSTRACT FROM AUTHOR]

Dipole–Dipole interactions (DDI) constitute an effective mechanism by which two physical entities can interact with each other. DDI processes can occur in a resonance framework if the energies of the two dipoles are very close. In this case, an energy transfer can occur without the need to emit a photon, taking the name of Förster Resonance Energy Transfer (FRET). Given their large dependence on the distance and orientation between the two dipoles, as well as on the electromagnetic properties of the surrounding environment, DDIs are exceptional for sensing applications. There are two main ways to carry out FRET-based sensing: (i) enhancing or (ii) inhibiting it. Interaction with resonant environments such as plasmonic, optical cavities, and/or metamaterials promotes the former while acting on the distance between the FRET molecules favors the latter. In this review, we browse both the two ways, pointing the spotlight to the intrinsic interdisciplinarity these two sensing routes imply. We showcase FRET-based sensing mechanisms in a variety of contexts, from pH sensors to molecular structure measurements on a nano-metrical scale, with a particular accent on the central and still mostly overlooked role played between a nano-photonically structured environment and photoluminescent molecules. [ABSTRACT FROM AUTHOR]

Hydrogen (H2) sensing is crucial for modern energy storage technology, which looks to hydrogen as the most promising alternative to fossil fuels. In this respect, magnesium (Mg) offers unique possibilities, since magnesium and hydrogen easily undergo a reversible hydrogenation reaction where Mg reversibly converts into MgH2. From an optical point of view, this process produces an abrupt refractive index change, which can be exploited for sensing applications. To maximize this opportunity, we envision an architecture composed of two Ag/ITO/Mg metal/dielectric resonators facing each other and displaced by 200 nm of vacuum. This structure forms a so-called Epsilon-Near-Zero (ENZ) multi-cavity resonator, in which the two internal Mg layers, used as tunneling coupling metals, are accessible to environmental agents. We demonstrate that the hydrogenation of the two Mg layers leads to substantial changes in the strong coupling between the cavities composing the entire resonator, with a consequent abrupt modification of the spectral response, thus enabling the sensing mechanism. One of the main advantages of the proposed system with respect to previous research is that the proposed multilayered architecture avoids the need for lithographic processes. This feature makes the proposed architecture inexpensive and wafer-to-chip scalable, considering that each kind of substrate from common glass to silicon can be used. Therefore, our sensing architecture offers great promise for applications in embedded H2 sensors. [ABSTRACT FROM AUTHOR]

A bio-photonic cavity quantum electrodynamic (C-QED) framework could be imagined as a system in which both the "cavity" and the "atom" participating in the light-matter interaction scenario are bio-inspired. Can a cavity be made of a bio-polymer? If so, how should such a cavity appear and what are the best polymers to fabricate it? Can a bioluminescent material stand the comparison with new-fashion semiconductors? In this review we answer these fundamental questions to pave the way toward an eco-friendly paradigm, in which the ever-increasing demand for more performing quantum photonics technologies meets the ever-increasing yet silent demand of our planet to reduce our environmental footprint. [ABSTRACT FROM AUTHOR]