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The geotechnical properties of clay soil and its mixtures with different proportions (0.75%, 0.85%, 1%, and 1.15%) of Agar Gum biopolymer and Ferrochromium Slag (0.25%, 0.50%, 0.75%, and 1%), having various curing times and freeze-thaw cycles, were studied through a series of soil mechanical tests to investigate possibilities to improve its undesired/problematic plasticity, compaction, and shear strength characteristics. The results revealed that treatment with an optimal ratio of 1% Agar Gum and 1% Ferrochromium Slag alone, as well as together with, improved the geotechnical properties of the clay soil considerably. Both the unconfined and shear strength properties, along with the cohesion and internal friction angle, increased as much as 47 to 173%, depending on the curing time. The higher the curing time, the higher the shear strength, cohesion, and internal friction angle are up to 21 days. Deteriorating the soil structure and/or fabric, freeze-thaw cycles, however, seem to have an adverse effect on the strength. The higher the freeze-thaw cycle, the lower the shear strength, cohesion, and internal friction angle. Also, some improvements in the plasticity and compaction properties were determined, and environmental concerns regarding Ferrochromium Slag usage have been addressed. [ABSTRACT FROM AUTHOR]

Construction of earth fill dams offers a cost-effective solution for various purposes. However, their susceptibility to internal soil erosion, known as piping, poses a significant risk of structural failure and resultant loss of life and property. Soil stabilization emerges as a practical technique to fortify these dams against such threats. This study investigated the impact of lime on the internal erosion properties of clay soils, focusing on CH and ML soil types. Specimens of different lime content were prepared and remolded at 95% relative compaction and optimum moisture content. Hole Erosion tests at varying lime concentrations and curing durations were adapted to conduct the investigation. This investigation aims to optimize lime content and curing time for cohesive soil stabilization against internal erosion. Findings revealed that 2% and 5% of quicklime, by dry weight of the soil, effectively stabilized CH and ML soils, respectively, against internal erosion, with a two-day curing period proving optimal. Furthermore, the addition of lime significantly enhanced erosion rate index and critical shear strength in clay soil, underscoring its efficacy in soil stabilization efforts. [ABSTRACT FROM AUTHOR]

In Mediterranean countries characterized by increasingly extended hot and dry periods, olive trees are often conventionally practiced in low fertility and rainfed soils. This study investigated over a 15-month period how conventional tillage, combined with or without incorporated solid digestate, and no tillage affected selected soil properties, photosynthetic activity and productivity of mature olive trees growing in highly clayey acid soil with an unbalanced nutrient content and Mn excess. Neither in soil nor in drupes were Mn, Fe, Cu and Al contents affected by the managements. However, in soil, exchangeable Mn that was always larger than 200 mg kg−1 threshold and unbalanced Ca, Mg, and K contents were evidenced in all treatments. Non-tilled soil showed the highest (p < 0.05) stomatal conductance and photosynthetic rate, and the highest (p < 0.05) fruits and oil yields. Instead, conventional tillage negatively (p < 0.05) affected plant physiology and productivity, likely due to the tilled increase in aeration, enhancing soil water loss and organic C mineralization. Conversely, digestate addition increased TOC, TN and EC. Stomatal conductance, the photosynthetic rate and plant yield significantly recovered (albeit not to no-tillage values) in tillage combined with incorporated digestate, suggesting that digestate-derived organic matter created soil conditions less constraining to plant growth and productivity than the conventional tillage did. Dealing with soil properties and climatic conditions is the key for adopting the best management practice for preserving plant productivity and soil fertility. [ABSTRACT FROM AUTHOR]

The use of organic fertilizers to replace chemically synthesized fertilizers has assumed an important role in managing plant nutrition and soil fertility. The various organic matrices currently available as organic byproducts and digestates are relatively abundant and have shown promising effects in terms of plant-available nutrients. However, like mineral fertilizers, organic fertilizers must be carefully managed to avoid negative effects on the environment, especially when they are repeatedly applied over time. The aim of the present study was to assess the effect of the single (DIG) and repeated application (DIGP) of solid anaerobic digestates compared to an unamended control (CTR) on the denitrifying enzymatic activity (DEA), which is responsible for nitrous oxide emissions into the atmosphere, and some related soil properties, such as total soluble nitrogen (TSN), nitrate (NO3−-N), extractable carbon (Cextr), microbial biomass carbon (MBC), and basal respiration (Rbas), for a period of ~3 months after application. The application of solid anaerobic digestates progressively boosts N and C concentrations in the soil, with the degree of enhancement directly correlated with the frequency of application over the sampling period. Depending on the textural properties of soils, there was a notable rise in denitrification enzyme activity (DEA), particularly during the DIGP treatment, suggesting that clay soils are highly susceptible to denitrification under suitable conditions. The results of this study recommend the careful management of soils subjected to repeated digestate amendment to prevent the occurrence of conditions conducive to denitrification and the promotion of N2O emissions. [ABSTRACT FROM AUTHOR]

The aim of this study was to propose a new approach to determine the liquid limit and plastic limit of clay soils by considering electrical conductivity (EC) measurements. The proposed method included incorporating a new parameter, F, which is the ratio of the volumetric water contents of diffuse double layer (DDL) water and free water. In addition, the EC parameter, σ, was considered as the ratio of electrical surface conductivity and electrical conductivity of water. The changes in the thickness of DDL (χ) were also assessed to obtain corresponding equations to establish a connection with clay mineralogy, water content, and specific gravity in the final prediction. Three-dimensional surface analyses were conducted to find a correlation among F, σ, and χ to identify an appropriate method to predict liquid limit and plastic limit. The study was conducted with 39 different types of samples, and the outcomes from the EC approach were validated against the conventional methods. Overall, the coefficient of determination, R2 = 0.90, and Lin's concordance correlation coefficient, (LCCC) = 0.91, were obtained for liquid limit prediction, whereas R2 = 0.64 and LCCC = 0.80 were obtained for plastic limit determination. [ABSTRACT FROM AUTHOR]

Natural source zone depletion (NSZD) is the main process of LNAPL (Light Non-Aqueous Phase Liquid) removal under natural conditions. The NSZD rates assessed ranged from 0.55 to 11.55 kg·m−2·a−1 (kilograms per square meter per year) in previous studies. However, most of these data were obtained from sandy sites, with few clayey sites. To gain knowledge of NSZD in clayey soil sites, the study assessed the NSZD of a petroleum hydrocarbon-contaminated clayey soil site in China, combining the concentration gradient method with metagenomic sequencing technology. The results show that the abundance of methane-producing key enzyme mcrA gene in the source zone was more abundant than in background areas, which suggests that there was methanogenesis, the key process of NSZD. The concentration gradients of oxygen and carbon dioxide existed only in shallow soil (<0.7 m), which suggests that there was a thin methane oxidation zone in the shallow zone. The calculated NSZD rates range from 0.23 to 1.15 kg·m−2·a−1, which fall within the moderate range compared to previous NSZD sites. This study expands the knowledge of NSZD in clayey soil and enriches the attenuation rate data for contaminated sites, which is of significant importance in managing petroleum contaminants. [ABSTRACT FROM AUTHOR]

Searching for alternative material options to reduce the extraction of natural resources is essential for promoting a more sustainable world. This is especially relevant in construction and infrastructure projects, where significant volumes of materials are used. This paper aims to introduce three alternative materials, crushed ground glass (GG), recycled gypsum (GY) and crushed lime waste (CLW), byproducts of construction industry geomaterials, to enhance the mechanical properties of clay soil in Cartagena de Indias, Colombia. These materials show promise as cementitious and frictional agents, combined with soil and cement. Rigorous testing, including tests on unconfined compressive strength (qu) and initial stiffness (Go) and with a scanning electron microscope (SEM), reveals a correlation between strength, stiffness and the novel porosity/binder index (η/Civ) and provides mixed design equations for the novel geomaterials. Micro-level analyses show the formation of hydrated calcium silicates and complex interactions among the waste materials, cement and clay. These new geomaterials offer an eco-friendly alternative to traditional cementation, contributing to geotechnical solutions in vulnerable tropical regions. [ABSTRACT FROM AUTHOR]

The timing of nitrogen fertilizer application in vineyards can determine the amount of nitrogen (N) absorbed, distributed, and accumulated in grapevine organs. The study aimed to evaluate the annual contribution of N from urea, applied at different times in Cabernet Sauvignon, grown in sandy and clayey soil in a subtropical climate. The sandy soil received 21.42 kg N ha−1 and the clayey soil 30 kg N ha−1, both enriched with 3% excess 15N atoms, applied at different times. The N derived from the fertilizer in grapevines, at all times of N application, and in sandy and clayey soil did not exceed 8%, with the highest values being observed in annual organs, especially in the leaves. The application of N marked at the phenological stages of IBB (50% at beginning of budbreak + 50% at full budbreak) enabled greater absorption of N derived from the fertilizer by the vines grown in both sandy and loamy soil. The N present in the annual organs (leaves, berries, stalks, and shoots) and in the perennial organs (stems and canes) of Cabernet Sauvignon grown in sandy and clayey soil was derived in greater percentages from the soil. [ABSTRACT FROM AUTHOR]

Soil salinization affects more than 25% of land globally. Subsurface pipe drainage is known for its effectiveness in improving saline–alkali land. The red clay layer (RCL) hinders soil improvement in the Hetao Irrigation District of Inner Mongolia, China. The soil water and salt migration rules at different buried depths and RCL were studied based on the field subsurface pipe drainage test and simulation using the DRAINMOD-S model (Version 6.1). The following implications can be drawn from the results: (1) Although the RCL affected the accuracy of the model, the calibrated statistical results met the application requirements, and the DRAINMOD-S model can be used to analyze subsurface pipe drainage under different distribution conditions of the RCL. (2) The RCL can reduce the drainage efficiency of the subsurface pipe, specifically when the distribution is shallow. (3) The soil desalting rate increased with an increase in the buried depth of the subsurface pipe. The desalination effect of shallow soil was better than that of deep soil. The RCL reduced the drainage and salt removal efficiency of the subsurface pipe. Burying the subsurface pipe as far above the RCL as possible should be considered. Thus, it is feasible to apply the DRAINMOD-S model to relevant studies. [ABSTRACT FROM AUTHOR]

This paper aims to improve the strength of soft clay soil using thermal treatment through a laboratory study that simulates the field application. The laboratory work consisted of preparing a soft clay (Cu = 14 kPa) inside a metal box (92.5 × 92.5 × 92.5) cm3. Boreholes of diameter 43 mm, with different lengths, spacing, and arrangements, were made inside the soil to work as a guide for heating pipes which connected to a controlled heating system. A novel heating system, using gas as a heat source, was developed and manufactured. After the end of the treatment periods, a load was applied until failure on a (20 × 20) cm2 square footing. Various parameter spacings (3, 4, and 5 times the outer diameter of the borehole), depths (1, 1.5, 2, and 2.5 times the width of the model footing), arrangements (square, circular, and triangular), and heating periods (2, 4, 6, 8, and 10 h) were investigated. The results showed the strength and behavior of the soil when subjected to the heated boreholes at different spacings, depths, and heating times, which were determined to be three times the outer diameter of the borehole, two times the width of the square footing, and eight hours, respectively, while the effect of the arrangement of the heated borehole casings was small. Also, a cone penetration probe (CPT) conducted on the heated soil showed that the unconsolidated shear strength (Cu) increased from 14 to 360 kPa and then decreased to 140 kPa (as an average with depth). In contrast, the average angle of internal friction (Ø) increased from 0 to 52 degrees and decreased to 16 degrees (as an average with depth) from the center of the heating model to the furthest point affected by heating. The EDS formula showed that components such as silicon, aluminum, and iron decreased at 300 °C and increased at 400 °C in the treated soils. The calcium content increased at 200 °C and then decreased sharply at 400 °C. The carbon percentage increased at 300 °C and decreased at 400 °C. The elemental proportions showed little change or remained stable at temperatures between 400 °C and 600 °C. [ABSTRACT FROM AUTHOR]

Tropical pasture legumes such as Desmanthus are expected to improve pasture productivity in the extensive grazing systems of Northern Australia. However, the soils in these areas are often hostile (e.g., hard-setting and nutrient-deficient), which reduces legume emergence and establishment. Furthermore, these soils are often not ameliorated with amendments such as gypsum or starter fertilisers before planting. A pot trial was conducted to investigate differences in the emergence and early growth of four Desmanthus species. The legumes were grown in three alkaline clay soils that were unamended or amended with either gypsum (1 t CaSO4.2H2O ha−1 equivalent), a starter MAP fertiliser (12 kg P ha−1 equivalent), or both gypsum and the starter fertiliser. Seedling emergence was recorded daily and shoot yield was determined after six weeks' growth. Final seedling emergence (as a percentage of viable seeds) varied among the Desmanthus species (c.f. D. leptophyllus = 63%, D. pernambucanus = 68%, D. bicornutus = 85%, and D. virgatus = 86%). On average, across the treatments, gypsum increased seedling emergence by 15%, whereas the starter fertiliser had no effect. The shoot yields and shoot phosphorus content of the Desmanthus species generally increased in response to the starter fertiliser. The collective results demonstrated that there were differences in emergence and early growth among the four Desmanthus species, which indicates that Desmanthus cultivar selection may be important in the relatively hostile soils of Northern Australia. Gypsum was an effective amendment for seedling emergence, whereas the starter fertiliser was an effective amendment to increase legume productivity. [ABSTRACT FROM AUTHOR]

Evaluation of soil sustainability should take into account chemical and mineralogical changes due to cultivation. Potassium (K) application is a key farming practice that may potentially affect phyllosilicate composition and soil properties. Irrigation is another agent that affects soil composition. This study aims to evaluate the imprints of cultivation on the chemical and mineralogical compositions of lowland soils under semi-arid and Mediterranean climate regimes and to assess them with the natural pedogenesis. The sites examined include two permanent plot experiments with crop rotation, and three single-plant plots. Cultivated, control, and fallow soils were analyzed for their chemical and mineralogical composition. The X-ray diffraction patterns of the clay fraction were decomposed to achieve quantitative detection of changes among the illite–smectite (IS) phases and in kaolinite amounts. In loamy and clayey soils dominated by IS phases, cultivation caused minor changes and diverse behavior of the IS phases. Yet, the K balance was negative under high fertilization levels and higher plant mass production. Fertilization enhanced the natural process of transforming IS into kaolinite and illite in the sandy soil, leading to a positive K balance. This study emphasizes the importance of IS minerals as a dynamic K pool that responds to plant needs. [ABSTRACT FROM AUTHOR]

The current techniques utilized for estimating seasonal fluctuations in earthing system resistance, including artificial neural networks (ANNs) and correlation/correction factors, rely on resistance records, soil resistivity measurements, and meteorological data collected across broad areas. However, they frequently fail to consider the impact of soil conditions and properties at the actual earthing location. As a solution, this research introduces a new method that models atmospheric conditions as soil suction and incorporates hydraulic soil properties (soil water retention characteristics and hydraulic conductivity) to estimate the seasonal changes in earthing resistance and performance. To illustrate this approach, this study constructs geometric models of vertical earthing rods for three homogeneous soil textures (clayey, silty, and sandy) utilizing COMSOL Multiphysics software. By coupling the differential equations governing electric current and water flow using Archie's formula and solving numerically with the finite element method (FEM) for various soil suctions, this research reveals that soil water retention and resistivity variations are notably influenced by soil texture. Sandy soil displays higher variability, silt soil demonstrates moderate changes, while clayey soil exhibits lower fluctuation. By linking soil resistivity changes to soil suction and hydraulic properties, this innovative method predicts seasonal trends in earthing resistance and performance. [ABSTRACT FROM AUTHOR]

The absence of calcium decreases the production of peanuts compared to any other element. To investigate the influence of calcium (Ca) applications on the production and seed quality of four diverse peanut cultivars from different regions—USA (NC-7), Egypt (Giza-6) and Nigeria (Samnut-23 and Samnut-24)—under clay soil conditions, two experiments were carried out at the Agricultural Experimental and Research Station, Cairo University, Egypt, during the two seasons of 2016 and 2017. The experimental design was a randomized complete block in a spilt-plot arrangement with three replications. The main plots were allocated to four peanut cultivars (Giza-6, Samnut-23, Samnut-24 and NC-7), and the sub-plots were devoted to calcium applications (soil application in the form of calcium sulfate dihydrate, foliar application in the form of calcium oxide and the control treatment of distilled water). Results indicated that all four peanut cultivars responded differently to the application of calcium fertilizers. The calcium application significantly enhanced peanut growth, yield components, biological, pod, seed, oil yields, seed oil, free fatty acids and seed calcium percentages in different cultivars. Soil calcium application significantly improved peanut production compared to foliar calcium application. NC-7 cultivar treated with the soil Ca application resulted in the maximum values of biological yield (92.9-ton ha−1), pod yield (6.8-ton ha−1), seed yield (4.4-ton ha−1), oil yield (2247.0 kg ha−1), pod index (203.2 g) and seed index (84.1 g). The interaction between the NC-7 cultivar and soil calcium applications is recommended to attain the best combination, leading to the highest yield and seed quality of peanuts. [ABSTRACT FROM AUTHOR]

Ammonia (NH3) emissions affect the environment, the climate, and human health and originate mainly from agricultural sources like urea fertilizers. Such losses from urea fertilizer can be avoided by different application techniques like incorporation. However, the knowledge of the effect of these techniques on NH3 emissions is very limited and ambiguous since incorporation can also promote nitrous oxide (N2O) emissions. Three different principles of fertilizer incorporation methods were compared in three different soils (sandy, loamy, and clayey) at two moisture levels of 70% and 30% water-holding capacity (WHC), shallow mixing at 2 cm, injection with the slit technique at 5 cm, and deep complete incorporation at 5 cm simulating plow incorporation. The laboratory study was conducted with open dynamic incubation chambers where NH3 emissions were monitored with washing bottles while N2O emissions were studied with gas chromatographic (GC) measurements. The highest cumulative NH3 emissions occurred at low soil moisture levels in sandy soil (34% of the N applied). A maximum reduction in emissions by 87% was achieved with slit injection and 82% with deep injection compared to standard surface application. The reduction effect was positively related to increasing clay content. N2O emissions were delayed and highest from sandy soil. Overall, all urea incorporation techniques showed great potential for mitigating NH3 emissions on the clayey soil; for sandy and drier soils, only deeper or closed slot injection were consistently effective. However, connected to the surface incorporation at the higher moisture level, a relevant increase in N2O emissions compared to surface application was observed. Therefore, an increase in N2O emissions by urea incorporation may rule out specific incorporation techniques for NH3 emissions reduction from field-applied urea. In agricultural practice, a lower reduction in NH3 by fertilizer incorporation can be assumed in sandy soils or under dry soil conditions, as well as a more challenging technical implementation. [ABSTRACT FROM AUTHOR]

Phyllite soil and red clay belong to the soils that negatively impact the engineering performance of railway subgrade and may cause subgrade bulges, uneven subgrade settlement, and other subgrade distresses. In order to make full use of these two soils, a collaborative improvement plan was proposed. A series of tests were conducted to analyze the synergistic effects of lime and red clay on the improvement of phyllite soil. The tests included the no loading swelling ratio, swelling pressure, consolidation, and direct shear tests. Additionally, scanning electron microscopy was used to investigate the role of lime and red clay in soil improvement. The test results show that a red clay ratio of 60% + lime content of 3% is the optimal composite improvement scheme. The scheme led to a 93% reduction in the no loading swelling ratio and an 88% reduction in swelling pressure. Additionally, cohesion, the internal friction angle, and the compression modulus increased by 345%, 73%, and 373%. Red clay and lime had weak synergistic improvement effects on the no loading swelling ratio, the swelling pressure, and the internal friction angle of phyllite soil, that is, the synergistic improvement effect of red clay and lime was less than the sum of the single improvement effect but greater than the single improvement effect. Red clay and lime had a strong synergistic improvement effect on the cohesion and the compression modulus of phyllite, that is, the synergistic improvement effect of red clay and lime was greater than the sum of the single improvement effect. The microstructure analysis test results show that red clay can fill the pores of phyllite soil and improve its immediate strength. Through hardening and cementation, lime can enhance the strength of phyllite soil as well as address the issue of the reduced engineering properties of phyllite soil and red clay when exposed to water. Red clay and lime promote each other's reactions and have a synergistic improvement effect on phyllite soil. [ABSTRACT FROM AUTHOR]

Featured Application: We found that in the areas with high seasonal rainfall, to stabilize clay soils, if the amount of Montmorillonite mineral is greater than a certain amount (for example, in this study, 45%), with any amount of chemical additives, they do not maintain their stability and collapse. Conversely, soils containing certain amounts of Illite and Kaolinite minerals with the smallest amount of chemical additives have the best performance. Although the interaction between clay minerals and lime is the most effective factor in lime stabilization techniques, it has not been deeply evaluated. This research study investigated the microstructural characteristics of lime-stabilized Bentonite and Kaolin soils using X-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive X-ray (EDX) analyses. To consider the variation in clay mineralogy, these soils were mixed at varied ratios, stabilized, and then subjected to a durability process. The microstructural findings showed that the pozzolanic reactions with lime did not occur or occurred at a low level for Bentonite soil. However, they occurred at a very high level for Kaolin soil. The durability test confirmed the microstructural results and showed that the samples in which Bentonite soil had a share of 40 to 100% by dry weight of the soil did not last with any percent of lime. When the Kaolin soil content reached 100% by dry weight of the soil, the specimens lasted in the best possible way, even with 4% of the lime. This study concluded that the determination of optimum lime content based on the amounts and types of soil clay minerals is an important innovation for geotechnical projects and may be very cost-effective. [ABSTRACT FROM AUTHOR]

This case study focuses on twelve compacted clay soil samples to understand their fundamental physical and thermal properties. For each sample, the density, thermal conductivity, thermal diffusivity, specific heat, and drying shrinkage were assessed. The identification and characterisation of the materials were also carried out by positioning them into the ternary diagram based on the percentage of sand, silt, and clay. These properties are definitive for the performance characteristics of materials used in rammed earth wall construction. The aim is to provide information for better knowledge and prediction regarding the dynamic heat flow in rammed earth walls. Experimental results show a relatively wide range of values for each property, reflecting the diverse properties of the sampled clays. The thermophysical characteristics of the 12 types of earth analysed showed correlations with reports in the literature in terms of density (1490–2150 kg/m3), porosity (23.22–39.99%), specific heat capacity (701–999 J/kgK), and thermal conductivity (0.523–1.209 W/mK), which indicates them as materials suitable for use in the construction of rammed earth walls. Using test data, a dynamic assessment of heat flow through simulated rammed earth walls was performed. For a better understanding of the results obtained, they were compared with results obtained for simulations where the building element would be made of concrete, i.e., a mineral wool core composite. Thus, heat flux at the wall surface and mass flux, respectively, during the 16 years of operation showed similar evolution for all 12 types of clay material analysed, with small variations explained by differences in thermophysical characteristics specific to each type of S1–S12 earth. In the case of walls made from clay material, there is a stabilisation in the evolution of the water content phenomenon by the 5th year of simulation. This contrasts with walls made of concrete, where the characteristic water content appears to evolve continuously over the 16-year period. Therefore, it can be said that in the case of the construction elements of existing buildings, which have already gone through a sufficient period for the maturation of the materials in their construction elements, the rammed earth wall quickly develops a moisture buffer function. In the case of simulating a mineral wool core composite wall, it cannot perform as a temperature or humidity buffer, exhibiting an enthalpy exchange with indoor air that is only 4% of that of the rammed earth walls; consequently, it does not play a significant role in regulating indoor comfort conditions. Overall, there is confirmation of the temperature and moisture buffering capabilities of rammed earth walls during both warm and cold periods of the year, which is consistent with other reports in the literature. The findings of this research provide a better insight into clay as a material for rammed earth walls for more efficient design and construction, offering potential improvements regarding indoor comfort, energy efficiency, and sustainability. The data also provides useful information in the fields of architecture and civil engineering regarding the use of clay as an eco-friendly building material. The results emphasise the importance of thoroughly understanding the thermophysical properties of clay to ensure the efficiency of rammed earth construction. [ABSTRACT FROM AUTHOR]

The present study investigates the functionalecological status of typical light clay soils in vineyards in the southern region of Crimea, using both traditional (including fallow soils) and organic land-use systems. This analysis was carried out by examining agrochemical indicators, microbial respiratory activity, microbial biomass, and the ecological status of the microbial community. In organic vineyard soils, the mean substrate-induced respiration, microbial biomass carbon and the ratio of microbial biomass to organic carbon were found to be 2.8, 4.0, and 4.1 times higher, respectively, compared to conventional farm soils. On the contrary, the microbial metabolic coefficient was 1.4 times lower, signifying more favorable conditions for the functioning of the soil microbiota. The increased mobile sulfur content in organic vineyard soils (18.3 mg kg−1 vs. 8.0 mg kg−1 in traditional farms) and inadequate mobile phosphorus supply in some farms present potential risks. The suboptimal functional state of the microbiome in fallow soils previously under traditional plant protection necessitates comprehensive ecotoxicological analyses before development. Assessing the soil functional ecological status through an ecophysiological evaluation of the microbiome is vital for understanding ampelocenosis soils and making informed decisions on vineyard management practices. [ABSTRACT FROM AUTHOR]

In this study, the combined effect of temperature (T) and pore water salinity on electrical surface conduction parameters was investigated. Two new electrical surface conduction parameters, namely, electrical conductivity of effective solid (σs) and size of diffuse double layer (DDL) water per unit volume of soil (χ), were considered in this study. The tested samples included two commercially available clays and four natural clay soils with diverse physico-chemical properties. The two surface conduction parameters were also used to assess the influence of temperature (T) and pore water salinity, as well as the electrical conductivity of free water (σFW), on the evolution of the free swelling index (FSI) of clays/clay soils through experimental methods. The findings suggested that elevated temperature and σFW increased σs but reduced χ, as well as the FSI of clays/clay soils. Furthermore, the rate of reduction for both χ and FSI augmented under the influence of increased free water salinity, particularly for clays/clay soils with high swelling capacity. The combined reductions of χ and FSI provided substantial evidence that clay DDL thickness decreases as T and σFW increase concurrently. [ABSTRACT FROM AUTHOR]

Hydrochloric acid is prevalent in numerous industries; leakage of this acid may cause persistent problems in the soil. The study aims to prevent any adverse impact of acid on the strength characteristics of silty clay soil by modifying the soil's acid resistance. In this study, unconfined compression tests are performed to investigate the strength of contaminated silty clay soil with concentrations of 4%, 8%, and 12% of HCl solution and the strength of treated soil with 0.4%, 0.5%, 0.6%, and 0.8% of nano-magnesium oxide. In addition, the strength of the soil enhanced with nano-MgO contaminated with different concentrations of hydrochloric acid was investigated to assess the effect of nano-MgO on modifying the acid resistance of clay soil. Moreover, the FE-SEM test was performed to analyze the microstructure of the soil under different circumstances. Based on the results, the strength of clay soil decreased due to contamination with the hydrochloric acid solutions; the reduction in strength was more noticeable when the acid solution became more acidic. Adding 0.6% of nano-magnesium oxide enhances the strength by about 114%. Findings show that adding 0.6% nano-MgO to the soil before exposing it to hydrochloric acid can enhance its acid resistance; the strength of the treated soil with nano-MgO was better at resisting the acid than the untreated soil. [ABSTRACT FROM AUTHOR]

Organic fertilization improves soil fertility and ameliorates the deleterious effects of accumulated salts in soil for sustainable agricultural production. This research was carried out on thirteen-year-old Mexican lime trees to study the effect of humic acid (HA), applied as soil (10, 20 or 30 mL·tree−1) and foliar (0.1 or 0.2%) applications, on soil fertility, tree growth, productivity and fruit quality. The experiment was conducted during the 2020 and 2021 seasons in a randomized complete block design of twelve treatments with three replicates with two trees each. Soil and foliar applications of HA were performed once and twice a month in Marsh, May and July, respectively. HA enhanced the soil's N, P, K, Ca, Mg, Fe, Mn, Zn, Cu and B availability and microbial activity, in addition to improved tree growth, canopy size, leaf chlorophyll and nutrient contents with reduced proline levels. The total yield and number of fruit per tree were increased with increased HA levels. Fruit weight, juice and soluble solids were also increased. The best results were achieved with the combined soil (30 mL·tree−1) and foliar (0.2%) applications of HA, which indicated a great potential to alleviate the effects of salinity stress on Mexican lime growth and productivity. [ABSTRACT FROM AUTHOR]

This study evaluates a binary mixture of fly ash and lime as a stabilizer for natural soils. A comparative analysis was performed on the effect on the bearing capacity of silty, sandy and clayey soils after the addition of lime and ordinary Portland cement as conventional stabilizers, and a non-conventional product of a binary mixture of fly ash and Ca(OH)2 called FLM. Laboratory tests were carried out to evaluate the effect of additions on the bearing capacity of stabilized soils by unconfined compressive strength (UCS). In addition, a mineralogical analysis to validate the presence of cementitious phases due to chemical reactions with FLM was performed. The highest UCS values were found in the soils that required the highest water demand for compaction. Thus, the silty soil added with FLM reached 10 MPa after 28 days of curing, which was in agreement with the analysis of the FLM pastes, where soil moistures higher than 20% showed the best mechanical characteristics. Furthermore, a 120 m long track was built with stabilized soil to evaluate its structural behavior for 10 months. An increase of 200% in the resilient modulus of the FLM-stabilized soils was identified, and a decrease of up to 50% in the roughness index of the FLM, lime (L) and Ordinary Portland Cement (OPC)-stabilized soils compared to the soil without addition, resulting in more functional surfaces. [ABSTRACT FROM AUTHOR]

The adoption of flowable mixtures of treated soils is suggested as a sustainable solution for repairing the damage caused by burrowing animals in the Po River embankments. Soil from damaged sites is proposed to be mixed with lime or cement, other additives, and water in order to obtain mixtures with an adequate compromise between viscosity—which is crucial for flowing the mixture into the hole with site machines—and shrinkage that might occur over time according to the hole boundary conditions. Injections of soil-treated mixtures must guarantee hydraulic and mechanical continuity with the existing embankment and reduce shrinkage phenomena that frequently occur with cement–bentonite grout, which is commonly used for this purpose. This study presents an interdisciplinary experimental programme in the search for the best formulation among several recipes of mixtures of soils, collected from four embankments of Po River or its tributaries and treated with lime or cement, different percentages of water, and other additives. The mixtures, after soil classification and viscosity determinations, were then used to create samples for which shrinkage and erosion susceptibility were estimated, respectively, through a non-standard volume measurement procedure and crumb tests. An abacus will be then proposed in order to give, as a first estimation, applicative indications on the best recipe among the investigated mixtures. [ABSTRACT FROM AUTHOR]

Soil moisture content (SWC) can change the diversity and composition of soil fungal communities by affecting soil texture and soil nutrients. To explore the response of soil fungal communities to moisture in the grassland ecosystem on the south shore of Hulun Lake, we set up a natural moisture gradient that was subdivided into high (HW), medium (MW), and low (LW) water contents. Vegetation was investigated by quadrat method, and aboveground biomass was collected by the mowing method. Soil physicochemical properties were obtained by internal experiments. The composition of the soil fungal community was determined using high-throughput sequencing technology. The results showed significant differences in soil texture, nutrients, and fungal species diversity under the moisture gradients. Although there was significant clustering of fungal communities in different treatments, the fungal community composition was not significantly different. According to the phylogenetic tree, the Ascomycota and Basidiomycota were the most important branches. The fungal species diversity was smaller when SWC was higher, and in this environment (HW), the fungal-dominant species were significantly related to SWC and soil nutrients. At this time, soil clay formed a protective barrier for the survival of the dominant classes Sordariomycetes and Dothideomycetes and increased their relative abundance. In summary, the fungal community responded significantly to SWC on the southern shore of the Hulun Lake ecosystem in Inner Mongolia, China, and the fungal community composition of the HW group was stable and easier to survive. [ABSTRACT FROM AUTHOR]

Although a number of studies have provided information on soil texture, soil classification, and depth to bedrock throughout China, few studies have combined this information, which is the basis for agricultural field management. A total of 81% of China's cultivated lands are distributed among the Middle–Lower Yangtze Plain (18.2%), arid and semiarid North China Plain (18.2%), Northeast Plain (17%), Huang-Huai-Hai Plain (16.1%), and Yunnan–Guizhou Plateau (11.6%). The Huang-Huai-Hai Plain has the highest density of agricultural land (58.5%) and the greatest depth to bedrock of cultivated land (243–402 m). The lowest cultivated depth to bedrock (4–84 m) is concentrated in the Sichuan Basin and its surrounding regions. The main cultivated soil types are Anthrosols, Fluvisols, Cambisols, Phaeozems, Luvisols, Kastanozems, Leptosols, and Acrisols, under the main topsoil texture classes of loam, clay loam, silty clay loam, silt loam, sandy loam, and clay. The Fluvisols had the largest depth to bedrock (156 m) on the Middle–Lower Yangtze Plain and Huang-Huai-Hai Plain, with the highest silt soil distributions but comparable lower sand contents. The Yunnan–Guizhou Plateau had the highest clay soil content. The cultivation under Kastanozems and Leptosols on the Qinghai–Tibet Plateau and in arid and semiarid North China and under Phaeozems on the Northeast Plain should be restricted and managed very cautiously facing erosion risk. The higher percentages of Anthrosols are on the Middle–Lower Yangtze Plain (37%), in Southern China (32%), and on the Yunnan–Guizhou Plateau (26%). The same cultivation aim (i.e., more crop 0production) has produced a similar range of properties over time among the soils developed on agricultural fields, which are classified as Anthrosols. However, various soil types can still be found in agroecosystems because of the variations in climate and topography. Our results highlight that the agriculture-based soil climate and topography shape the interaction of the soil development and not only the pedogenic history of the soil development under variations in the soil depth to bedrock but also the cultivation of distinct pedogenic features. This study provides cultivated soil information on the depth to bedrock, soil classification, and soil texture in China, as well as instructions for field strategies for sustainable agricultural development. [ABSTRACT FROM AUTHOR]

This work presents an experimental study on the physico-mechanical and microstructural characteristics of stabilised soils and the effect of wetting and drying cycles on their durability as road subgrade materials. The durability of expansive road subgrade with a high plasticity index treated with different ratios of ground granulated blast furnace slag (GGBS) and brick dust waste (BDW) was investigated. Treated and cured samples of the expansive subgrade were subjected to wetting–drying cycles, California bearing ratio (CBR) tests, and microstructural analysis. The results show a gradual reduction in the California bearing ratio (CBR), mass, and the resilient modulus of samples for all subgrade types as the number of cycles increases. The treated subgrades containing 23.5% GGBS recorded the highest CBR value of 230% under dry conditions while the lowest CBR value of 15% (wetting cycle) was recorded for the subgrade treated with 11.75% GGBS and 11.75% BDW at the end of the wetting–drying cycles, both of which find useful application in road pavement construction as calcium silicate hydrate (CSH) gel was formed in all stabilised subgrade materials. However, the increase in alumina and silica content upon the inclusion of BDW initiated the formation of more cementitious products due to the increased availability of Si and Al species as indicated by EDX analysis. This study concluded that subgrade materials treated with a combination of GGBS and BDW are durable, sustainable and suitable for use in road construction. [ABSTRACT FROM AUTHOR]

Land subsidence in coastal and delta cities often results in infrastructure and residential building damages, while also increasing the area's flooding vulnerability. The coastal cities of Messolonghi and Aitolikon are typical examples, as they are built on top of old stream deposits near the coast. In the last several years, the gradual subsidence of the sites, combined with the impact of climate change, resulted in multiple floods. The rush of seawater over the lowlands has also been reported. Persistent scatterer interferometry (PSI) is a remote-sensing technique that can provide a reliable and cost-effective solution, as it can be used to identify and monitor soil displacements. In this study, a novel parallelized PSI (P-PSI) processing chain, developed by the Operational Unit Center for Earth Observation Research and Satellite Remote Sensing (BEYOND) of the National Observatory of Athens, as well as the Copernicus EGMS product were used to identify these displacements. The results were examined in correlation with other potential factors such as the overexploitation of the underground water, the natural compaction of the clay soil layers, the primary and secondary consolidation due to the external construction loading, the oxidation of the organic soils, tidal gauge data, precipitation data, and ground truth data. In Messolonghi, various deformation rates were recorded, with maximum mean values of −5 mm/year in the eastern part, whereas in Aitolikon, the maximum values were around −4.5 mm/year. The displacements were mostly attributed to the primary consolidation due to the building loads. Deformation patterns and their correlation with precipitation could also be witnessed. It was evident that the increased precipitation rates and sea level rise played a leading role in the constant flooding. [ABSTRACT FROM AUTHOR]

Simple Summary: Fire is traditionally used by farmers for clearing fields when the fallow period is short. Soil chemical properties changed significantly after burning and returned to prefire levels after 1 year. Bacillus, HSB OF53-F07, Conexibacter, and Acidothermus abundances increased immediately after burning and then significantly declined, with lower levels 1 year after burning. Anaeromyxobacter and Candidatus Udaeobacter dominated at 1 year after burning. Burning under high soil moisture conditions and within a very short time caused no effect to the bacterial soil communities. Rice straw and stubble burning is widely practiced to clear fields for new crops. However, questions remain about the effects of fire on soil bacterial communities and soil properties in paddy fields. Here, five adjacent farmed fields were investigated in central Thailand to assess changes in soil bacterial communities and soil properties after burning. Samples of soil prior to burning, immediately after burning, and 1 year after burning were obtained from depths of 0 to 5 cm. The results showed that the pH, electrical conductivity, NH4-N, total nitrogen, and soil nutrients (available P, K, Ca, and Mg) significantly increased immediately after burning due to an increased ash content in the soil, whereas NO3-N decreased significantly. However, these values returned to the initial values. Chloroflexi were the dominant bacteria, followed by Actinobacteria and Proteobacteria. At 1 year after burning, Chloroflexi abundance decreased remarkably, whereas Actinobacteria, Proteobacteria, Verrucomicrobia, and Gemmatimonadetes abundances significantly increased. Bacillus, HSB OF53-F07, Conexibacter, and Acidothermus abundances increased immediately after burning, but were lower 1 year after burning. These bacteria may be highly resistant to heat, but grow slowly. Anaeromyxobacter and Candidatus Udaeobacter dominated 1 year after burning, most likely because of their rapid growth and the fact that they occupy areas with increased soil nutrient levels after fires. Amidase, cellulase, and chitinase levels increased with increased organic matter levels, whereas β-glucosidase, chitinase, and urease levels positively correlated with the soil total nitrogen level. Although clay and soil moisture strongly correlated with the soil bacterial community's composition, negative correlations were found for β-glucosidase, chitinase, and urease. In this study, rice straw and standing stubble were burnt under high soil moisture and within a very short time, suggesting that the fire was not severe enough to raise the soil temperature and change the soil microbial community immediately after burning. However, changes in soil properties due to ash significantly increased the diversity indices, which was noticeable 1 year after burning. [ABSTRACT FROM AUTHOR]

The main thrust of this research was to establish any benefits of mellowing, and the optimal moisture content (OMC) for compacting mellowed sulphate-bearing clay soil undergoing the stabilization process. Two three-day mellowing regimes were carried out, prior to final compaction, at different initial moisture contents of 30% or 40% OMC. The unmellowed specimens were compacted immediately after mixing with the blended stabilizers. A blend of quicklime (L) with a sustainable by-product, silica fume (SF), at a 1:1 ratio (2%L–2%SF) was used. Linear expansion and unconfined compressive strength (UCS) tests were carried out to evaluate the benefits of mellowing. The test results suggested that the mellowed test specimens achieved better UCS and swelling properties compared to the unmellowed specimens. Mellowing at 1.2 OMC produced better strength performance than at 1.4 OMC, whereas mellowed specimens at 1.4 OMC showed better resistance to linear expansion compared to 1.2 OMC. The research findings suggested that optimal performance was achieved by mellowing at the higher initial moisture condition of 40% OMC and compacting the materials at the lower moisture condition of 1.2 OMC. [ABSTRACT FROM AUTHOR]

The utilization of industrial by-products as stabilizers is gaining attention from the sustainability perspective. Along these lines, granite sand (GS) and calcium lignosulfonate (CLS) are used as alternatives to traditional stabilizers for cohesive soil (clay). The unsoaked California Bearing Ratio (CBR) was taken as a performance indicator (as a subgrade material for low-volume roads). A series of tests were performed by varying the dosages of GS (30%, 40%, and 50%) and CLS (0.5%, 1%, 1.5%, and 2%) for different curing periods (0, 7, and 28 days). This study revealed that the optimal dosages of granite sand (GS) are 35%, 34%, 33%, and 32% for dosages of calcium lignosulfonate (CLS) of 0.5%, 1.0%, 1.5%, and 2.0%, respectively. These values are needed to maintain a reliability index greater than or equal to 3.0 when the coefficient of variation (COV) of the minimum specified value of the CBR is 20% for a 28-day curing period. The proposed RBDO (reliability-based design optimization) presents an optimal design methodology for designing low-volume roads when GS and CLS are blended for clay soils. The optimal mix, i.e., 70% clay blended with 30% GS and 0.5% CLS (exhibiting the highest CBR value) is considered an appropriate dosage for the pavement subgrade material. Carbon footprint analysis (CFA) was performed on a typical pavement section according to Indian Road Congress recommendations. It is observed that the use of GS and CLS as stabilizers of clay reduces the carbon energy by 97.52% and 98.53% over the traditional stabilizers lime and cement at 6% and 4% dosages, respectively. [ABSTRACT FROM AUTHOR]

Aflatoxins (AFs) are fungal secondary metabolites frequently detected in soil that exhibit in vitro toxicity to certain soil microorganisms. However, microbial responses at different levels and in complex systems such as the soil environment have not been systematically studied. Therefore, we investigated multiple microbial responses in two different soils (sandy loam and clay) to aflatoxin B1 (AFB1) at environmentally relevant concentrations (0.5–500 µg kg−1) during a 28-day incubation. General microbial parameters for biomass (microbial biomass carbon and ergosterol), activity (glucose-induced and basal respiration), and catabolic functionality (substrate utilization patterns) were assessed. We observed minor and transient effects in both soils. In sandy loam, we found negative effects on activity and catabolic functionality with increased metabolic quotient, while clay soil exhibited stimulation for the same parameters, suggesting a hormetic effect due to reduced bioavailability through sorption onto clay minerals. Our results indicate that AFB1 does not pose a threat to general microbial indicators under the test conditions in soils without previous AF contamination. Given the toxic potential of AFs to specific microorganisms, further studies should investigate responses at higher taxonomic and functional levels in natural environments of aflatoxigenic fungi, such as tropical soils, and including additional physicochemical stressors. [ABSTRACT FROM AUTHOR]

Over-fertilization has a significant impact on soil microbial properties and its ecological environment. However, the effects of long-term fertilization on microbial properties on a large scale are still vague. This meta-analysis collected 6211 data points from 109 long-term experimental sites in China to evaluate the effects of fertilizer type and fertilization duration, as well as soil and climate conditions, on the effect sizes on various microbial properties and indices. The organic fertilizers combined with straw (NPKS) and manure (NPKM) had the highest effect sizes, while the chemical fertilizers N (sole N fertilizer) and NPK (NPK fertilizer) had the lowest. When compared with the control, NPKM treatment had the highest effect size, while N treatment had the lowest effect size on MBN (111% vs. 19%), PLFA (110% vs. −7%), fungi (88% vs. 43%), Actinomycetes (97% vs. 44%), urease (77% vs. 25%), catalase (15% vs. −11%), and phosphatase (58% vs. 4%). NPKM treatment had the highest while NPK treatment had the lowest effect size on bacteria (123% vs. 33%). NPKS treatment had the highest while N treatment had the lowest effect sizes on MBC (77% vs. 8%) and invertase (59% vs. 0.2%). NPKS treatment had the highest while NPK treatment had the lowest effect size on the Shannon index (5% vs. 1%). The effect sizes of NPKM treatment were the highest predominantly in arid regions because of the naturally low organic carbon in soils of these regions. The effect sizes on various microbial properties were also highly dependent on soil texture. In coarse-textured soils the effect sizes on MBC and MBN peaked sooner compared with those of clayey or silty soils, although various enzymes were most active in silty soils during the first 10 years of fertilization. Effect sizes on microbial properties were generally higher under NPKM and NPKS treatments than under NPK or N treatments, with considerable effects due to climate conditions. The optimal field fertilizer regime could be determined based on the effects of fertilizer type on soil microorganisms under various climate conditions and soil textures. This will contribute to the microbial biodiversity and soil health of agricultural land. Such controls should be used for adaptation of fertilization strategies to global changes. [ABSTRACT FROM AUTHOR]

Sand drift erosion is common on aeolian landforms, particularly in the Gobi desert where sand drift is often quite strong. Sand drift erosion can lead to many types of hazards, including severe crop loss, structural damage to buildings or infrastructure, and abrasion of soil or clay components that contribute to the production of fine particulate matter. This article combines the Gobi sand flow model with the solid particles erosion model to simulate the sand drift erosion process in a variety of Gobi environments. The results show that the impact erosion of saltation particles is highly dependent on both the friction velocity and the gravel coverage. Saltation erosion amount increases with the increment of friction velocity and the gravel coverage. The vertical profile of saltating erosion rate displays a clear stratification pattern composed of a linear increasing layer, a damage layer, and a monotonic decreasing layer. The maximum value of the saltation erosion rate increases as the friction velocity increases and their curve shows a power-law relationship. The damage height caused by saltation erosion is primarily concentrated in the height range of 0.03 m to 0.15 m, and it increases approximately linearly with friction velocity. [ABSTRACT FROM AUTHOR]

The economic and environmental sustainability of extensive livestock production systems requires the optimisation of soil management, pasture production and animal grazing. Soil compaction is generally viewed as an indicator of soil degradation processes and a determinant factor in crop productivity. In the Montado silvopastoral ecosystem, characteristic of the Iberian Peninsula, animal trampling is mentioned as a variable to consider in soil compaction. This study aims: (i) to assess the spatial variation in the compaction profile of the 0–0.30 m deep soil layer over several years; (ii) to evaluate the effect of animal trampling on soil compaction; and (iii) to demonstrate the utility of combining various technological tools for sensing and mapping indicators of soil characteristics (Cone Index, CI; and apparent electrical conductivity, ECa), of pastures' vegetative vigour (Normalised Difference Vegetation Index, NDVI) and of cows' grazing zones (Global Positioning Systems, GPS collars). The significant correlation between CI, soil moisture content (SMC) and ECa and between ECa and soil clay content shows the potential of using these expedient tools provided by the development of Precision Agriculture. The compaction resulting from animal trampling was significant outside the tree canopy (OTC) in the four evaluated dates and in the three soil layers considered (0–0.10 m; 0.10–0.20 m; 0.20–0.30 m). However, under the tree canopy (UTC), the effect of animal trampling was significant only in the 0–0.10 m soil layer and in three of the four dates, with a tendency for a greater CI at greater depths (0.10–0.30 m), in zones with a lower animal presence. These results suggest that this could be a dynamic process, with recovery cycles in the face of grazing management, seasonal fluctuations in soil moisture or spatial variation in specific soil characteristics (namely clay contents). The NDVI shows potential for monitoring the effect of livestock trampling during the peak spring production phase, with greater vigour in areas with less animal trampling. These results provide good perspectives for future studies that allow the calibration and validation of these tools to support the decision-making process of the agricultural manager. [ABSTRACT FROM AUTHOR]

Blasting in clay soil in the field of anchoring and foundation of objects and structures has its benefits in construction and geotechnical practice. The foundations of the method lay in the fact that a shock wave is generated when the explosive charge is detonated. The shock wave, with high pressure at the wavefront, causes the natural structure of the clay soil to be destroyed, and a spherical expansion in the clay mass is formed. The presented research is focused on determining the shape and volume of the resulting expansion in test blasts performed with several types of explosives. An application named Borehole was developed to determine the resulting spherical expansion formed after the detonation of an explosive charge with the integration of the GNSS method of measurement, depth camera, and laser. The application Borehole calculates expansion volume based on the coordinates obtained with the GNSS and the laser-obtained distance of the formed expansion and provides a graphical interpretation in 2D and 3D views. Additionally, when developing the application Borehole, compatibility with CAD tools was considered, primarily for better verification and a more detailed graphical interpretation of 3D views. The developed method allows for simple determination of the volume and dimension of the spherical expansion in clay soil with acceptable accuracy for the design and building of geotechnical structures constructed above and underground. [ABSTRACT FROM AUTHOR]

Cropland soils are key systems in global carbon budgets due to their high carbon-sequestration potential. It is widely accepted that clays are one of the soil components that have a significant effect on the stabilisation of soil organic carbon (SOC), owing to its surface interactions with organic molecules. However, the identification of the direct effects of clays on SOC stabilization is complicated, mainly due to the difficulty of accurately characterizing the mineralogy of clays, especially phyllosilicates. In this study, the relationships between soil phyllosilicates and functional SOC pools in woodlands and comparable olive groves, under two contrasting management systems (bare soils versus soil under cover crops) and parent materials (calcareous and siliceous), were explored. The total mineralogy of soil and clay fractions and the soil-clay assemblages were analysed through the decomposition of X-ray diffraction patterns, and were then related to four SOC pools. Total and unprotected SOC was higher in olive groves under cover crops, and this was true independent of the parent material, proving the importance of herbaceous covers in SOC sequestration in woody crops. Some significant correlations between clay minerals and SOC fractions were found. Interestingly, mixed-layer content was correlated with the biochemically protected SOC fraction (r = 0.810, p < 0.05), and this was so even when the partial correlation coefficient was calculated (r = 0.761, p < 0.05). According to the partial correlation networks (PCN), four separated clusters of variables were obtained, which joined into only one at fdr < 0.25. The PCNs supported the direct correlation between mixed-layer content, especially those rich in smectite, and the biochemically protected SOC fraction, suggesting that smectite layers may stabilize organic molecules. Since potassium enrichment is higher in the rooted layers of woodland and soils under cover crops, and this increase is related to the collapse of swelling layers, these soils were poorer in smectite phases than the bare soils. This also would explain why the biochemically protected SOC was more abundant in the latter. [ABSTRACT FROM AUTHOR]

The bearing capacity of the phyllite soil subgrade can be greatly improved by red clay, but the water stability of the modified soil is still poor. Hence, the blended soil has been found to be unsuitable for the construction of high-speed railways. This paper proposes an innovative scheme, by adding appropriate amounts of cement and red clay concurrently, to improve phyllite soil, which achieves a higher bearing capacity of the subgrade immediately after compaction, while also solving the problem of insufficient water stability. Laboratory tests of the permeability and disintegration characteristics of phyllite soils improved by cement, red clay, and both were carried out. The test results show that the permeability coefficient and maximum disintegration rate of soil can be improved effectively by using both red clay and cement. It was found that the optimal combination scheme is to add 3% cement and 40% red clay to phyllite soil by mass. Under the optimal scheme, the permeability coefficient, maximum disintegration rate, and disintegration rate of the improved soil decreased by 90.02%, 90.30%, and 99.02%, respectively, compared with the phyllite soil. The microscopic study shows that the mechanism of red clay blending with phyllite is that the finer particles of red clay infill the pores among the phyllite particles, thus reducing its permeability coefficient. The mechanism of adding cement to the blending soil mainly results from the production of hard-setting new materials and the formation of a cementation network among the soil particles, which not only increases the shear strength of the soil, but also reduces the permeability coefficient and the maximum disintegration ratio of the soil. This work makes full use of the complementary characteristics of red clay and phyllite soil and the advantages of hard-setting new materials, which will provide a new idea for soil improvement of the phyllite soil in the future. [ABSTRACT FROM AUTHOR]

Simple Summary: Voles of the genus Microtus represent one of the most speciose mammalian genera in the Holarctic. Moreover, they are also widespread in the European agricultural landscape. In addition, they are the most common vertebrate pests in European agriculture, causing extensive annual damages to a large variety of crops and exposing humans to an increased risk of pathogen transmission. In order to propose mitigation and possible management measures, it is necessary to record the initial abundance and distribution patterns of vole species within complex ecosystems. Considering the large extensions occupied by agroecosystems and the demanding but small-scale application of live trapping, an optimal method to initiate small mammal monitoring on large spatial scales is through Barn Owl Tyto alba diet analysis. Barn Owls prey almost exclusively on small mammals and predominantly on voles; thus, they can be used as an ideal proxy for the distribution and abundance patterns of small mammals in the field. In our study, we studied the diet of Barn Owls over a total range of 3000 sq. km for two continuous years through pellet analysis (more than 10,000 pellets) and identified the distribution and abundance patterns of four vole species with respect to different environmental gradients. Voles are the most common vertebrate pests in European agriculture. Identifying their distribution and abundance patterns provides valuable information for future management. Barn Owl diet analysis is one of the optimum methods used to record small mammal distribution patterns on large spatial scales. From 2003 to 2005, a total of 10,065 Barn Owl pellets were collected and analyzed from 31 breeding sites in the largest agroecosystem in Greece, the Thessaly plains. A total of 29,061 prey items were identified, offering deep insight into small mammal distribution, specifically voles. Four discrete vole species (Harting's vole Microtus hartingi, East European vole Microtus levis, Thomas's pine vole Microtus thomasi, and Grey dwarf hamster Cricetulus migratorius) comprised 40.5% (11,770 vole prey items) of the total Barn Owl prey intake. The presence and abundance of the voles varied according to underlying environmental gradients, with soil texture and type playing a major role. M. levis showed no significant attachments to gradients, other than a mild increase in Mollisol soils. It was syntopic in all sites with M. hartingi, which was the dominant and most abundant small mammal species, preferring non-arable cultivated land, natural grasslands, set-aside fields, and fallow land. M. thomasi was strictly present in western Thessaly and strongly associated with a sandy-clay soil texture and Alfisol soils. C. migratorius was the least represented vole (162 items), exclusively present in eastern Thessaly and demonstrating a stronger association with cereals, Mollisol soils, and an argillaceous-clay soil texture. This is the first study in Greece at such a large spatial scale, offering insights for pest rodents' distribution in intensive agroecosystems and their response to environmental gradients including soil parameters. [ABSTRACT FROM AUTHOR]

Soil texture has a great influence on the physical–hydric and chemical behavior of soils. In the Amazon regions, due to the presence of dense forest cover and limited access to roads, carrying out surveys and mapping of soils is challenging. When data exist, they are relatively sparse and the distribution is quite uneven. In this context, machine learning algorithms (ML) associated with remote sensor covariates offer a framework to derive digital maps of soil attributes. The objective of this study was to produce maps of surface and subsurface soil clay, silt, and sand contents in a 13.440 km2 area in the Amazon. The specific objectives were to (a) evaluate the gain in prediction accuracy when using the P-band of airborne radar as a covariate; (b) evaluate two sampling approaches (Reference Area—RA and Total Area—TA); and (c) evaluate the transferability and performance of three ML algorithms: regression tree (RT), random forest (RF), and support vector machine (SVM). The study site was divided into three blocks, called Urucu, Araracanga, and Juruá, respectively. The soil dataset consisted of 151 surface and subsurface sand, silt, and clay observations and 21 covariates (20 relief variables and the backscattering coefficient from the P-band). Both the RA and TA sampling approach used 114 observations for training the prediction models (75%) and 37 for validation (25%). The RA approach was better for the development of sand and silt models. Overall, RF derived the most accurate predictions for all variables. The effect of introducing the P-band backscattering coefficient improved the sand prediction accuracy at the surface and subsurface in Araracanga, which had the highest sand content, with relative improvements (RI) of the R2, root mean square error (RMSE), and mean absolute error (MAE) of 46%, 3%, and 4% at the surface, respectively, and 66.7%, 4.4%, and 5.2% at the subsurface, respectively. For silt, the P-band improved the predictions at the surface in Araracanga, which had the lowest silt contents among the blocks. For clay, adding the P-band improved the RF predictions at the subsurface, with RI of the R2, RMSE, and MAE of 29%, 5%, and 5%, respectively. Despite the low observation density, inherently hindered by the low accessibility of the area and high costs of sampling thereof, the results showed the potential of ML algorithms boosted by airborne radar P-band to map soil clay, silt, and sand contents in the Amazon. [ABSTRACT FROM AUTHOR]

Petroleum-contaminated soil (PCS) exhibits a variety of oil–soil interfacial properties. Surface heterogeneity of soil particles is one of the most critical influencing aspects. The interaction energies of the heterogeneous surfaces of montmorillonite (Mnt) and kaolinite (Kln) for saturates adsorption were determined by molecular simulation to be −1698.88 ± 0.67 (001 surface of Mnt), −73.81 ± 0.51 (010 edge of Mnt), −3086.33 ± 0.46 (001 surface of Kln), and −850.17 ± 0.74 (010 edge of Kln) kJ/mol, respectively. The adsorption of both clays with saturates relied on van der Waals forces, and the edges of Mnt were hardly adsorbed with saturates. According to adhesive force measurements, the oil–clay interaction forces of Mnt and Kln were 111.18 ± 0.01 and 122.65 ± 0.03 μN, respectively. In agreement with the simulations, Kln adsorbed saturates more strongly. Dynamic interfacial rheology and liquid viscoelasticity also revealed differences in adsorption behaviors between Mnt–saturates and Kln–saturates. It demonstrated that in the case of relatively low clay concentrations, the impact of particle surface heterogeneity on the adsorption process was stronger than that of structure even though Mnt had multilayer structures. Moreover, in thermodynamic adsorption experiments, it was evident that Kln adsorbed more oil than Mnt at the adsorption equilibrium states even though both were multilayer adsorptions and the adsorption amounts declined with increasing temperature. Simultaneously, the characteristics of the thermal adsorption of clay and saturates with different proportions were consistent with clay dispersion in saturates, and Kln released more heat being combined with oil. Overall, the heterogeneity of clay particles strongly affects the oil–clay interfacial chemical behaviors, causing more difficulty in treating PCS containing Kln than those containing Mnt. These results provide a theoretical basis for PCS treatment technology. [ABSTRACT FROM AUTHOR]

Considering that, in the context of the ecological restoration of a large number of exposed rock slopes, it is difficult for existing artificial soil to meet the requirements of mechanical properties and ecological construction at the same time, this paper investigates the stabilization benefits of polyvinyl acetate and attapulgite-treated clayey soil through a series of laboratory experiments. To study the effectiveness of polyvinyl acetate (PVA) and attapulgite as soil stabilizer, a triaxial strength test, an evaporation test and a vegetation growth test were carried out on improved soil with different amounts of PVA content (0, 1%, 2%, 3%, and 4%) and attapulgite replacement (0, 2%, 4%, 6%, and 8%). The results show that the single and composite materials of polyvinyl acetate and attapulgite can increase the peak deviator stress of the sample. The addition of polyvinyl acetate can improve the soil strength by increasing the cohesion of the sample; the addition of attapulgite improves the soil strength mainly by increasing the internal friction angle of the sample. The strength of the composite is greatly improved by increasing the cohesion and internal friction angle of the sample at the same time. The effect of adding materials increased significantly with increasing curing age. Moreover, polyvinyl acetate and attapulgite improve the soil water retention of the soil by improving the water-holding capacity, so that the soil can still ensure the good growth of vegetation under long-term drought conditions. The scanning electron microscopy (SEM) images indicated that the PVA and attapulgite of soil affect the strength characteristics of soil specimens by the reaction of PVA and water, which changes the structure of the soil and, by the interweaving of attapulgite soil particles, acts as the skeleton of the aggregate. Overall, PVA and attapulgite can effectively increase clayey soil stability by improving the cohesive force and internal friction angle of clayey soil. [ABSTRACT FROM AUTHOR]

Soil characteristics, especially clay content and clay type, have significant impacts on splash erosion. This investigation was conducted to determine the effects of clay content and clay type (zeolite, phlogopite, bentonite, and kaolinite) on the shear strength and splash erosion of clay–sand mixtures compared with a clay soil under controlled conditions. Clay–sand mixtures were prepared by mixing 15, 30, and 45 kg 100 kg−1 of the selected clays with pure sand and a clay soil; these mixtures were pre-treated with three levels of wetting and drying (W&D) cycles, and then shear strength was measured. The splash erosion rate was measured at three levels of water status: air-dry, plastic limit (PL), and liquid limit (LL). The highest values of splash erosion were observed in the samples without the W&D cycle, and after applying the W&D cycles, splash erosion decreased. Moreover, splash erosion was higher in the air-dry and LL groups. Splash erosion decreased with increased clay content because of the structure development in the mixtures. In general, as clay content increased, splash erosion was reduced and shear strength was significantly increased. From the highest to lowest mean of cohesion, the results showed the following order: bentonite > kaolinite > phlogopite > clay soil > zeolite. However, splash erosion showed the following order for the studied clays: zeolite > clay soil > phlogopite > kaolinite > bentonite. Nonlinear power models, best-fitted relations between splash erosion and shear strength, and the shear strength could explain about 30–33% of the splash erosion variability in this study. [ABSTRACT FROM AUTHOR]

In this paper, we focus on the application of mechanical properties in a soil–rock mixture modified by microbial mineralization under the influence of different factors, including pH value, cementing solution concentration, and cementing time. Cementing fluids and samples with different pH values, calcium ion concentrations, and mineralization cementation were prepared. The process of urea hydrolysis MICP under different factors was studied. A solidified soil–rock mixture sample under triaxial compression was measured. Then, combined with scanning test methods, such as SEM and XRD, the influence of different factors on the mechanical strength and failure mode of the soil–rock mixture structure was analyzed from a microscopic point of view. The results show that a low concentration of cementing solution with a high concentration of bacteria liquid generated the highest calcium carbonate content and the strongest cementing ability. When the pH value of the cementation solution is six, the cementation effect between the pores is the best, and the deviatoric stress is stronger. When wet-curing samples, short or long curing time will adversely affect the strength of soil–rock mixture samples, the strongest curing and cementing ability is 5 days. The microscopic results show that the microbial mineralization technology fills the pores between the particles, and the interaction force between particles is enhanced to enhance the strength of the soil–rock mixture. [ABSTRACT FROM AUTHOR]

Some Clayey soils are generally categorized as weak soils, and structures lying on such soils have been exposed to severe damage. Therefore, the central thesis of this paper is the impact of a waste material known as a silica fume as nano and micro material on soil's behaviour. To evaluate the effects of those additives on Atterberg limits, compaction characteristics and unconfined compressive strength, clayey soil samples have been transformed using micro and nano silica fume (by-product materials). In the current investigation, silica fume is used at four different percentages: 0, 2, 4, and 7%. The results show that the plasticity index of soil decreases with the addition of micro silica and increases with the addition of nano-silica. Increasing nano silica percentage improves the dry density of the compacted soil and reduces the optimum moisture content. An opposite behavior is observed with adding micro silica to compacted soil. Finally, 4% of silica fume is found to be the optimum dosage to improve the unconfined compressive strength of the treated soil with both additives. As a result, treating the weak clay soil with micro and/or nano-silica fume has the potential to be impactful. [ABSTRACT FROM AUTHOR]

Resistance value (R-value) is one of the basic subgrade stiffness characterizations that express a material's resistance to deformation. In this paper, artificial intelligence (AI)-based models—especially M5P, support vector machine (SVM), and Gaussian process regression (GPR) algorithms—are built for R-value evaluation that meets the high precision and rapidity requirements in highway engineering. The dataset of this study comprises seven parameters: hydrated lime-activated rice husk ash, liquid limit, plastic limit, plasticity index, optimum moisture content, and maximum dry density. The available data are divided into three parts: training set (70%), test set (15%), and validation set (15%). The output (i.e., R-value) of the developed models is evaluated using the performance measures coefficient of determination (R2), mean absolute error (MAE), relative squared error (RSE), root mean square error (RMSE), relative root mean square error (RRMSE), performance indicator (ρ), and visual framework (Taylor diagram). GPR is concluded to be the best performing model (R2, MAE, RSE, RMSE, RRMSE, and ρ equal to 0.9996, 0.0258, 0.0032, 0.0012, 0.0012, and 0.0006, respectively, in the validation phase), very closely followed by SVM, and M5P. The application used for the aforementioned approaches for predicting the R-value is also compared with the recently developed artificial neural network model in the literature. The analysis of performance measures for the R-value dataset demonstrates that all the AI-based models achieved comparatively better and reliable results and thus should be encouraged in further research. Sensitivity analysis suggests that all the input parameters have a significant influence on the output, with maximum dry density being the highest. [ABSTRACT FROM AUTHOR]

The benefits of washed rice water (WRW) as a plant fertilizer, particularly over a consecutive application period, are not well studied. An experiment was therefore carried out to determine: the continuous effects of applying unfermented (F0) and 3-day fermented (F3) WRW on the: (1) soil chemical properties, soil bacterial count, and the growth and plant nutrient content of a test crop, choy sum (Brassica chinensis var. parachinensis), grown on three contrasting soil textures (sandy clay loam, clay, and silt loam); (2) nutrient leaching losses from these three soils due to the continuous application of WRW; (3) crops' improvement in water use, if any, in terms of its water productivity (WP) and water use efficiency (WUE); and (4) the relationship between soil bacterial count and plant growth parameters. The effects of F0 and F3 were compared with conventional NPK fertilizer and a control (only tap water; CON). Two factors, treatments and soil types, were used factorially in a randomized complete block design for three consecutive planting cycles. Results showed that NPK and F3 produced a significantly (p < 0.01) higher plant growth in terms of fresh and dry leaf weights and total leaf area by 5 to 61%, compared to that obtained in the other treatments. Furthermore, plants receiving either NPK or F3 had a significantly higher plant nutrient content (P, K, Ca, Mg, and Cu) in the third planting cycle. Clay soil treated with F3, NPK, and F0 had significantly higher NH 4 + , P, Ca, Mg, Zn, and B, by 19 to 152% relative to the other soils, irrespective of treatments. Soil nutrient leaching losses of P, K, Ca, Mg, Cu, Zn, and B decreased with successive planting cycles for all treatments. However, soils treated with either F3 or F0 experienced higher leaching of NH 4 + and NO 3 −   by 37 to 259% and 13 to 34%, respectively, relative to the NPK and CON. Plants treated with either NPK or F3 also had higher WP by 21 to 42% than the other treatments. For all the treatments, plants' WUE increased with successive planting cycles; however, there was no significant difference between the treatments. F3 stimulated a significantly higher growth and yield of choy sum due to its nutrient and bacterial contents, and the continuous increase in plant growth with successive planting cycles indicated the carryover effects of the treatments, particularly by F3. [ABSTRACT FROM AUTHOR]

The study of the mechanical properties between the pile and soil is limited when an enlarged head is added at the bottom of the pile foundation, which acts as anchor stabilization. This study investigates the blade pile foundation used in a solar panel project, which is subjected to lateral wind load action. The parametrical study is performed through the numerical simulation of the blade pile that is embedded in clay soil. The study considers both the soil modulus and the strength parameter of cohesion and concludes that the blade pile foundation capacity has a positive correlation with both. Moreover, when adding blades to a normal circular hollow section (CHS) pile, if the clay cohesion is less than 35 MPa, the capacity improvement rate will be greater. It analyzes the simulated load versus the soil displacement by considering clay in the soil states of very soft, soft, firm, stiff, very stiff and hard. This study finds that the blade application increases the lateral capacity of the pile foundation. In addition, when the soil is very soft to firm, adding blades results in a higher percentage of capacity improvement, which is up to 14.8% for the standard 1.5-m CHS pile with an outside diameter of 76.1 mm. [ABSTRACT FROM AUTHOR]

Air temperature in the Northern Hemisphere has been progressively warming in the recent decades, and the ground temperatures have increased correspondingly. The air temperature increasing due to the climate change induces degradation of permafrost and frost heaving activation. The frost heaving forces cause unevenly distributed damaging displacement of foundations and thus poses problems to the development of Arctic regions. Frost-heave uplift forces can be reduced by protecting piles with an OSPTReline (or Reline) polymer heat-shrinkable jacket. The interaction of heaving soil with a pile covered with the Reline jacket is modeled in laboratory to estimate the uplift force and the related shear strength of frozen soil along the soil-pile adfreeze surface at temperatures from −6 to −1 °C. The data are obtained for silty sand and silty clay soils and mortar (1:5 cement-sand mixture). The experiments show that frost-heave uplift forces on Reline-protected piles are 52% to 85% lower than on uncovered steel piles (steel grade 09G2S—analog to European steel grade S355JR), depending on soil type and temperature. [ABSTRACT FROM AUTHOR]

Using stationary electrochemical, polarization resistance, cathodic charging, transient electrochemical impedance spectroscopy, and theoretical and molecular mechanics studies, epoxy polymer-coated carbon steel specimens' ability to protect metals from corrosion in various soil extracts was examined. According to the polarization resistance tests results, the polymer coating remained stable for 60 days in all three soil extracts, with a 90% efficiency for the steel coated in Soil Extract A, indicating that the sandy soil is less aggressive than the other two. The aggressiveness of clay soil was confirmed by the fact that a polymer-coated steel rod in the clay soil extract experienced a corrosion current density of 97 µA/cm2. In contrast, the same rod in sandy soil had a current density of 58 µA/cm2. The coating's good adsorption contact with the metal surface was further guaranteed by molecular dynamics simulations, which provided atomic-level evidence of the epoxy molecule's adsorption behavior (geometry) and adsorption energy on the carbon steel surface. [ABSTRACT FROM AUTHOR]