1. Computational Approach to the Surface-Crosslinking Process of Superabsorbent Polymer via Central Composite Design.
- Author
-
Kim, Hae-Chan, Kwon, Yong-Rok, Kim, Jung-Soo, Kwon, Miyeon, Kim, Jong-Ho, and Kim, Dong-Hyun
- Subjects
- *
SUPERABSORBENT polymers , *RESPONSE surfaces (Statistics) , *SALINE solutions , *CENTRIFUGATION , *AQUEOUS solutions , *FOURIER transforms - Abstract
The improvement of gel strength and absorption properties through the surface-crosslinking of superabsorbent polymers (SAPs) is essential for sanitary industry applications. We prepared core-SAP via aqueous solution copolymerization, and then surface-crosslinked the core-SAP under various conditions. The structure of the SAP was characterized using Fourier transform infrared (FT-IR) spectroscopy. Central composite design (CCD) of response surface methodology (RSM) has been applied to determine the optimum surface-crosslinking conditions such as surface-crosslinker content, reaction temperature, and reaction time. The optimal surface-crosslinking conditions were identified at a surface-crosslinker content of 2.22 mol%, reaction temperature of 160 °C, and reaction time of 8.7 min. The surface-crosslinked SAP showed excellent absorbency under load of 50 g/g with a permeability of 50 s. Other absorption properties were also evaluated by measuring the free absorbency and centrifuge retention capacity in saline solution. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF