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Porous cerium oxide (ceria) nanoparticles were prepared with and without manganese (Mn) by using the flash combustion technique. Samples with different loadings (Ce/Mn ratio ranged from 100 to 10) were prepared by using a one-step process and water only as a solvent. Moreover, citric acid was utilized as a fuel in an aqueous medium, and the overall synthesis mixture was dried at 100 °C overnight and then calcinated at 550 °C for 3 h. The obtained final solid product was characterized by inductively coupled plasma (ICP), X-ray powder diffraction (XRD), diffuse reflectance ultraviolet-visible spectroscopy (DR-UV-Vis), and scanning electron microscopy (SEM), which was coupled with Energy Dispersive X-Ray Analysis (EDX), high resolution transmission electron microscopy (HR-TEM), and photoluminescence (PL) analysis. The characterization data showed that Mn ions were totally incorporated into the framework of ceria up to the applied loading. Under visible light illumination, the photocatalytic activity of the prepared samples was tested in the decolorization reaction of methyl green (MG) dye (wavelength greater than 425 nm). The results showed that increasing Mn content improved the photocatalytic activity of ceria. The sample with a Ce/Mn ratio of 10 performed 1.8 times better than bare porous ceria. Finally, the reusability of the best-performing sample was investigated in four consecutive runs without treatment, and slight deactivation was monitored after the fourth run. [ABSTRACT FROM AUTHOR]

In this work, the photocatalytic hydrogen evolution from ammonia borane under near-infrared laser irradiation at ambient temperature was demonstrated by using the novel core-shell upconversion-semiconductor hybrid nanostructures (NaGdF4:Yb3+/Er3+@NaGdF4@Cu2O). The particles were successfully synthesized in a final concentration of 10 mg/mL. The particles were characterized via high resolution transmission electron microscopy (HRTEM), photoluminescence, energy dispersive X-ray analysis (EDAX), and powder X-ray diffraction. The near-infrared-driven photocatalytic activities of such hybrid nanoparticles are remarkably higher than that with bare upconversion nanoparticles (UCNPs) under the same irradiation. The upconverted photoluminescence of UCNPs efficiently reabsorbed by Cu2O promotes the charge separation in the semiconducting shell, and facilitates the formation of photoinduced electrons and hydroxyl radicals generated via the reaction between H2O and holes. Both serve as reactive species on the dissociation of the weak B-N bond in an aqueous medium, to produce hydrogen under near-infrared excitation, resulting in enhanced photocatalytic activities. The photocatalyst of NaGdF4:Yb3+/Er3+@NaGdF4@Cu2O (UCNPs@Cu2O) suffered no loss of efficacy after several cycles. This work sheds light on the rational design of near-infrared-activated photocatalysts, and can be used as a proof-of-concept for on-board hydrogen generation from ammonia borane under near-infrared illumination, with the aim of green energy suppliers. [ABSTRACT FROM AUTHOR]