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Magnesium oxychloride cement (MOC), a type of special construction material, has drawn much research attention in solid waste utilization and environmental protection due to its eco-friendly production. Ammonia soda residue (ASR), a by-product generated from sodium carbonate manufacturing, is one of the industrial wastes that can be recycled in MOC systems. However, ASR exhibits adverse effects on the fresh performance and volume stability of MOC pastes. This paper aims at improving the properties of ASR-MOC by introducing fly ash (FA), solid waste from the power industry. Firstly, the roles of FA in MOC pastes are evaluated and analyzed. Then, three substitution ratios of FA (33.3%, 50% and 66.7% in weight) for ASR are designed for MOC pastes with 10% to 40% industrial wastes. Flowability, setting, strength and expansion of all mixtures were experimentally studied. Furthermore, X-ray diffraction (XRD) and scanning electron microscope (SEM) approaches were adopted to illustrate the microstructure changes. Results show that by adding different amounts of FA, the inferior flowability of MOC caused by ASR can be improved by 6–23%, the setting process can be prolonged by 30–55% and the expansion ratio can be reduced by 14–66%. The intensity of characteristic peaks of 5-phase and Mg(OH)2, together with the degrees of crystallization in XRD curves, well explain the strength variation and volume stability of ASR-MOC pastes. According to the regulation of relative specification, up to 20% of solid wastes in weight (10% FA + 10% ASR) can be consumed, contributing greatly to the greener sustainable development of construction materials. [ABSTRACT FROM AUTHOR]