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Phosphine could be a key molecule in the understanding of exotic chemistry that occurs in (exo)planetary atmospheres. While phosphine has been detected in the Solar System's giant planets, it has not been observed in exoplanets to date. In the exoplanetary context, however, it has been theorized to be a potential biosignature molecule. The goal of our study was to identify which illustrative science cases for PH3 chemistry are observable with a space-based mid-infrared nulling interferometric observatory like the Large Interferometer for Exoplanets (LIFE) concept. We identified a representative set of scenarios for PH3 detections in exoplanetary atmospheres that vary over the whole dynamic range of the LIFE mission. We used chemical kinetics and radiative transfer calculations to produce forward models of these informative, prototypical observational cases for LIFEsim, our observation simulator software for LIFE. In a detailed, yet first order approximation, it takes a mission like LIFE: (i) about 1 h to find phosphine in a warm giant around a G star at 10 pc, (ii) about 10 h in H2 or CO2 dominated temperate super-Earths around M star hosts at 5 pc, (iii) and even in 100 h it seems very unlikely that phosphine would be detectable in a Venus-Twin with extreme PH3 concentrations at 5 pc. Phosphine in concentrations previously discussed in the literature is detectable in 2 out of the 3 cases, and it is detected about an order of magnitude faster than in comparable cases with James Webb Space Telescope. We show that there is a significant number of objects accessible for these classes of observations. These results will be used to prioritize the parameter range for the next steps with more detailed retrieval simulations. They will also inform timely questions in the early design phase of a mission like LIFE and guide the community by providing easy-to-scale first estimates for a large part of detection space of such a mission. [ABSTRACT FROM AUTHOR]

Exoplanet hunting efforts have revealed the prevalence of exotic worlds with diverse properties, including Earth-sized bodies, which has fueled our endeavor to search for life beyond the Solar System. Accumulating experiences in astrophysical, chemical, and climatological characterization of uninhabitable planets are paving the way to characterization of potentially habitable planets. In this paper, we review our possibilities and limitations in characterizing temperate terrestrial planets with future observational capabilities through the 2030s and beyond, as a basis of a broad range of discussions on how to advance ''astrobiology'' with exoplanets. We discuss the observability of not only the proposed biosignature candidates themselves but also of more general planetary properties that provide circumstantial evidence, since the evaluation of any biosignature candidate relies on its context. Characterization of temperate Earth-sized planets in the coming years will focus on those around nearby late-type stars. The James Webb Space Telescope ( JWST) and later 30-meter-class ground-based telescopes will empower their chemical investigations. Spectroscopic studies of potentially habitable planets around solar-type stars will likely require a designated spacecraft mission for direct imaging, leveraging technologies that are already being developed and tested as part of the Wide Field InfraRed Survey Telescope (WFIRST) mission. Successful initial characterization of a few nearby targets will be an important touchstone toward a more detailed scrutiny and a larger survey that are envisioned beyond 2030. The broad outlook this paper presents may help develop new observational techniques to detect relevant features as well as frameworks to diagnose planets based on the observables. [ABSTRACT FROM AUTHOR]

Extrasolar Earth and super-Earth planets orbiting within the habitable zone of M dwarf host stars may play a significant role in the discovery of habitable environments beyond Earth. Spectroscopic characterization of these exoplanets with respect to habitability requires the determination of habitability parameters with respect to remote sensing. The habitable zone of dwarf stars is located in close proximity to the host star, such that exoplanets orbiting within this zone will likely be tidally locked. On terrestrial planets with an icy shell, this may produce a liquid water ocean at the substellar point, one particular 'Eyeball Earth' state. In this research proposal, HABEBEE: exploring the HABitability of Eyeball-Exo-Earths, we define the parameters necessary to achieve a stable icy Eyeball Earth capable of supporting life. Astronomical and geochemical research will define parameters needed to simulate potentially habitable environments on an icy Eyeball Earth planet. Biological requirements will be based on detailed studies of microbial communities within Earth analog environments. Using the interdisciplinary results of both the physical and biological teams, we will set up a simulation chamber to expose a cold- and UV-tolerant microbial community to the theoretically derived Eyeball Earth climate states, simulating the composition, atmosphere, physical parameters, and stellar irradiation. Combining the results of both studies will enable us to derive observable parameters as well as target decision guidance and feasibility analysis for upcoming astronomical platforms. Key Words: Bioastronomy-Extrasolar planets-Extreme environments-Extremophiles-Habitable zone. Astrobiology 13, 309-314. [ABSTRACT FROM AUTHOR]