1. A method for the measurement of mass and number of graphene oxide sheets in suspension based on non-spherical approximations
- Author
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Elise Andrea Guerini, Livia Elena Crica, Kostas Kostarelos, Thomas James Dennison, and University of Manchester
- Subjects
Materials science ,Graphitic materials ,Oxide ,Hydrodynamic size ,Particle ,Colloidal suspensions ,law.invention ,Particle analysis ,chemistry.chemical_compound ,law ,General Materials Science ,Resonating sensors ,Composite material ,Liquid suspension ,Suspension (vehicle) ,Graphene ,Mechanical Engineering ,General Chemistry ,Condensed Matter Physics ,2D materials ,RMM ,Aqueous dispersions ,chemistry ,Mechanics of Materials ,Microscopic techniques ,Bouyant mass - Abstract
Currently, particle analysis of 2D materials in suspension is commonly restricted to microscopic techniques in the dry state, and thus does not permit an accurate investigation of colloidal suspensions. Colloids in bulk can be assessed by light scattering and diffraction to investigate features such as their hydrodynamic size, charge and concentration. However, the main drawback of such techniques lies in the application of analytical and computational methods based on models assuming particle sphericity which are not representative for 2D materials. Resonance mass measurement (RMM) is a technique which can enable the analysis of 2D materials in suspension without the assumptions of spherical models. Here, we report the application of RMM to measure particle mass and concentration for three types of graphene oxide (GO) aqueous dispersions. Using micro- and nano-suspended resonating sensors, we were able to decipher gravimetric differences between GO and graphitic materials. Our results support the urge for proper definitions and standardisations of graphene based materials, and offer a new method of characterisation for 2D material colloids in liquid suspension., This work was supported through a studentship offered by the EPSRC Centre for Doctoral Training in the Science and Applications of Graphene and Related Nanomaterials (GrapheneNOWNANO CDT; EP/L01548X/1) within the Nanomedicine Lab at the Faculty of Biology, Medicine and Health (FBMH) and the National Graphene Institute, The University of Manchester, UK. The microscopy facilities at the FBMH EM Core Facility and the Bioimaging Facility and the Wellcome Trust were accessed in this study.
- Published
- 2021