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The H (n = 2) atomic density determination by means of vacuum ultra-violet (VUV) emission spectroscopy of the Lyman-α line in laboratory low pressure plasmas is strongly affected by self-absorption of emitted photons inside the plasma leading to an underestimation of this density. A correction of the densities obtained from VUV emission spectroscopy measurements is performed by using the escape factor method. The corrections applied can reach orders of magnitude even in low pressure plasmas. Assumptions on the spatial distribution of emitting and absorbing particles as well as on the corresponding line profiles have to be made. Consequently, additional measurements are performed, which raises the requirement of a benchmark of the applied correction procedure. In contrast, tunable diode laser absorption spectroscopy (TDLAS) on the Balmer-α line is a direct measurement of the H (n = 2) density and is thus suitable for a benchmark. For the ICP under consideration, H (n = 2) densities obtained via TDLAS are near 3 × 1015 m−3 whereas uncorrected VUV emission spectroscopy gives values in the range of roughly 1013 m−3 depending on pressure and applied RF power. The calculated escape factors are on the order of 2–8 × 10−3. An excellent agreement with TDLAS is observed by applying them to the results of the VUV emission spectroscopy.

Inductively coupled radio frequency (RF) ion sources operating at 1 MHz under the condition of a low gas pressure of 0.3 Pa are the basis of negative hydrogen/deuterium ionbased neutral beam injection systems of future fusion devices. The applied high RF powers of up to 75 kW impose considerable strain on the RF system and so the RF power transfer efficiency η becomes a crucial measure of the ion source’s reliability. η depends on external parameters such as geometry, RF frequency, power, gas pressure and hydrogen isotope. Hence, η along with the plasma parameters are investigated experimentally at the ITER prototype RF ion source. At only 45%–65% in hydrogen and an increase of around 5% in deuterium, η is found to be surprisingly low in this ion source. The power that is not coupled to the plasma is lost by Joule heating of the RF coil (∼26%) and due to eddy currents in the internal Faraday screen (∼74%). The matching transformer adds up to 8 kW of losses to the system. The low values of η and the high share of the losses in the Faraday screen and the transformer strongly suggest optimization opportunities. At high power densities well above 5 W cm−3, indications for neutral depletion as well as for the ponderomotive effect are found in the pressure and power trends of η and the plasma parameters. The comprehensive data set may serve for comparison with other RF ion sources and more standard inductively coupled plasma setups as well as for validating models to optimize RF coupling.

Collisional radiative (CR) models for molecular hydrogen are of high relevance for performing qualitative and quantitative analysis of excited-state population densities measured in plasmas or predicting the dependence of plasma emission on parameter variations. Although the development of such models for H2 started decades ago, major uncertainties still exist regarding the most important set of input parameters, namely the cross sections for electron-impact excitation. The deviations between cross sections from different datasets are particularly pronounced in the energy region close to the threshold energy, strongly increasing the uncertainty of CR models applied to low-temperature plasmas. This paper presents experimental validation of a set of newly calculated non ro-vibrationally resolved electron-impact cross sections calculated for the triplet system of H2 using the molecular convergent close-coupling method in the adiabatic-nuclei formulation. These cross sections are implemented into a CR model based on the flexible solver Yacora. A first comparison of CR calculations with the different datasets to experimentally-determined population densities is performed at a planar ICP discharge for varying pressure (between 1 and 10 Pa) and RF power (between 700 and 1100 W). For the experimentally-accessible electron temperature and density range (2.5–10 eV and 1.8–3.3 × 1016 m−3, respectively), very good agreement between the model and experiment is obtained using the new data set, in contrast to previously used cross sections.

Inductively coupled low-pressure discharges containing InBr have been investigated spectroscopically. In order to obtain plasma parameters such as the vibrational and rotational temperature of the InBr molecule, the emission spectra of the and the transitions have been simulated. The program is based on the molecular constants and takes into account vibrational states up to v = 24. The required Franck–Condon factors and vibrationally resolved transition probabilities have been computed solving the Schrödinger equation using the Born–Oppenheimer approximation. The ground state density of the InBr molecule in the plasma has been determined from absorption spectra using effective transition probabilities for the A–X and B–X transition according to the vibrational population. The obtained densities agree well with densities derived from an Arrhenius type vapour pressure equation.