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M15 is a globular cluster with a known spread in neutron-capture elements. This paper presents abundances of neutron-capture elements for 62 stars in M15. Spectra were obtained with the Michigan/Magellan Fiber System spectrograph, covering a wavelength range from ∼4430 to 4630 Å. Spectral lines from Fe i, Fe ii, Sr i, Zr ii, Ba ii, La ii, Ce ii, Nd ii, Sm ii, Eu ii, and Dy ii were measured, enabling classifications and neutron-capture abundance patterns for the stars. Of the 62 targets, 44 are found to be highly Eu-enhanced r -II stars, another 17 are moderately Eu-enhanced r -I stars, and one star is found to have an s -process signature. The neutron-capture patterns indicate that the majority of the stars are consistent with enrichment by the r -process. The 62 target stars are found to show significant star-to-star spreads in Sr, Zr, Ba, La, Ce, Nd, Sm, Eu, and Dy, but no significant spread in Fe. The neutron-capture abundances are further found to have slight correlations with sodium abundances from the literature, unlike what has been previously found; follow-up studies are needed to verify this result. The findings in this paper suggest that the Eu-enhanced stars in M15 were enhanced by the same process, that the nucleosynthetic source of this Eu pollution was the r -process, and that the r -process source occurred as the first generation of cluster stars was forming. [ABSTRACT FROM AUTHOR]

With the most trans-iron elements detected of any star outside the solar system, HD 222925 represents the most complete chemical inventory among metal-poor stars enhanced with elements made by the rapid neutron capture (" r ") process. As such, HD 222925 may be a new "template" for the observational r -process, where before the (much higher-metallicity) solar r -process residuals were used. In this work, we test under which conditions a single site accounts for the entire elemental r -process abundance pattern of HD 222925. We found that several of our tests—with the single exception of the black hole–neutron star merger case—challenge the single-site assumption by producing an ejecta distribution that is highly constrained, in disagreement with simulation predictions. However, we found that ejecta distributions that are more in line with simulations can be obtained under the condition that the nuclear data near the second r -process peak are changed. Therefore, for HD 222925 to be a canonical r -process template likely as a product of a single astrophysical source, the nuclear data need to be reevaluated. The new elemental abundance pattern of HD 222925—including the abundances obtained from space-based, ultraviolet (UV) data—call for a deeper understanding of both astrophysical r -process sites and nuclear data. Similar UV observations of additional r -process–enhanced stars will be required to determine whether the elemental abundance pattern of HD 222925 is indeed a canonical template (or an outlier) for the r -process at low metallicity. [ABSTRACT FROM AUTHOR]

The ages of the oldest stars shed light on the birth, chemical enrichment, and chemical evolution of the universe. Nucleocosmochronometry provides an avenue to determining the ages of these stars independent from stellar-evolution models. The uranium abundance, which can be determined for metal-poor r -process enhanced (RPE) stars, has been known to constitute one of the most robust chronometers known. So far, U abundance determination has used a single U ii line at λ 3859 Å. Consequently, U abundance has been reliably determined for only five RPE stars. Here, we present the first homogeneous U abundance analysis of four RPE stars using two novel U ii lines at λ 4050 Å and λ 4090 Å, in addition to the canonical λ 3859 Å line. We find that the U ii lines at λ 4050 Å and λ 4090 Å are reliable and render U abundances in agreement with the λ 3859 U abundance, for all of the stars. We, thus, determine revised U abundances for RPE stars, 2MASS J09544277+5246414, RAVE J203843.2–002333, HE 1523–0901, and CS 31082–001, using multiple U ii lines. We also provide nucleocosmochronometric ages of these stars based on the newly derived U, Th, and Eu abundances. The results of this study open up a new avenue to reliably and homogeneously determine U abundance for a significantly larger number of RPE stars. This will, in turn, enable robust constraints on the nucleocosmochronometric ages of RPE stars, which can be applied to understand the chemical enrichment and evolution in the early universe, especially of r -process elements. [ABSTRACT FROM AUTHOR]

We present new observational benchmarks of rapid neutron-capture process (r -process) nucleosynthesis for elements at and between the first (A ∼ 80) and second (A ∼ 130) peaks. Our analysis is based on archival ultraviolet and optical spectroscopy of eight metal-poor stars with Se (Z = 34) or Te (Z = 52) detections, whose r -process enhancement varies by more than a factor of 30 (âˆ'0.22 ≤ [Eu/Fe] ≤ +1.32). We calculate ratios among the abundances of Se, Sr through Mo (38 ≤ Z ≤ 42), and Te. These benchmarks may offer a new empirical alternative to the predicted solar system r -process residual pattern. The Te abundances in these stars correlate more closely with the lighter r -process elements than the heavier ones, contradicting and superseding previous findings. The small star-to-star dispersion among the abundances of Se, Sr, Y, Zr, Nb, Mo, and Te (≤0.13 dex, or 26%) matches that observed among the abundances of the lanthanides and third r -process-peak elements. The concept of r -process universality that is recognized among the lanthanide and third-peak elements in r -process-enhanced stars may also apply to Se, Sr, Y, Zr, Nb, Mo, and Te, provided the overall abundances of the lighter r -process elements are scaled independently of the heavier ones. The abundance behavior of the elements Ru through Sn (44 ≤ Z ≤ 50) requires further study. Our results suggest that at least one relatively common source in the early Universe produced a consistent abundance pattern among some elements spanning the first and second r -process peaks. [ABSTRACT FROM AUTHOR]

We report the detection of an Al ii line at 2669.155 Å in 11 metal-poor stars, using ultraviolet spectra obtained with the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope. We derive Al abundances from this line using a standard abundance analysis, assuming local thermodynamic equilibrium (LTE). The mean [Al/Fe] ratio is −0.06 ± 0.04 (σ = 0.22) for these 11 stars spanning − 3.9 < [Fe/H] < −1.3, or [Al/Fe] = −0.10 ± 0.04 (σ = 0.18) for 9 stars spanning −3.0 < [Fe/H] < −1.3 if two carbon-enhanced stars are excluded. We use these abundances to perform an empirical test of non-LTE (NLTE) abundance corrections predicted for resonance lines of Al i , including the commonly used optical Al i line at 3961 Å. The Al ii line is formed in LTE, and the abundance derived from this line matches that derived from high-excitation Al i lines predicted to have minimal NLTE corrections. The differences between the abundance derived from the Al ii line and the LTE abundance derived from Al i resonance lines are +0.4 to +0.9 dex, which match the predicted NLTE corrections for the Al i resonance lines. We conclude that the NLTE abundance calculations are approximately correct and should be applied to LTE abundances derived from Al i lines. [ABSTRACT FROM AUTHOR]

We present high-resolution Magellan/MIKE spectra of 22 bright (9 < V < 13.5) metal-poor stars (−3.18 < [Fe/H] < −1.37) in three different stellar streams, the Helmi debris stream, the Helmi trail stream, and the ω Centauri progenitor stream. We augment our Helmi debris sample with results for 10 stars by Roederer et al. for a total of 32 stars. Detailed chemical abundances of light elements as well as heavy neutron-capture elements have been determined for our 22 stars. All three streams contain carbon-enhanced stars. For 13 stars, neutron-capture element lines were detectable, and they all show signatures in agreement with the scaled solar r-process pattern, albeit with a large spread of −0.5 < [Eu/Fe] < +1.3. Eight of these stars show an additional small s-process contribution superposed onto their r-process pattern. This could be discerned because of the relatively high signal-to-noise ratio of the spectra given that the stars are close by in the halo. Our results suggest that the progenitors of these streams experienced one or more r-process events early on, such as a neutron star merger or another prolific r-process source. This widely enriched these host systems before their accretion by the Milky Way. The small s-process contribution suggests the presence of asymptotic giant branch stars and associated local (inhomogeneous) enrichment as part of the ongoing chemical evolution by low-mass stars. Stars in stellar streams may thus be a promising avenue for studying the detailed history of large dwarf galaxies and their role in halo assembly with easily accessible targets for high-quality spectra of many stars. [ABSTRACT FROM AUTHOR]

We derive dynamical parameters for a large sample of 446 r-process-enhanced (RPE) metal-poor stars in the halo and disk systems of the Milky Way, based on data releases from the R-Process Alliance, supplemented by additional literature samples. This sample represents more than a 10-fold increase in size relative to that previously considered by Roederer et al. and, by design, covers a larger range of r-process-element enrichment levels. We test a number of clustering analysis methods on the derived orbital energies and other dynamical parameters for this sample, ultimately deciding on application of the HDBSCAN algorithm, which obtains 30 individual chemodynamically tagged groups (CDTGs); 21 contain between 3 and 5 stars, and 9 contain between 6 and 12 stars. Even though the clustering was performed solely on the basis of their dynamical properties, the stars in these CDTGs exhibit statistically significant similarities in their metallicity ([Fe/H]), carbonicity ([C/Fe]), and neutron-capture element ratios ([Sr/Fe], [Ba/Fe], and [Eu/Fe]). These results demonstrate that the RPE stars in these CDTGs have likely experienced common chemical-evolution histories, presumably in their parent satellite galaxies or globular clusters, prior to being disrupted into the Milky Way's halo. We also confirm the previous claim that the orbits of the RPE stars preferentially exhibit pericentric distances that are substantially lower than the present distances of surviving ultrafaint dwarf and canonical dwarf spheroidal galaxies, consistent with the disruption hypothesis. The derived dynamical parameters for several of our CDTGs indicate their association with previously known substructures, dynamically tagged groups, and RPE groups. [ABSTRACT FROM AUTHOR]

We present vanadium (V) abundances for 255 metal-poor stars derived from high-resolution optical spectra from the Magellan Inamori Kyocera Echelle spectrograph on the Magellan Telescopes at Las Campanas Observatory, the Robert G. Tull Coudé Spectrograph on the Harlan J. Smith Telescope at McDonald Observatory, and the High Resolution Spectrograph on the Hobby–Eberly Telescope at McDonald Observatory. We use updated V i and V ii atomic transition data from recent laboratory studies, and we increase the number of lines examined (from one to four lines of V i , and from two to seven lines of V ii). As a result, we reduce the V abundance uncertainties for most stars by more than 20% and expand the number of stars with V detections from 204 to 255. In the metallicity range −4.0 < [Fe/H] < −1.0, we calculate the mean ratios [V i /Fe i ] = −0.10 ± 0.01 (σ = 0.16) from 128 stars with ≥2 V i lines detected, [V ii /Fe ii ] = +0.13 ± 0.01 (σ = 0.16) from 220 stars with ≥2 V ii lines detected, and [V ii /V i ] = +0.25 ± 0.01 (σ = 0.15) from 119 stars. We suspect that this offset is due to departures from local thermodynamic equilibrium, and we recommend using [V ii /Fe ii ], which is enhanced relative to the solar ratio, as a better representation of [V/Fe]. We provide more extensive evidence for abundance correlations detected previously among scandium, titanium, and vanadium, and we identify no systematic effects in the analysis that can explain these correlations. [ABSTRACT FROM AUTHOR]

Extensive progress has recently been made in our understanding of heavy-element production via the r-process in the universe, specifically with the first observed neutron star binary merger (NSBM) event associated with the gravitational-wave signal detected by LIGO, GW170817. The chemical abundance patterns of metal-poor r-process-enhanced stars provide key evidence for the dominant site(s) of the r-process and whether NSBMs are sufficiently frequent or prolific r-process sources to be responsible for the majority of r-process material in the universe. We present atmospheric stellar parameters (using a nonlocal thermodynamic equilibrium analysis) and abundances from a detailed analysis of 141 metal-poor stars carried out as part of the R-Process Alliance (RPA) effort. We obtained high-resolution "snapshot" spectroscopy of the stars using the MIKE spectrograph on the 6.5 m Magellan Clay telescope at Las Campanas Observatory in Chile. We find 10 new highly enhanced r-II (with [Eu/Fe] > +1.0), 62 new moderately enhanced r-I (+0.3 < [Eu/Fe] ≤ +1.0), and 17 new limited-r ([Eu/Fe] < +0.3) stars. Among those, we find 17 new carbon-enhanced metal-poor (CEMP) stars, of which five are CEMP-no. We also identify one new s-process-enhanced ([Ba/Eu] > +0.5) and five new r/s (0.0 < [Ba/Eu] < +0.5) stars. In the process, we discover a new ultra-metal-poor (UMP) star at [Fe/H] = −4.02. One of the r-II stars shows a deficit in α and Fe-peak elements, typical of dwarf galaxy stars. Our search for r-process-enhanced stars by RPA efforts has already roughly doubled the known r-process sample. [ABSTRACT FROM AUTHOR]

We report the discovery of J1521−3538, a bright (V = 12.2), very metal-poor ([Fe/H] = −2.8) strongly r-process-enhanced field horizontal branch star, based on a high-resolution, high signal-to-noise Magellan/MIKE spectrum. J1521−3538 shows the largest r-process element overabundance in any known r-process-enhanced star, with [Eu/Fe] = +2.2, and its chemical abundances of 22 neutron-capture elements closely match the scaled solar r-process pattern. J1521−3538 is also one of few known carbon-enhanced metal-poor stars with r-process enhancement (CEMP-r stars), as found after correcting the measured C abundance for the star's evolutionary status. We propose to extend the existing classification of moderately enhanced () r-I and strongly r-process enhanced () r-II stars to include an r-III class, for r-process stars such as J1521−3538, with and , or times the solar ratio of europium to iron. Using cosmochronometry, we estimate J1521−3538 to be and , using two different sets of initial production ratios. These ages are based on measurements of the Th line at 4019 Å and other r-process element abundances. This is broadly consistent with the old age of a low-mass, metal-poor field red horizontal branch star. J1521−3538 likely originated in a low-mass dwarf galaxy that was later accreted by the Milky Way, as evidenced by its highly eccentric orbit. [ABSTRACT FROM AUTHOR]

We report on the spectroscopic analysis of RAVE J183013.5−455510, an extremely metal-poor star, highly enhanced in CNO, and with discernible contributions from the rapid neutron-capture process. There is no evidence of binarity for this object. At = −3.57, this star has one of the lowest metallicities currently observed, with 18 measured abundances of neutron-capture elements. The presence of Ba, La, and Ce abundances above the solar system r-process predictions suggests that there must have been a non-standard source of r-process elements operating at such low metallicities. One plausible explanation is that this enhancement originates from material ejected at unusually high velocities in a neutron star merger event. We also explore the possibility that the neutron-capture elements were produced during the evolution and explosion of a rotating massive star. In addition, based on comparisons with yields from zero-metallicity faint supernova, we speculate that RAVE J1830−4555 was formed from a gas cloud pre-enriched by both progenitor types. From analysis based on Gaia DR2 measurements, we show that this star has orbital properties similar to the Galactic metal-weak thick-disk stellar population. [ABSTRACT FROM AUTHOR]

Recent studies suggest that metal-poor stars enhanced in carbon but containing low levels of neutron-capture elements may have been among the first to incorporate the nucleosynthesis products of the first generation of stars. We have observed 16 stars with enhanced carbon or nitrogen using the MIKE Spectrograph on the Magellan Telescopes at Las Campanas Observatory and the Tull Spectrograph on the Smith Telescope at McDonald Observatory. We present radial velocities, stellar parameters, and detailed abundance patterns for these stars. Strontium, yttrium, zirconium, barium, europium, ytterbium, and other heavy elements are detected. In four stars, these heavy elements appear to have originated in some form of r-process nucleosynthesis. In one star, a partial s-process origin is possible. The origin of the heavy elements in the rest of the sample cannot be determined unambiguously. The presence of elements heavier than the iron group offers further evidence that zero-metallicity rapidly rotating massive stars and pair instability supernovae did not contribute substantial amounts of neutron-capture elements to the regions where the stars in our sample formed. If the carbon- or nitrogen-enhanced metal-poor stars with low levels of neutron-capture elements were enriched by products of zero-metallicity supernovae only, then the presence of these heavy elements indicates that at least one form of neutron-capture reaction operated in some of the first stars. [ABSTRACT FROM AUTHOR]

We report the first detection of elements at all three r-process peaks in the metal-poor halo star HD 160617. These elements include arsenic and selenium, which have not been detected previously in halo stars, and the elements tellurium, osmium, iridium, and platinum, which have been detected previously. Absorption lines of these elements are found in archive observations made with the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope. We present up-to-date absolute atomic transition probabilities and complete line component patterns for these elements. Additional archival spectra of this star from several ground-based instruments allow us to derive abundances or upper limits of 45 elements in HD 160617, including 27 elements produced by neutron-capture reactions. The average abundances of the elements at the three r-process peaks are similar to the predicted solar system r-process residuals when scaled to the abundances in the rare earth element domain. This result for arsenic and selenium may be surprising in light of predictions that the production of the lightest r-process elements generally should be decoupled from the heavier r-process elements. [ABSTRACT FROM AUTHOR]

We present a comprehensive abundance analysis of 20 elements for 16 new low-metallicity stars from the Chemical Abundances of Stars in the Halo (CASH) project. The abundances have been derived from both Hobby-Eberly Telescope High Resolution Spectrograph snapshot spectra (R ~ 15,000) and corresponding high-resolution (R ~ 35,000) Magellan Inamori Kyocera Echelle spectra. The stars span a metallicity range from [Fe/H] from -2.9 to -3.9, including four new stars with [Fe/H] < -3.7. We find four stars to be carbon-enhanced metal-poor (CEMP) stars, confirming the trend of increasing [C/Fe] abundance ratios with decreasing metallicity. Two of these objects can be classified as CEMP-no stars, adding to the growing number of these objects at [Fe/H] < -3. We also find four neutron-capture-enhanced stars in the sample, one of which has [Eu/Fe] of 0.8 with clear r-process signatures. These pilot sample stars are the most metal-poor ([Fe/H] ≾ -3.0) of the brightest stars included in CASH and are used to calibrate a newly developed, automated stellar parameter and abundance determination pipeline. This code will be used for the entire ~500 star CASH snapshot sample. We find that the pipeline results are statistically identical for snapshot spectra when compared to a traditional, manual analysis from a high-resolution spectrum. [ABSTRACT FROM AUTHOR]

We report the detection of several absorption lines of neutral phosphorus (P, Z = 15) in archival near-ultraviolet spectra obtained with the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope. We derive phosphorus abundances or interesting upper limits in 14 late-type stars with metallicities spanning –3.8 < [Fe/H] <–0.1. Previously, phosphorus had only been studied in Galactic stars with –1.0 < [Fe/H] <+0.3. Iron lines reveal abundance offsets between the optical and ultraviolet regions, and we discuss and apply a correction factor to account for this offset. In stars with [Fe/H] >–1.0, the [P/Fe] ratio decreases toward the solar value with increasing metallicity, in agreement with previous observational studies. In stars with [Fe/H] <–1.0, 〈 [P/Fe]〉 = +0.04 ± 0.10, which overlaps with the [P/Fe] ratios found in several high-redshift damped Lyman-α systems. This behavior hints at a primary origin in massive stars. [ABSTRACT FROM AUTHOR]

We use the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope to obtain new high-quality spectra covering the 1900 ⩽λ ⩽ 2360 Å wavelength range for two metal-poor stars, HD 108317 and HD 128279. We derive abundances of Cu II, Zn II, As I, Se I, Mo II, and Cd II, which have not been detected previously in either star. Abundances derived for Ge I, Te I, Os II, and Pt I confirm those derived from lines at longer wavelengths. We also derive upper limits from the non-detection of W II, Hg II, Pb II, and Bi I. The mean [As/Fe] ratio derived from these two stars and five others in the literature is unchanged over the metallicity range –2.8 < [Fe/H] <–0.6, 〈 [As/Fe]〉 = +0.28 ± 0.14 (σ = 0.36 dex). The mean [Se/Fe] ratio derived from these two stars and six others in the literature is also constant, 〈 [Se/Fe]〉 = +0.16 ± 0.09 (σ = 0.26 dex). The As and Se abundances are enhanced relative to a simple extrapolation of the iron-peak abundances to higher masses, suggesting that this mass region (75 ⩽A ⩽ 82) may be the point at which a different nucleosynthetic mechanism begins to dominate the quasi-equilibrium α-rich freezeout of the iron peak. 〈 [Cu II/Cu I]〉 = +0.56 ± 0.23 in HD 108317 and HD 128279, and we infer that lines of Cu I may not be formed in local thermodynamic equilibrium in these stars. The [Zn/Fe], [Mo/Fe], [Cd/Fe], and [Os/Fe] ratios are also derived from neutral and ionized species, and each ratio pair agrees within the mutual uncertainties, which range from 0.15 to 0.52 dex. [ABSTRACT FROM AUTHOR]

We present an elemental-abundance analysis, in the near-ultraviolet (NUV) spectral range, for the extremely metal-poor star BD+44°493 a ninth magnitude subgiant with [Fe/H] =–3.8 and enhanced carbon, based on data acquired with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope. This star is the brightest example of a class of objects that, unlike the great majority of carbon-enhanced metal-poor (CEMP) stars, does not exhibit over-abundances of heavy neutron-capture elements (CEMP-no). In this paper, we validate the abundance determinations for a number of species that were previously studied in the optical region, and obtain strong upper limits for beryllium and boron, as well as for neutron-capture elements from zirconium to platinum, many of which are not accessible from ground-based spectra. The boron upper limit we obtain for BD+44°493, log ε (B) <–0.70, the first such measurement for a CEMP star, is the lowest yet found for very and extremely metal-poor stars. In addition, we obtain even lower upper limits on the abundances of beryllium, log ε (Be) <–2.3, and lead, log ε (Pb) <–0.23 ([Pb/Fe] <+1.90), than those reported by previous analyses in the optical range. Taken together with the previously measured low abundance of lithium, the very low upper limits on Be and B suggest that BD+44°493 was formed at a very early time, and that it could well be a bona-fide second-generation star. Finally, the Pb upper limit strengthens the argument for non-s-process production of the heavy-element abundance patterns in CEMP-no stars. [ABSTRACT FROM AUTHOR]

The elements germanium (Ge, Z = 32), arsenic (As, Z = 33), and selenium (Se, Z = 34) span the transition from charged-particle or explosive synthesis of the iron-group elements to neutron-capture synthesis of heavier elements. Among these three elements, only the chemical evolution of germanium has been studied previously. Here we use archive observations made with the Space Telescope Imaging Spectrograph on board the Hubble Space Telescope and observations from several ground-based facilities to study the chemical enrichment histories of seven stars with metallicities –2.6 ⩽ [Fe/H] ⩽ –0.4. We perform a standard abundance analysis of germanium, arsenic, selenium, and several other elements produced by neutron-capture reactions. When combined with previous derivations of germanium abundances in metal-poor stars, our sample reveals an increase in the [Ge/Fe] ratios at higher metallicities. This could mark the onset of the weak s-process contribution to germanium. In contrast, the [As/Fe] and [Se/Fe] ratios remain roughly constant. These data do not directly indicate the origin of germanium, arsenic, and selenium at low metallicity, but they suggest that the weak and main components of the s-process are not likely sources. [ABSTRACT FROM AUTHOR]