1. Preparation of Ta2O5 nanoparticles by using cathode glow discharge electrolysis
- Author
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Quan-Fang Lu, Juan-Long Li, Jie Yu, Li-Juan Cui, Bo Wang, Xiao-Juan Ma, and Yan Feng
- Subjects
tantalum pentoxide (Ta2O5) ,nanoparticles (NPs) ,cathode glow discharge electrolysis (CGDE) ,preparation mechanism ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Chemical technology ,TP1-1185 - Abstract
Tantalum pentoxide nanoparticles (Ta _2 O _5 NPs) were fabricated by cathode glow discharge electrolysis (CGDE) generated between a needle-like platinum wire cathode and a tantalum foil anode in 6 g L ^−1 Na _2 SO _4 electrolyte solution containing 5 ml hydrofluoric acid (HF) and 0.075 g cetyltrimethyl ammonium bromide (CTAB). The chemical structure, composition and morphology of the obtained powder were analyzed by using XRD, FT-IR, SEM/EDS, XPS and UV–vis DRS. The results found that Ta _2 O _5 NPs with orthorhombic structure and wide band gap (3.6 eV) are successfully fabricated at 500 V discharge voltage in about 3 h. CTAB as a stabilizing agent can reduce the agglomeration due to forming CTA ^+ and attaching the surface of the synthetic products. A possible preparation mechanism of Ta _2 O _5 NPs is proposed. Firstly, the tantalum foil anode is oxidized to form a compact Ta _2 O _5 layer. Then, Ta _2 O _5 surface is etched to form soluble [TaF _7 ] ^2− complexes in the presence of HF. After that, soluble [TaF _7 ] ^2− complexes can react with H _2 O to form Ta(OH) _5 . Finally, Ta(OH) _5 is further converted to Ta _2 O _5 from plasma-liquid interface into solution.
- Published
- 2021
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