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We present an analysis of the first two XRISM/Resolve spectra of the well-known Seyfert-1.5 active galactic nucleus (AGN) in NGC 4151, obtained in 2023 December. Our work focuses on the nature of the narrow Fe K _α emission line at 6.4 keV, the strongest and most common X-ray line observed in AGN. The total line is found to consist of three components. Even the narrowest component of the line is resolved with evident Fe K _α _,1 (6.404 keV) and K _α _,2 (6.391 keV) contributions in a 2:1 flux ratio, fully consistent with neutral gas with negligible bulk velocity. Subject to the limitations of our models, the narrowest and intermediate-width components are consistent with emission from optically thin gas, suggesting that they arise in a disk atmosphere and/or wind. Modeling the three line components in terms of Keplerian broadening, they are readily associated with (1) the inner wall of the “torus,” (2) the innermost optical “broad-line region” (or “X-ray BLR”), and (3) a region with a radius of r ≃ 100 GM / c ^2 that may signal a warp in the accretion disk. Viable alternative explanations of the broadest component include a fast-wind component and/or scattering; however, we find evidence of variability in the narrow Fe K _α line complex on timescales consistent with small radii. The best-fit models are statistically superior to simple Voigt functions, but when fit with Voigt profiles the time-averaged lines are consistent with a projected velocity broadening of FWHM $\,=\,{1600}_{-200}^{+400}\,\mathrm{km}\,{{\rm{s}}}^{-1}$ . Overall, the resolution and sensitivity of XRISM show that the narrow Fe K line in AGN is an effective probe of all key parts of the accretion flow, as it is currently understood. We discuss the implications of these findings for our understanding of AGN accretion, future studies with XRISM, and X-ray-based black hole mass measurements.

We analyze features of the Fe K spectrum of the high-mass X-ray binary Cygnus X-3. The spectrum was obtained with the Chandra High Energy Transmission Grating Spectrometer in the third diffraction order. The increased energy resolution of the third order enables us to fully resolve the Fe xxv He α complex and the Fe xxvi Ly α lines. The emission-line spectrum shows the expected features of photoionization equilibrium, excited in the dense stellar wind of the companion star. We detect discrete emission from inner-shell transitions, in addition to absorption likely due to multiple unresolved transitions in lower ionization states. The emission-line intensity ratios observed in the range of the spectrum occupied by the Fe xxv n = 1–2 forbidden and intercombination lines suggest that there is a substantial contribution from resonantly scattered inner-shell emission from the Li- and Be-like ionization states. The Fe xxv forbidden and intercombination lines arise in the ionization zone closest to the compact object, and since they are not subject to radiative-transfer effects, we can use them in principle to constrain the radial velocity amplitude of the compact object. We infer that the results indicate a compact object mass of the order of the mass of the Wolf–Rayet companion star, but we note that the presence of resonantly scattered radiation from Li-like ions may complicate the interpretation of the He-like emission spectrum, and specifically of the radial velocity curve of the Fe xxv forbidden line.