Search

We investigate the finite-time performance of a quantum endoreversible Carnot engine cycle and its inverse operation — Carnot refrigeration cycle, employing a spin-1/2 system as the working substance. The thermal machine is alternatively driven by a hot boson bath of inverse temperature β h and a cold boson bath at inverse temperature β c (>β h). While for the engine model the hot bath is constructed to be squeezed, in the refrigeration cycle the cold bath is established to be squeezed, with squeezing parameter r. We obtain the analytical expressions for both efficiency and power in heat engines and for coefficient of performance and cooling rate in refrigerators. We find that, in the high-temperature limit, the efficiency at maximum power is bounded by the analytical value η + = 1 − sech ( 2 r ) ( 1 − η C ) , and the coefficient of performance at the maximum figure of merit is limited by ε + = sech ( 2 r ) ( 1 + ε C ) sech ( 2 r ) ( 1 + ε C ) − ε C − 1 , where η C = 1 – β h/β c and ε C = β h/(β c – β h) are the respective Carnot values of the engines and refrigerators. These analytical results are identical to those obtained from the Carnot engines based on harmonic systems, indicating that the efficiency at maximum power and coefficient at maximum figure of merit are independent of the working substance.

Finite-time cycle period for a quantum Otto machine implies that either an adiabatic stroke or an isochoric process proceeds in finite time duration. The quantum Otto refrigerators under consideration consist of two adiabatic strokes, where the system (isolated from the heat reservoir) undergoes finite-time unitary transformation, and two isochoric steps, where the system may not reach thermal equilibrium even at the respective ends of the two stages due to finite-time interaction intervals. Using two-time projective measurement method, we find the probability distribution functions of both coefficient of performance and cooling load, which are dependent on the time duration along each process. With these distributions we find the analytical expressions for the performance parameters as well as their fluctuations. We then numerically determine the performance and fluctuations for the refrigerator operating with a two-level system employed in a recent experimental implementation. Our results clarify the role of finite-time durations of four processes on the performance and fluctuations of the quantum Otto refrigerators.

We propose a quantum-mechanical Brayton engine model that works between two superposed states, employing a single particle confined in an arbitrary power-law trap as the working substance. Applying the superposition principle, we obtain the explicit expressions of the power and efficiency, and find that the efficiency at maximum power is bounded from above by the function: η+ = θ/(θ + 1), with θ being a potential-dependent exponent.

The performance in finite time of a quantum-mechanical Brayton engine cycle is discussed, without introduction of temperature. The engine model consists of two quantum isoenergetic and two quantum isobaric processes, and works with a single particle in a harmonic trap. Directly employing the finite-time thermodynamics, the efficiency at maximum power output is determined. Extending the harmonic trap to a power-law trap, we find that the efficiency at maximum power is independent of any parameter involved in the model, but depends on the confinement of the trapping potential.

An irreversible cycle model of a quantum heat engine with internal friction is established, which is composed of two adiabatic and two isomagnetic field processes. The working substance of the cycle consists of an ensemble of many non-interacting spin-1/2 systems. Based on a quantum master equation and semi-group approach, the general performance characteristics of the heat engine are investigated. The general expressions for several important parameters, such as the efficiency, power output, and rate of the entropy production, are derived. The performance of the cycle is optimized with respect to the temperatures of the working substance. By numerical solutions, the maximum power output and the corresponding parameters are calculated. The optimal regions of efficiency, temperatures of the working substance, and cycle period are determined. Moreover, the performance of the heat engine in the frictionless case is obtained, which is different from that in the friction case. Finally, the results obtained are generalized to the performance optimization of the heat engine working with spin-J systems.

The performance of the Ericsson refrigeration cycle using an ideal Fermi gas as the working substance, which is simply referred to as the Fermi Ericsson refrigeration cycle, is examined, based on the equation of state of an ideal Fermi gas. The inherent regenerative losses and the coefficient of performance (COP) of the cycle are calculated. Three special cases are discussed in detail. It is found that under the conditions of low and high temperatures, the COP of the cycle is only a function of temperature, while under other conditions, the COP of the cycle is not only a function of temperature, but also is dependent on the pressures and other parameters. The results obtained here may reveal the general performance characteristics of the Fermi Ericsson refrigeration cycle.

Based on quantum thermodynamic processes, we make a quantum-mechanical (QM) extension of the typical heat engine cycles, such as the Carnot, Brayton, Otto, Diesel cycles, etc., with no introduction of the concept of temperature. When these QM engine cycles are implemented by an ideal gas confined in an arbitrary power-law trap, a relation between the quantum adiabatic exponent and trap exponent is found. The differences and similarities between the efficiency of a given QM engine cycle and its classical counterpart are revealed and discussed.

We investigate the thermodynamic performance of a quantum-dot refrigerator consisting of a single orbital interacting quantum dot embedded between two electron reservoirs at different temperatures and chemical potentials. Based on the quantum master equation the expressions for the cooling power and the coefficient of performance are derived. The characteristic curves between the cooling power and the coefficient of performance are plotted, and the optimal regions of the performance parameters are determined. Moreover, the optimal performance parameters are calculated numerically. Finally, the influence of the Coulomb interaction and the temperature ratio on optimal performance parameters are discussed in detail. The results obtained here can provide some theoretical guidelines for the design and operation of the practical quantum-dot refrigerator. Our work is not restricted to the linear-response regime.

Particle hopping on a one-dimensional lattice driven by an external force in a periodic sawtooth potential and temperature field may act as a micro-Brownian refrigerator. In order to clarify the underlying physical pictures of the refrigerator, heat flows via both the potential energy and the kinetic energy of the particle are considered simultaneously. Based on the master equation describing the jump of the particle among the three states, expressions for the cooling rate and the coefficient of performance of the refrigerator are derived analytically. The general performance characteristic curves are plotted by numerical calculation. It is found that the characteristic curve between the cooling rate and the coefficient of performance is a loop-shaped one; the Brownian refrigerator is irreversible and its coefficient of performance is always less than the Carnot value. The influence of the temperature ratio of the heat reservoirs and the height of the sawtooth potential on the optimal performance characteristic parameters is analyzed. When heat flow via the kinetic energy of the particle is neglected, the characteristic curve between the cooling rate and the coefficient of performance is an open-shaped one. In this case, the Brownian refrigerator is reversible and its coefficient of performance reaches the Carnot value in the quasistatic limit.

A local stability analysis of an endoreversible Carnot refrigerator, working at the maximum objective function of the product of the cooling rate R and the coefficient of performance e, is presented. The endoreversible Carnot refrigerator consists of a reversible Carnot refrigerator that exchanges heat with the heat reservoirs TH through the thermal conductance α and with the cold reservoirs TL through the thermal conductance β. In addition, the working fluid has the same heat capacity C in the two isothermal branches of the cycle. By linearization and stability analysis, we find that the relaxation times are a function of α, β, the heat capacity C and τ=TL /TH; that the endoreversible Carnot refrigerator is stable for every value of α, β, C and τ; that after a perturbation, the system state exponentially decays to the steady state with either of two different relaxation times; that both relaxation times are proportional to α/2C; and that one of them is a monotonically increasing function τ and the other is almost independent of τ. Finally, the phase portraits for the trajectories after a small perturbation over the steady-state values of internal temperatures are presented.

An energy selective electron (ESE) refrigerator with heat leaks is established in a one-dimensional system. Based on the theory of electronic transport, the expressions of the heat flux into hot and cold electron reservoirs are derived. When the heat leaks between two electron reservoirs via phonons are taken into account, the cooling rate, coefficient of performance (COP) and input power are obtained. The performance characteristic curves such as the cooling rate versus the COP, the cooling rate and the COP versus the center position of the resonance energy level are plotted by numerical calculation. The influence of the center position and width of the resonance energy level on the performance of the ESE refrigerator is analyzed in detail. Lastly, the influence of heat leaks and average temperature on the performance of the ESE refrigerator is discussed. The results obtained here have theoretical significance for understanding the thermodynamic performance of the practical ESE refrigerator.