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We report the first detection of the metal-bearing molecules sodium sulfide and magnesium sulfide and the tentative detection of calcium monoxide in the interstellar medium toward the Galactic center molecular cloud G+0.693-0.027. The derived column densities are (5.0 ± 1.1) × 1010 cm−2, (6.0 ± 0.6) × 1010 cm−2, and (2.0 ± 0.5) × 1010 cm−2, respectively. This translates into fractional abundances with respect to H2 of (3.7 ± 1.0) × 10−13, (4.4 ± 0.8) × 10−13, and (1.5 ± 0.4) × 10−13, respectively. We have also searched for other Na-, Mg-, and Ca-bearing species toward this source but none of them have been detected and thus we provide upper limits for their abundances. We discuss the possible chemical routes involved in the formation of these molecules containing metals under interstellar conditions. Finally, we compare the ratio between sulfur-bearing and oxygen-bearing molecules with and without metals, finding that metal-bearing sulfur molecules are much more abundant than metal-bearing oxygen ones, in contrast with the general trend found in the ratios between other nonmetal-oxygen- and sulfur-bearing molecules. This further strengthens the idea that sulfur may be a little depleted in G+0.693-0.027 as a result of the low-velocity shocks present in this source sputtering large amounts of material from dust grains. [ABSTRACT FROM AUTHOR]

A quarter century after the detection of the last interstellar carboxylic acid, acetic acid (CH3COOH), we report the discovery of a new one, the cis-trans form of carbonic acid (HOCOOH), toward the Galactic center molecular cloud G+0.693–0.027. HOCOOH stands as the first interstellar molecule containing three oxygen atoms and the third carboxylic acid detected so far in the interstellar medium. Albeit the limited available laboratory measurements (up to 65 GHz), we have also directly identified several pairs of unblended lines in the astronomical data (between 75 and 120 GHz), which allowed us to slightly improve the set of spectroscopic constants. We derive a column density for cis-trans HOCOOH of N = (6.4 ± 0.4) × 1012 cm−2, which yields an abundance with respect to molecular H2 of 4.7 × 10−11. Meanwhile, the extremely low dipole moment (about 15 times lower) of the lower-energy conformer, cis-cis HOCOOH, precludes its detection. We obtain an upper limit to its abundance with respect to H2 of ≤1.2 × 10−9, which suggests that cis-cis HOCOOH might be fairly abundant in interstellar space, although it is nearly undetectable by radio astronomical observations. We derive a cis-cis / cis-trans ratio of ≤25, consistent with the smaller energy difference between both conformers compared with the relative stability of trans- and cis -formic acid. Finally, we compare the abundance of these acids in different astronomical environments, further suggesting a relationship between the chemical content found in the interstellar medium and the chemical composition of the minor bodies of the solar system, which could be inherited during the star formation process. [ABSTRACT FROM AUTHOR]

We present a study of narrow filaments toward a massive infrared dark cloud, NGC 6334S, using the Atacama Large Millimeter/submillimeter Array. Thirteen gas filaments are identified using the H13CO+ line, while a single continuum filament is revealed by the continuum emission. The filaments present a compact radial distribution with a median filament width of ∼0.04 pc, narrower than the previously proposed "quasi-universal" 0.1 pc filament width. The higher spatial resolution observations and higher density gas tracer tend to identify even narrower and lower mass filaments. The filament widths are roughly twice the size of embedded cores. The gas filaments are largely supported by thermal motions. The nonthermal motions are predominantly subsonic and transonic in both identified gas filaments and embedded cores, which may imply that stars are likely born in environments of low turbulence. A fraction of embedded objects show a narrower velocity dispersion compared with their corresponding natal filaments, which may indicate that turbulent dissipation is taking place in these embedded cores. The physical properties (mass, mass per unit length, gas kinematics, and width) of gas filaments are analogous to those of narrow filaments found in low- to high-mass star-forming regions. The more evolved sources are found to be farther away from the filaments, a situation that may have resulted from the relative motions between the young stellar objects and their natal filaments. [ABSTRACT FROM AUTHOR]

Observations carried out toward starless and prestellar cores have revealed that complex organic molecules are prevalent in these objects, but it is unclear what chemical processes are involved in their formation. Recently, it has been shown that complex organics are preferentially produced at an intermediate-density shell within the L1544 prestellar core at radial distances of ∼4000 au with respect to the core center. However, the spatial distribution of complex organics has only been inferred toward this core, and it remains unknown whether these species present a similar behavior in other cores. We report high-sensitivity observations carried out toward two positions in the L1498 starless core, the dust peak and a position located at a distance of ∼11,000 au from the center of the core where the emission of CH3OH peaks. Similarly to L1544, our observations reveal that small O-bearing molecules and N-bearing species are enhanced by factors of ∼4–14 toward the outer shell of L1498. However, unlike L1544, large O-bearing organics such as CH3CHO, CH3OCH3, or CH3OCHO are not detected within our sensitivity limits. For N-bearing organics, these species are more abundant toward the outer shell of the L1498 starless core than toward the one in L1544. We propose that the differences observed between O-bearing and N-bearing species in L1498 and L1544 are due to the different physical structure of these cores, which in turn is a consequence of their evolutionary stage, with L1498 being younger than L1544. [ABSTRACT FROM AUTHOR]

Infrared Dark Clouds (IRDCs) are cold, high mass surface density and high density structures, likely to be representative of the initial conditions for massive star and star cluster formation. CO emission from IRDCs has the potential to be useful for tracing their dynamics, but may be affected by depleted gas phase abundances due to freeze out onto dust grains. Here we analyze C18O J = 1 → 0 and J = 2 → 1 emission line data, taken with the Instituto de Radioastronomia Milimetrica 30 m telescope, of the highly filamentary IRDC G035.39.-0033. We derive the excitation temperature as a function of position and velocity, with typical values of ~7 K, and thus derive total mass surface densities, Sciso. assuming standard gas phase abundances and accounting for optical depth in the line, which can reach values of ~1. The mass surface densities reach values of ~0.07 g cm-2. We compare these results to the mass surface densities derived from mid-infrared extinction mapping, ΣSMF by Butler & Tan, which are expected to be insensitive to the dust temperatures in the cloud. With a significance of ≲10σ, we find ΣC18O/ΣSMF decreases by about a factor of five as Σ increases from ~0.02 to ~0.2 g cm-2, which we interpret as evidence for CO depletion. Several hundred solar masses are being affected, making this one of the most massive clouds in which CO depletion has been observed directly. We present a map of the depletion factor in the filament and discuss implications for the formation of the IRDC. [ABSTRACT FROM AUTHOR]

Filamentary structures are ubiquitously seen in the interstellar medium. The concentrated molecular mass in the filaments allows fragmentation to occur in a shorter timescale than the timescale of the global collapse. Such hierarchical fragmentation may further assist the dissipation of excessive angular momentum. It is crucial to resolve the morphology and the internal velocity structures of the molecular filaments observationally. We perform 0.″5-2.″5 angular resolution interferometric observations toward the nearly face-on OB cluster-forming region G33.92+0.11. Observations of various spectral lines, as well as the millimeter dust continuum emission, consistently trace several ∼1 pc scale, clumpy molecular arms. Some of the molecular arms geometrically merge to an inner 3.0 + 2.8– 1.4 × 103M☼, 0.6 pc scale central molecular clump, and may directly channel the molecular gas to the warm (∼50 K) molecular gas immediately surrounding the centrally embedded OB stars. The NH3 spectra suggest a medium turbulence line width of FWHM ≲ 2 km s–1 in the central molecular clump, implying a ≳10 times larger molecular mass than the virial mass. Feedbacks from shocks and the centrally embedded OB stars and localized (proto)stellar clusters likely play a key role in the heating of molecular gas and could lead to the observed chemical stratification. Although (proto)stellar feedbacks are already present, G33.92+0.11 chemically appears to be at an early evolutionary stage given by the low abundance limit of SO2 observed in this region. [ABSTRACT FROM AUTHOR]

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry at low temperatures has provided new insight into these processes predicting that COM formation depends strongly on parameters such as visual extinction and the level of CO freeze out. We report deep observations of COMs toward two positions in the L1544 pre-stellar core: the dense, highly-extinguished continuum peak with A V ≥30 mag within the inner 2700 au; and a low-density shell with average A V ~7.5-8 mag located at 4000 au from the core's center and bright in CH 3 OH. Our observations show that CH 3 O, CH 3 OCH 3 and CH 3 CHO are more abundant (by factors ~2-10) toward the low-density shell than toward the continuum peak. Other COMs such as CH 3 OCHO, c-C 3 H 2 O, HCCCHO, CH 2 CHCN and HCCNC show slight enhancements (by factors ≤3) but the associated uncertainties are large. This suggests that COMs are actively formed and already present in the low-density shells of pre-stellar cores. The modelling of the chemistry of O-bearing COMs in L1544 indicates that these species are enhanced in this shell because i) CO starts freezing out onto dust grains driving an active surface chemistry; ii) the visual extinction is sufficiently high to prevent the UV photo-dissociation of COMs by the external interstellar radiation field; and iii) the density is still moderate to prevent severe depletion of COMs onto grains.