1. Observations and emission constraints of trichlorofluoromethane (CFC-11) in southeastern China: first-year results from a new AGAGE station
- Author
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Yuyang Chen, Bo Yao, Jing Wu, Honglong Yang, Ao Ding, Song Liu, Xicheng Li, Simon O’Doherty, Juan Li, Yali Li, Haibo Yu, Wenli Wang, Liqu Chen, Xin Yang, Tzung-May Fu, Huizhong Shen, Jianhuai Ye, Chen Wang, and Lei Zhu
- Subjects
Montreal Protocol ,CFC-11 ,emission ,southeastern China ,inverse modeling ,interspecies correlation method ,Environmental technology. Sanitary engineering ,TD1-1066 ,Environmental sciences ,GE1-350 ,Science ,Physics ,QC1-999 - Abstract
The recovery of the ozone layer relies on decreasing atmospheric mixing ratios of ozone-depleting substances (ODSs), including chlorofluorocarbons (CFCs). A significant decline in the mixing ratio of trichlorofluoromethane (CFC-11 or $\mathrm{CCl_3F}$ ), the second most abundant CFC, has been observed since the mid-1990s. However, a slowdown in the decline after 2012 indicates a rise in emissions, particularly in Eastern Asia. Ground-based observations are lacking in southeastern China, limiting a thorough evaluation of CFC-11 levels and emissions in this region. A new Advanced Global Atmospheric Gases Experiment background station was established at Xichong (XCG), Shenzhen, China, to provide high-frequency continuous in situ observations. The annual mean CFC-11 mixing ratio, recorded from May 2022 to April 2023, is 221.64 ± 2.29 ppt. When compared with a monthly (MHD) or daily (MLO) observation, this value is found to be 0.45% to 5.36% higher than the northern hemispheric background. With the inverse modeling and interspecies correlation method, we estimate CFC-11 emissions in southeastern China between 1.23 ± 0.25 Gg yr ^−1 and 1.58 ± 0.21 Gg yr ^−1 , in line with the bottom-up estimation of 1.50 Gg yr ^−1 . Results indicate that CFC-11 emissions in the Pearl River Delta region have returned to levels before 2010, aligning with regional and global trends. Observations from XCG would compensate for the deficiency of CFC-11 measurements in southeastern China, paving the road for ODS studies in this region and beyond.
- Published
- 2024
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