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Several astronomical observations have shown that the ortho/para ratio (OPR) of H2 can differ from the expected statistical value of 3 or the local thermodynamic equilibrium (LTE) value at the gas or dust temperature. It is thus important to know the OPR of H2 newly formed on dust grain surfaces, in order to clarify the dependence of the observed OPR in space on the formation process. Using an experimental setup designed to mimic interstellar medium environments, we measured the OPR of H2 and D2 formed on the surface of porous amorphous water ice held at 10 K. We report for the first time the OPR value for newly formed D2, consistent with the expected LTE value at the high-temperature limit found by previous theoretical and experimental works on the determination of the OPR upon H2 formation on surfaces at low temperature. [ABSTRACT FROM AUTHOR]