1. Electron trapping at SiO2/4H-SiC interface probed by transient capacitance measurements and atomic resolution chemical analysis
- Author
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Fabrizio Roccaforte, Giuseppe Nicotra, Ioannis Deretzis, Antonino La Magna, Patrick Fiorenza, Filippo Giannazzo, Corrado Spinella, Ferdinando Iucolano, Corrado Bongiorno, and Mario Saggio
- Subjects
EELS ,Materials science ,Oxide ,FOS: Physical sciences ,transient capacitance ,near interface oxide traps ,Bioengineering ,Applied Physics (physics.app-ph) ,02 engineering and technology ,7. Clean energy ,01 natural sciences ,Molecular physics ,SiO2/4H-SiC interface ,chemistry.chemical_compound ,Gate oxide ,0103 physical sciences ,Scanning transmission electron microscopy ,Silicon carbide ,General Materials Science ,Electrical and Electronic Engineering ,Quantum tunnelling ,010302 applied physics ,Condensed Matter - Materials Science ,business.industry ,Mechanical Engineering ,Electron energy loss spectroscopy ,Materials Science (cond-mat.mtrl-sci) ,Physics - Applied Physics ,General Chemistry ,STEM ,021001 nanoscience & nanotechnology ,Semiconductor ,chemistry ,Mechanics of Materials ,Field-effect transistor ,0210 nano-technology ,business - Abstract
Studying the electrical and structural properties of the interface of the gate oxide (SiO2) with silicon carbide (4H-SiC) is a fundamental topic, with important implications for understanding and optimising the performances of metal-oxide-semiconductor field effect transistor (MOSFETs). In this paper, near interface oxide traps (NIOTs) in lateral 4H-SiC MOSFETs were investigated combining transient gate capacitance measurements (C-t) and state of the art scanning transmission electron microscopy in electron energy loss spectroscopy (STEM-EELS) with sub-nm resolution. The C-t measurements as a function of temperature indicated that the effective NIOTs discharge time is temperature independent and electrons from NIOTs are emitted toward the semiconductor via-tunnelling. The NIOTs discharge time was modelled also taking into account the interface state density in a tunnelling relaxation model and it allowed us to locate traps within a tunnelling distance of up to 1.3 nm from the SiO2/4H-SiC interface. On the other hand, sub-nm resolution STEM-EELS revealed the presence of a non-abrupt (NA) SiO2/4H-SiC interface. The NA interface shows the re-arrangement of the carbon atoms in a sub-stoichiometric SiOx matrix. A mixed sp(2)/sp(3) carbon hybridization in the NA interface region suggests that the interfacial carbon atoms have lost their tetrahedral SiC coordination.
- Published
- 2018
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