1. Scaling at the rod-to-flexible chain crossover in the stiff limit
- Author
-
D Atkatz, J. W. Halley, and Hisao Nakanishi
- Subjects
Gaussian ,Monte Carlo method ,Crossover ,General Physics and Astronomy ,Statistical and Nonlinear Physics ,Renormalization group ,Universality (dynamical systems) ,symbols.namesake ,Excluded volume ,symbols ,Statistical physics ,Scaling ,Mathematical Physics ,Self-avoiding walk ,Mathematics - Abstract
The authors critically examine the present theoretical understanding of the conformational rod-to-flexible chain crossover of a linear chain polymer in dilute solution with a good solvent. There is good evidence for weak universality in this crossover while strong universality seems unlikely from available evidence. In addition, this system should exhibit a second crossover from a Gaussian to an excluded volume. They present a scaling hypothesis for the behaviour of this second crossover and compare with the initial results of numerical simulations and with the experiment of Murakami et al. (1980).
- Published
- 1990