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Binary neutron star (NS) mergers have been expected to synthesize r-process elements and emit radioactively powered radiation, called kilonovae. Although r-process nucleosynthesis was confirmed by the observations of GW170817/AT2017gfo, no trace of individual elements has been identified except for strontium. In this paper, we perform systematic calculations of line strength for bound–bound transitions and radiative transfer simulations in NS merger ejecta toward element identification in kilonova spectra. We find that Sr ii triplet lines appear in the spectrum of a lanthanide-poor model, which is consistent with the absorption feature observed in GW170817/AT2017gfo. The synthetic spectrum also shows the strong Ca ii triplet lines. This is natural because Ca and Sr are coproduced in the material with relatively high electron fraction and their ions have similar atomic structures with only one s-electron in the outermost shell. The line strength, however, highly depends on the abundance distribution and temperature in the ejecta. For our lanthanide-rich model, the spectra show the features of doubly ionized heavy elements, such as Ce, Tb, and Th. Our results suggest that the line-forming region of GW170817/AT2017gfo was lanthanide-poor. We show that the Sr ii and Ca ii lines can be used as a probe of physical conditions in NS merger ejecta. Absence of the Ca ii line features in GW170817/AT2017gfo implies that the Ca/Sr ratio is <0.002 in mass fraction, which is consistent with nucleosynthesis for electron fraction ≥0.40 and entropy per nucleon (in units of Boltzmann constant) ≥25. [ABSTRACT FROM AUTHOR]

Hexagonal boron nitride (hBN) has become a prominent material for nanophotonic and quantum technology studies. Its wide bandgap can accommodate room temperature radiative optical transitions originating from defect states in different atomic structures. Here, we report the engineering of visible defects in chemical vapor deposited monolayer hBN irradiated by femtosecond pulses (0.1–0.5 W) at room temperature. Photoluminescence and transient photoluminescence measurements reveal the presence of a sharp emission at 630 nm with a time constant of approximately 3 ns randomly distributed around the irradiated region. We imaged the distribution of the photogenerated electrons by time-resolved photoemission electron microscopy in the picosecond and nanosecond timescales with 100 nm spatial resolution. We determined the precise location of the defects within the region of interest corresponding to an optical transition between 1.95 eV and 3.90 eV above the valence band maximum of hBN, ascribed to NBVN color centers. [ABSTRACT FROM AUTHOR]

Spectroscopy based on Stark broadening is a very efficient and successful method for diagnosing the physical conditions in laboratory or astrophysical plasmas. The studies are often focused on the lines of hydrogen or hydrogen-like ions due to the simple atomic structure. However, the Stark modeling may be difficult even for one-electron systems, in particular when radiative transitions with highly-degenerate Rydberg states are considered. Besides, the computations may become challenging for the modeling of line shapes in an optically thick plasma and accounting for non-local thermodynamical equilibrium (non-LTE) effects on the state populations. The statistical approach is a powerful technique which can be used to simplify complex coupled problems by replacing the numerous levels or lines by a single continuous distribution characterized by a reduced number of exact moments: area, center-of-gravity, variance, etc. In this paper, we study various statistical properties of a hydrogenic atom broadened by Stark effect. First, we derive the moments of level energies accounting for linear and quadratic Stark effects, electric-quadrupole and fine structure corrections. The resulting formulas allows one to estimate the relative importance of these corrections on the energies. We then derive the moments of the strength-weighted line energies for the Lyman and Balmer series in the framework of Linear-Stark effect. The moments are then used in a Gram–Charlier expansion series to represent the line shape, the resolution of the spectrum being controlled by the order at which the series is truncated. We show that the line shape of the transition can be expressed using universal functions of n and , independent of the atomic number and of the field intensity. This allows for fast Stark broadening calculations which can be used in more complex simulations (in opacity or emissivity codes, for radiative transfer simulations or non-LTE models). [ABSTRACT FROM AUTHOR]

The (2s1/22p1/222p3/22)5/2-(2s22p1/222p3/2)3/2 x-ray transition in the N-like 208Pb75+was observed using the Tokyo electron beam ion trap at the University of Electro-Communications. The Pb spectral line energies were measured relative to the Lyman-a lines of the H-like S and the 1s4p 1P1-1s2 1S0 transition in the He-like P. In the present work, the line from the N-like lead ions is analysed and the transition energy is determined to be 2662.98 +- 0.12 eV. We also calculate the transition energies of the (2s1/22p1/222p3/22)5/2-(2s22p1/222p3/2)3/2 lines in N-like ions from Sn (Z = 50) through U (Z = 92) with the general relativistic atomic structure package Vanderbilt University (GRASPVU) package which is based on the multiconfiguration Dirac-Fock (MCDF) method. The calculations are compared with the available experimental results. [ABSTRACT FROM AUTHOR]

Two-electron-one-photon (TEOP) M1 and E2 transition energies, line strengths and transition probabilities between the states of the 2p3 and 2s22p odd configurations for B-like ions with 18 [?] Z [?] 92 have been calculated using the GRASP2K package based on the multiconfiguration Dirac-Hartree-Fock (MCDHF) method. Employing active-space techniques to expand the configuration list, we have systematically considered the valence, core-valence and core-core electron correlation effects. Breit interaction and quantum electrodynamical (QED) effects were also included to correct atomic state wavefunctions and the corresponding energies. Influences of electron correlation, Breit interaction and QED effects on transition energies and line strengths of the TEOP M1 and E2 transitions were analysed in detail. The present results were also compared with other theoretical and experimental values. [ABSTRACT FROM AUTHOR]