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Start Over Author "Kuniyo Yamada" Publisher international union of crystallography (iucr)
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1. (3S,2′S,5′S,6′R,8′R,10′R)-3-Hydroxy-4-(5′-hydroxy-10′-hydroxymethyl-5′-methyl-1′,7′,9′-trioxadispiro[5.1.5.2]pentadec-2′-yl)but-1-ene

Author

Tetsuzo Ito, Masanobu Midorikawa, Takeshi Noda, and Kuniyo Yamada

Subjects
Hydrogen bond, Chemistry, General Materials Science, General Chemistry, Condensed Matter Physics, Medicinal chemistry, Ene reaction
Abstract

The configurations of four of the six chiral centers in the title compound, C18H30O6, are the same as those in pinnatoxin A, while one is inverted. The configuration of the sixth chiral center, which has no equivalent in pinnatoxin A, has also been determined. The overall mol­ecular structure is stabilized by intra­molecular O—H⋯O hydrogen bonds.

Published
2006

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