1. Crystal structure and dielectric properties of Ca0.85Nd0.1TiO3 - LnAIO3 ceramics
- Author
-
Jun-Mo Yang, H.S. Shin, N.I. Zahari, Dong Ho Kang, Eung Soo Kim, and H. Ohsato
- Subjects
Ceramics ,Materials science ,Valence (chemistry) ,Ionic radius ,Acoustics and Ultrasonics ,Rietveld refinement ,Electric Conductivity ,Molecular Conformation ,Analytical chemistry ,Membranes, Artificial ,Crystal structure ,Dielectric ,Materials Testing ,Grain boundary ,Electrical and Electronic Engineering ,Crystallization ,High-resolution transmission electron microscopy ,Instrumentation ,Solid solution - Abstract
The microwave dielectric properties of Ca(0.85)Nd(0.1)TiO(3) - LnAlO(3) (Ln = Sm, Gd, Dy, Er) ceramics are investigated in this paper. The structural characteristics of the specimens were evaluated by Rietveld refinement of Xray diffraction (XRD) patterns and high-resolution transmission electron microscopy (HRTEM). Solid solution limits were dependent on the ionic radius of Ln(3+) ions. With the decrease of the ionic radius of the Ln(3+) ions, the thermal stability of the resonant frequency decreases. This can be attributed to the increased level of oxygen octahedral distortion caused by the increase in the B-site bond valence in the ABO(3) perovskite structure. The dielectric constant (K) and the quality factor (Qf) of the specimens were dependent on the polarizability and grain size, respectively.
- Published
- 2008
- Full Text
- View/download PDF