Search

Three-dimensional parts with a wide range of properties were synthesized by combining together self-propagating high-temperature synthesis (SHS) and selective laser sintering (SLS). Different powder mixtures were investigated for producing piezoceramics, ferrites, and the high-temperature superconductor. Changing the structure, volume fraction, phase, and pore-distribution within the composite optimized the physical properties. The optimum regime for laser synthesis and some of their associated electro-physical properties were determined by changing the laser parameters, as well as, by conducting the reactions in an applied dc magnetic field. The mechanical properties and the ability to influence the Shape Memory Effect in synthesized porous NiTi were also studied. Stress-strain, X-ray, scanning electronic microscopy (SEM), and energy dispersive analysis by X-rays (EDAX) characterization data were shown to be dependent on laser irradiation parameters. A comparative study of bone-integration with porous NiTi implants was conducted.

Fullerene hydrides of C60H18, C60H36 and C70H36 are studied by using IR, 1H and 13C NMR, X-ray photoelectron and electron energy loss spectroscopies, and magnetochemistry. The comparison of IR and solid state 1H and 13C NMR data for C60H36 with the theoretical ones allows the suggestion that fullerene hydride has a T symmetric structure and contains 4 isolated benzenoid rings located at tetrahedral positions on the surface of a closed skeleton of the molecule. The EELS revealed that the transition from fullerene to the hydride is accompanied by the decrease of the density of valence electrons. Magnetization measurements showed C60H36 to be a ferromagnet. The hydrogenated fullerenes were prepared by transfer hydrogenation procedures involving 9,10-dihydroanthracene. The compositions of the hydrides are determined by field desorption mass-spectral analysis.