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3 results on '"Vito Capriati"'

1. The influence of varying reaction conditions on the coordination behavior of the phosphonoformate anion

Author

M. Egenhöfer, Sara Barile, Konstantin Karaghiosoff, and Vito Capriati

Subjects
Inorganic Chemistry, Foscarnet, Reaction conditions, Chemistry, Organic Chemistry, medicine, Pharmaceutical sciences, Biochemistry, Combinatorial chemistry, medicine.drug
Abstract

In medical and pharmaceutical science phosphonic acids and phosphonates play an important role with regard to their wide application in various drugs as medicines against osteoporosis or antiviral ...

Published
2020
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2. Versatile coordination chemistry of the phosphonoformate anion

Author

Sara Barile, Maria Colamonico, Vito Capriati, Jörn Martens, Roberta Cutolo, Konstantin Karaghiosoff, and Pasquale Mastropierro

Subjects
chemistry.chemical_classification, fungi, Organic Chemistry, food and beverages, Biochemistry, Medicinal chemistry, Phosphonate, Ion, Coordination complex, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Group (periodic table), Moiety
Abstract

Phosphonoformate – the simplest member of the group of phosphono-carboxylic-acids containing a phosphonic as well as a directly bonded carboxylic moiety - can be regarded as a structural mimic of t...

Published
2018
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3. On the Configurational Stability of α-Lithiated Sulfurated Styrene Oxides: Synthetic and Mechanistic Aspects

Author

Mariangela Dammacco, Antonio Salomone, Filippo Maria Perna, Vito Capriati, Interuniversitario Nazionale, Saverio Florio, Capriati, Vito, Dammacco, Mariangela, Florio, Saverio, Perna, Filippo Maria, and Salomone, Antonio

Subjects
Inorganic Chemistry, chemistry.chemical_compound, Silicon, chemistry, Organic Chemistry, Oxide, chemistry.chemical_element, Organic chemistry, Configurational stability, Biochemistry, Racemization, Sulfur, Styrene
Abstract

The configurational stability of some sulfurated styrene oxides has been inves- tigated. Chemical studies have shown that in THF at 157 K α-lithiated ortho- and para- phenylthiostyrene oxides are configurationally unstable and undergo a fast racemization on the time scale of the reaction, whereas α-lithiated meta-phenylthiostyrene oxide retains its stereochemical integrity for at least 60 min. The deprotonation-trapping methodology has also been employed for the preparation of a sulfurated β-aminoalcohol effective for the fight against phytopathogenic fungi. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

Published
2011
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