1. Synthesis and characterization of stannacyclododecane-yl-dithiocarbamates
- Author
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Patricia García y García, Marcela López-Cardoso, Gabriela Vargas-Pineda, Raymundo Cea-Olivares, and Perla Román-Bravo
- Subjects
chemistry.chemical_classification ,Denticity ,chemistry.chemical_element ,Medicinal chemistry ,Pyrrolidine ,Characterization (materials science) ,chemistry.chemical_compound ,Thiomorpholine ,chemistry ,Morpholine ,Materials Chemistry ,Organic chemistry ,Piperidine ,Physical and Theoretical Chemistry ,Tin ,Dithiocarbamate - Abstract
Thirteen new stannacyclododecane dithiocarbamate complexes have been prepared by reacting 12-chloro-12-n-butyl-1,11-dioxa-4,8-dithia-12-stannacyclododecane (1) and 12-chloro-12-n-butyl-1,4,8,11-tetrathia-12-stannacyclododecane (2) with pyrrolidine-, morpholine-, thiomorpholine-, piperidine-, piperazinebis-, and 3-pyrroline-carbodithioates, respectively, as well as with diethyl-dithiocarbamate. All complexes were characterized by elemental analyses, IR, EI-MS, and NMR (1H, 13C, and 119Sn) studies. The spectroscopic data suggest the replacement of the chlorides by the corresponding dithiocarbamates with monodentate coordination, leading to six-coordinate tin atoms in all the cases.
- Published
- 2011
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