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1. Resolution and Characterization of 2,2'-Bis(Diphenylphosphino)-1,1'-Bibenzimidazole (BIMIP): the First Chiral Atropisomeric Diphosphine Ligand with Hindered Rotation around a N-N Bond

Author

Patrizia Antognazza, Franco Sannicolò, Tullio Pilati, Tiziana Benincori, and Sabrina Mazzoli

Subjects
Inorganic Chemistry, Crystallography, Enantiopure drug, Chemistry, Stereochemistry, Ligand, Organic Chemistry, Resolution (electron density), Enantioselective synthesis, Biochemistry, Stoichiometry, Kinetic resolution
Abstract

2,2'-Bis(diphenylphosphino)-1,1'-bibenzimidazole BIMIP) was resolved in an enantiomerically pure state through a kinetic resolution process effected by complexation of the racemate with half of the stoichiometric amount of a chiral aminopalladium complex. The enantiopure diphosphine was fully characterized by X-ray diffractometric analysis.

Published
1999
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