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This paper is concerned with the controllability of quantum systems in the case where the standard dipolar approximation, involving the permanent dipole moment of the system, has to be corrected by a so-called polarizability term, involving the field induced dipole moment. Sufficient conditions for controllability between eigenstates of the free Hamiltonian are derived and control laws are explicitly given. As an illustration, the results are applied to the planar rotation of the HCN molecule. [ABSTRACT FROM PUBLISHER]

We show the approximate rotational controllability of a polar linear molecule by means of three nonresonant linear polarized laser fields. The result is based on a general approximate controllability result for the bilinear Schrödinger equation, with wavefunction varying in the unit sphere of an infinite-dimensional Hilbert space and with several control potentials, under the assumption that the internal Hamiltonian has discrete spectrum. [ABSTRACT FROM PUBLISHER]

This note presents an example of bilinear conservative system in an infinite dimensional Hilbert space for which approximate controllability in the Hilbert unit sphere holds for arbitrary small times. This situation is in contrast with the finite dimensional case and is due to the unboundedness of the drift operator. [ABSTRACT FROM PUBLISHER]

In this paper we study the error in the approximate simultaneous controllability of the bilinear Schro¨dinger equation. We provide estimates based on a tracking algorithm for general bilinear quantum systems and on the study of the finite dimensional Galerkin approximations for a particular class of quantum systems, weakly-coupled systems. We then present two physical examples: the perturbed quantum harmonic oscillator and the infinite potential well. [ABSTRACT FROM PUBLISHER]

We provide bounds on the error between dynamics of an infinite dimensional bilinear Schro¨dinger equation and of its finite dimensional Galerkin approximations. Standard averaging methods are used on the finite dimensional approximations to obtain constructive controllability results. As an illustration, the methods are applied on a model of a 2D rotating molecule. [ABSTRACT FROM PUBLISHER]