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Ascertaining water quality for irrigational use by employing conventional methods is often time taking and expensive due to the determination of multiple parameters needed, especially in developing countries. Therefore, constructing precise and adequate models may be beneficial in resolving this problem in agricultural water management to determine the suitable water quality classes for optimal crop yield production. To achieve this objective, five machine learning (ML) models, namely linear regression (LR), random subspace (RSS), additive regression (AR), reduced error pruning tree (REPTree), and support vector machine (SVM), have been developed and tested for predicting of six irrigation water quality (IWQ) indices such as sodium adsorption ratio (SAR), percent sodium (%Na), permeability index (PI), Kelly ratio (KR), soluble sodium percentage (SSP), and magnesium hazards (MH) in groundwater of the Nand Samand catchment of Rajasthan. The accuracy of these models was determined serially using the mean squared error (MSE), correlation coefficients (r), mean absolute error (MAE), and root mean square error (RMSE). The SVM model showed the best-fit model for all irrigation indices during testing, that is, RMSE: 0.0662, 4.0568, 3.0168, 0.1113, 3.7046, and 5.1066; r: 0.9364, 0.9618, 0.9588, 0.9819, 0.9547, and 0.8903; MSE: 0.004381, 16.45781, 9.101218, 0.012383, 13.72447, and 26.078; MAE: 0.042, 3.1999, 2.3584, 0.0726, 2.9603, and 4.0582 for KR, MH, SSP, SAR, %Na, and PI, respectively. The KR and SAR values were predicted accurately by the SVM model in comparison to the observed values. As a result, machine learning algorithms can improve irrigation water quality characteristics, which is critical for farmers and crop management in various irrigation procedures. Additionally, the findings of this research suggest that ML models are effective tools for reliably predicting groundwater quality using general water quality parameters that may be acquired directly on periodical basis. Assessment of water quality indices may also help in deriving optimal strategies to utilise inferior quality water conjunctively with fresh water resources in the water-limited areas. [ABSTRACT FROM AUTHOR]