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External gas-assisted injection molding (EGAIM) has been used to reduce the sink marks of amorphous polymer products, but that of crystalline polymer products has not yet been reported. EGAIM of a crystalline polymer product was investigated in this study, and the influences of process parameters on the sink marks were discussed based on experiments. An isotactic polypropylene (iPP) product was fabricated by EGAIM under different process conditions. A uniform design was applied as an experimental design to investigate the influences of the process parameters on the sink marks. A regression equation was established to describe the quantitative relationship between the important parameters and sink marks in which a data-processing method was applied to determine the optimal value of Fα at significant level α to reduce the possibility of omission of some important parameters. The results show that EGAIM was effective in reducing the sink marks in these iPP products, and the most important parameters were the cooling time, gas pressure, and gas time. This study also provides the quantitative relationship between the important parameters and sink marks as reference for the research of EGAIM on crystalline polymer.

The microstructure of a molded product considerably influences its macroscopic properties. In this study, the influence of molding process on microstructure, tensile property, and surface quality was explored on the glass fiber-reinforced polypropylene (GFRPP) parts molded by rapid heat cycle molding (RHCM) and conversion injection molding (CIM). Tensile strength and surface gloss were chosen to measure macroscopic properties of the molded parts. The microstructure including multilayer, fiber orientation, crystallinity, and fiber-matrix bonding strength were analyzed by simulations, scanning electron microscopy, wide-angle X-ray diffraction, and dynamic mechanical analysis. The relationship between the macroscopic properties and microstructure of the RHCM samples was also discussed. The results indicate that as the mold cavity surface temperature increases, the tensile strength increases firstly and decreases thereafter. The tensile strength of RHCM parts reached the maximum at the mold heating temperature of 60°C. It is also observed that the surface gloss of the sample increases as the mold cavity surface temperature rises, and the increase of surface gloss decreases distinctly with the mold heating temperature higher than 90°C.

Temperature greatly influences the mechanical response of acrylonitrile butadiene styrene (ABS). The tensile behavior of ABS was explored in this study. The tensile experiments were conducted at a wide range of temperatures (from 40°C to 130°C). A model was established to reveal the quantitative relationship between temperature and tensile behavior of ABS. The results of tensile experiments showed that tensile behavior of ABS exhibited glassy state and high-elastics state. The model was also divided into two parts that rely on the boundary of glass transition temperature, in which the parameters of the model were calculated by the fitting method. The model predictions showed a good agreement with the results of the experimental tensile test. This study provides the quantitative relationship between temperature and tensile behavior of ABS, which saves time and experimental costs.