1. Direct observation of Jahn-Teller critical dynamics at a charge-order Verwey transition
- Author
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Gastaldo, Vinícius Pascotto, Rao, Mala N., Bosak, Alexey, D'Astuto, Matteo, Prodi, Andrea, Verseils, Marine, Klein, Yannick, Bellin, Christophe, Paolasini, Luigi, de Oliveira, Adilson, Gilioli, Edmondo, Chaplot, Samrath Lal, Gauzzi, Andrea, Pascotto Gastaldo, Vinícius, Rao, Mala, Chaplot, Samrath, Departamento de Fisica, Universidade Federal de São Carlos, Rodovia Washington Luis, km 235 - SP-310, 13565-905 São Carlos, SP, Brazil, Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Bhabha Atomic Research Centre (BARC), Government of India, Department of Atomic Energy, European Synchroton Radiation Facility [Grenoble] (ESRF), Magnétisme et Supraconductivité (MagSup), Institut Néel (NEEL), Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), Istituto dei Materiali per l'Elettronica ed il Magnetismo [Genova] (IMEM-CNR), Consiglio Nazionale delle Ricerche (CNR), Universidade Federal de São Carlos [São Carlos] (UFSCar), Magnétisme et Supraconductivité (NEEL - MagSup), and National Research Council of Italy | Consiglio Nazionale delle Ricerche (CNR)
- Subjects
Strongly Correlated Electrons (cond-mat.str-el) ,Jahn-Teller effect ,FOS: Physical sciences ,02 engineering and technology ,Charge order ,021001 nanoscience & nanotechnology ,01 natural sciences ,Condensed Matter - Strongly Correlated Electrons ,0103 physical sciences ,Condensed Matter::Strongly Correlated Electrons ,[PHYS.COND.CM-SCE]Physics [physics]/Condensed Matter [cond-mat]/Strongly Correlated Electrons [cond-mat.str-el] ,[PHYS.COND]Physics [physics]/Condensed Matter [cond-mat] ,010306 general physics ,0210 nano-technology - Abstract
By means of diffuse and inelastic x-ray scattering (DS,IXS), we probe directly the charge-ordering (CO) dynamics in the Verwey system (NaMn$_3$)Mn$_4$O$_{12}$, where a peculiar quadruple perovskite structure with no oxygen disorder stabilizes a nearly full Mn$^{3+}$/Mn$^{4+}$ static charge order at $T_{\rm CO}$=175 K concomitant to a commensurate structural modulation with propagation vector ${\bf q}_{\rm CO}=(\frac{1}{2},\frac{1}{2},0)$. At $T_{\rm CO}$, the IXS spectra unveil a softening of a 35.3 meV phonon at ${\bf q}_{\rm CO}$. Lattice dynamical calculations enable us to attribute this soft phonon to a A$_g$ mode whose polarization matches the Jahn-Teller-like distortion pattern of the structural modulation. This result demonstrates that the Jahn-Teller instability is the driving force of the CO Verwey transition in (NaMn$_3$)Mn$_4$O$_{12}$, thus elucidating a long-standing controversy regarding the mechanism of this transition observed in other mixed-valence systems like magnetite.
- Published
- 2021
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