1. Point defect distribution in high-mobility conductive SrTiO(3) crystals
- Author
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A. Barthélémy, C. Carrétéro, Gervasi Herranz, Karim Bouzehouane, Amir Hamzić, Mario Basletić, Franck Fortuna, Eric Jacquet, A. Gentils, Emil Tafra, Manuel Bibes, O. Copie, Centre de Spectrométrie Nucléaire et de Spectrométrie de Masse (CSNSM), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI), Université d'Orléans (UO)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Unité mixte de physique CNRS/Thales (UMPhy CNRS/THALES), Centre National de la Recherche Scientifique (CNRS)-THALES, and Institut de Ciencia de materials de barcelone
- Subjects
defect clusters ,Materials science ,AR+-IRRADIATED SRTIO3 ,STO ,positron annihilation ,point defects ,ion radiation effects ,Oxide ,BEAM ,02 engineering and technology ,Substrate (electronics) ,LIFETIME ,STRONTIUM-TITANATE ,01 natural sciences ,[SPI.MAT]Engineering Sciences [physics]/Materials ,chemistry.chemical_compound ,POSITRON-ANNIHILATION ,Vacancy defect ,0103 physical sciences ,Thin film ,010306 general physics ,Quantum well ,Condensed matter physics ,Doping ,Positron annihilation ,Point defects ,Defect clusters ,Ion radiation effects ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Crystallographic defect ,NATURAL SCIENCES. Physics ,Electronic, Optical and Magnetic Materials ,PRIRODNE ZNANOSTI. Fizika ,INTERFACE ,ROOM-TEMPERATURE ,chemistry ,Quantum dot ,OXYGEN VACANCIES ,[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] ,ELECTRON ,0210 nano-technology ,RESISTANCE - Abstract
Among perovskites, SrTiO_3 (STO) is one of the most widely studied oxides because of its potential in many applications in oxide electronics. Recently it has been shown that irradiated STO surfaces exhibit high-mobility conduction in contrast to the insulating behaviour of stoichiometric STO single crystals. The possibility of modifying the properties of solids just by etching their surfaces opens up new perspectives for engineering of the functional properties of materials. But for that purpose, a deeper knowledge of damage extension and its consequences on the physical properties is highly desired. Bearing this in mind, we have characterized the spatial distribution and the nature of vacancy defects in insulating as-received as well as in ion-irradiated STO substrates exhibiting high-mobility conduction. Because tiny amounts of oxygen vacancies can trigger substantial modifications of the physical properties of STO, positron annihilation spectroscopy techniques appear as an appropriate characterization tool. We show that Ti vacancies are native defects homogeneously distributed in as-received substrates. In contrast, the dominant vacancy defects consist of non-homogeneous distributions of cation-oxygen vacancy complexes in ion-etched substrates. Their spatial extension is tuned over a few microns in ionetched samples. Our results shed light on the transport mechanisms of conductive STO crystals and on strategies for defect-engineered oxide quantum wells, wires and dots.
- Published
- 2010
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