1. Eco-friendly Optical Adhesives Based onVegetable Oil Thermosets
- Author
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Alice Mija, Norio Murata, Arisa Hagiwara, Guillaume Falco, Seiko Mitachi, Daiki Kojima, Institut de Chimie de Nice (ICN), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Côte d'Azur (UCA)-Université Nice Sophia Antipolis (... - 2019) (UNS), and COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)
- Subjects
010302 applied physics ,Materials science ,Polymer science ,0103 physical sciences ,Thermosetting polymer ,[CHIM]Chemical Sciences ,02 engineering and technology ,Adhesive ,Composite material ,021001 nanoscience & nanotechnology ,0210 nano-technology ,01 natural sciences ,Environmentally friendly - Abstract
International audience; Highly moisture-resistant optical adhesives need to be developed for optical devices to ensure that they can be used reliably in optical devices for outside environment use. Further, a principal aim is that these adhesives have less toxicity impact on the environment and also on humans, so they need to be eco-friendly. A Vegetable Oil Based Epoxidized Thermoset (VOBET) derived from linseed, was tested as an optical adhesive after being cured with different hardeners. A conventional optical adhesive, the petroleum-based, Epotek 353ND was used as a ref. material. With increasing humidity the ref. material's shear strength decreased significantly and interface peeling was obsd. for all samples, while VOBET samples maintained a certain level of strength. One particular VOBET formulation showed exceptional reliability. A comparison of shear strength before and after a pressure cooker test of thermally cured VOBET samples and Epotek 353ND samples showed that the strength of the latter decreased significantly while the former maintained a certain ratio of the initial strength. Furthermore, one particular VOBET formulation that was successfully cured at room temp. showed ∼7.2 MPa shear strength, which is comparable to that of Epotek 353ND.
- Published
- 2015
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