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1. A dedicated robust instrument for water vapor generation at low humidity for use with a laser water isotope analyzer in cold and dry polar regions

Author

C. Leroy-Dos Santos, M. Casado, F. Prié, O. Jossoud, E. Kerstel, M. Farradèche, S. Kassi, E. Fourré, A. Landais, Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette] (LSCE), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Glaces et Continents, Climats et Isotopes Stables (GLACCIOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Laboratoire Interdisciplinaire de Physique [Saint Martin d’Hères] (LIPhy ), Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA), Agence Nationale de la Recherche, ANR Institut Polaire Français Paul Emile Victor, IPEV: 1110, 1205 Prince Albert II of Monaco Foundation: 2487, Financial support. This research has been supported by the Prince Albert II of Monaco Foundation: 2487, Acknowledgements. The development presented in this paper was largely inspired by the initial PhD work of Janek Landsberg, which we gratefully acknowledge here. The research leading to these results has received funding from the Prince Albert II of Monaco Foundation 'ANTARCTIC-SNOW' program, the ANR 'EAIIST' project and the ADELISE 'CNRS-LEFE' program. The deployment of this instrument in the field was made possible by the logistic support from the 'NIVO2' and ADELISE 'IPEV' programs. We thank the two reviewers for their useful comments which greatly improved the article., ANR-16-CE01-0011,EAIIST,Projet International d'exploration de la calotte polaire de l'Antarctique de l'Est(2016), and Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)

Subjects
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph], Atmospheric Science, Spectrum analyzer, 010504 meteorology & atmospheric sciences, δ18O, lcsh:TA715-787, 010401 analytical chemistry, lcsh:Earthwork. Foundations, Humidity, Atmospheric sciences, Laser, 01 natural sciences, 0104 chemical sciences, law.invention, lcsh:Environmental engineering, 13. Climate action, law, Environmental science, Polar, Precipitation, lcsh:TA170-171, Spectroscopy, Water vapor, 0105 earth and related environmental sciences
Abstract

Obtaining precise continuous measurements of water vapor isotopic composition in dry places (polar or high-altitude regions) is an important challenge. The current limitation is the strong influence of humidity on the measured water isotopic composition by laser spectroscopy instruments for low humidity levels (below 3000 ppmv). This problem is addressed by determining the relationships between humidity and measured δ18O and δD of known water standards. Here, we present the development of a robust field instrument able to generate water vapor, down to 70 ppmv, at very stable humidity levels (average 1σ lower than 10 ppmv). This instrument, operated by a Raspberry interface, can be coupled to a commercial laser spectroscopy instrument. We checked the stability of the system as well as its accuracy when expressing the measured isotopic composition of water vapor on the VSMOW–SLAP (Vienna Standard Mean Ocean Water – Standard Light Antarctic Precipitation) scale. It proved to be highly stable during autonomous operation over more than 1 year at the East Antarctic Concordia and Dumont d'Urville stations.

Published
2021

2. Narrow Linewidth Excitonic Emission in Organic-Inorganic Lead Iodide Perovskite Single Crystals

Author

Diab, Hiba, Trippé-Allard, Gaëlle, Lédée, Ferdinand, Jemli, Khaoula, Vilar, Christèle, Bouchez, Guillaume, Jacques, Vincent L.R., Tejeda, Antonio, Even, Jacky, Lauret, Jean-Sébastien, Deleporte, Emmanuelle, Garrot, Damien, Laboratoire Aimé Cotton (LAC), École normale supérieure - Cachan (ENS Cachan)-Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires (PPSM), École normale supérieure - Cachan (ENS Cachan)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Groupe d'Etude de la Matière Condensée (GEMAC), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Physique des Solides (LPS), Université Paris-Sud - Paris 11 (UP11)-Centre National de la Recherche Scientifique (CNRS), Fonctions Optiques pour les Technologies de l'informatiON (FOTON), Université de Rennes (UR)-Université européenne de Bretagne - European University of Brittany (UEB)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Télécom Bretagne-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Photonique Quantique et Moléculaire (LPQM), École normale supérieure - Cachan (ENS Cachan)-CentraleSupélec-Centre National de la Recherche Scientifique (CNRS), This work has received funding from the European Union’s Horizon 2020 research and innovation programme under the grant agreement No 687008. The information and views set out in this paper are those of the author(s) and do not necessarily reflect the official opinion of the European Union. Neither the European Union institutions and bodies nor any person acting on their behalf may be held responsible for the use which may be made of the information contained herein. J.S. Lauret is ajunior member of the Institut Universitaire de France., Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11)-École normale supérieure - Cachan (ENS Cachan), Centre National de la Recherche Scientifique (CNRS)-Université Paris-Sud - Paris 11 (UP11), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Université européenne de Bretagne - European University of Brittany (UEB)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), and Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-École Nationale Supérieure des Sciences Appliquées et de Technologie (ENSSAT)-Télécom Bretagne-Centre National de la Recherche Scientifique (CNRS)

Subjects
Materials science, Photoluminescence, Exciton, 02 engineering and technology, 010402 general chemistry, 7. Clean energy, 01 natural sciences, Laser linewidth, Condensed Matter::Materials Science, Condensed Matter::Superconductivity, General Materials Science, Physical and Theoretical Chemistry, Thin film, Spectroscopy, Perovskite (structure), business.industry, Condensed Matter::Other, 021001 nanoscience & nanotechnology, Condensed Matter::Mesoscopic Systems and Quantum Hall Effect, 0104 chemical sciences, [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry, Full width at half maximum, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Optoelectronics, Crystallite, 0210 nano-technology, business
Abstract

International audience; Hybrid perovskite thin films have demonstrated impressive performance for solar energy conversion and optoelectronic applications. However, further progress will benefit from a better knowledge of the intrinsic photophysics of materials. Here, the temperature-dependent emission properties of CH3NH3PbI3 single crystals are investigated and compared to those of thin polycrystalline films by means of steady-state and time-resolved photoluminescence spectroscopy. Single crystals photoluminescence present a sharp excitonic emission at high energy, with full width at half maximum of only 5 meV, assigned to free excitonic recombination. We highlight a strong thermal broadening of the free excitonic emission, due to exciton–LO-phonon coupling. The emission turned to be very short-lived with a subnanosecond dynamics, mainly induced by the fast trapping of the excitons. The free excitonic emission is completely absent of the thin film spectra, which are dominated by trap state bands.

Published
2016

3. Modification of the Elastic Constants of a Peptide-Decorated Lamellar Phase

Author

Marcel Waks, John Kauffman, Wladimir Urbach, Nicolas Tsapis, Alain Chaffotte, John Everett, Peter Kahn, Dror E. Warschawski, R. Ober, Laboratoire de Physique de la Matière Condensée (LPMC), Collège de France (CdF (institution))-Centre National de la Recherche Scientifique (CNRS), Biochimie cellulaire, Institut Pasteur [Paris] (IP)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de biologie physico-chimique des protéines membranaires (LBPC-PM (UMR_7099)), Institut de biologie physico-chimique (IBPC (FR_550)), Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS), Rutgers University System (Rutgers), Laboratoire d'Imagerie Paramétrique (LIP), Université Pierre et Marie Curie - Paris 6 (UPMC)-IFR58-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Physique Statistique de l'ENS (LPS), Fédération de recherche du Département de physique de l'Ecole Normale Supérieure - ENS Paris (FRDPENS), École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS), N.T. was supported by a 'Société de Secours des Amis des Sciences' fellowship. P.K. acknowledges the support of the New Jersey Agriculture Experiment Station (Paper D-01405-1-01)., Université Paris Diderot - Paris 7 (UPD7)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)-Fédération de recherche du Département de physique de l'Ecole Normale Supérieure - ENS Paris (FRDPENS), École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS), Institut Pasteur [Paris]-Centre National de la Recherche Scientifique (CNRS), and Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Materials science, Surfactants, [SDV]Life Sciences [q-bio], Peptide, 02 engineering and technology, Decane, Peptides and proteins, 01 natural sciences, Stiffness, chemistry.chemical_compound, Lamellar phase, 0103 physical sciences, Electrochemistry, [CHIM]Chemical Sciences, General Materials Science, Vesicles, 010306 general physics, Spectroscopy, chemistry.chemical_classification, Bilayer, Vesicle, Surfaces and Interfaces, Lipid bilayer mechanics, 021001 nanoscience & nanotechnology, Condensed Matter Physics, Crystallography, chemistry, [SDE]Environmental Sciences, 0210 nano-technology, Thickness
Abstract

International audience; We have investigated the effect of the insertion of a triblock peptide (hydrophobic−hydrophilic−hydrophobic) in a nonionic lamellar phase composed of C12E4, decane, and water, stabilized by bilayer thermal fluctuations. Circular dichroism shows the peptide to be unordered in water, whereas its hydrophilic part is rigid and organized in an α-helix in the presence of surfactant bilayers. Surface tension measurements prove that the peptide is located at the hydrophobic−hydrophilic interface. Together with spectrofluorometry, these experiments suggest that the peptide lies on the bilayer surface. The Caillé parameter, η, of the lamellar phase, obtained by SAXS experiments, decreases with peptide concentration. This decrease has been interpreted as an increase of the bilayer effective thickness induced by the peptide and is well fitted by a recent model. The bilayer bending rigidity κ increases linearly with peptide concentration, up to two times the rigidity of a bare bilayer with mole ratio of peptide to surfactant as low as 5.2 × 10-4. The smectic compressibility modulus, B̄, decreases, implying that the peptide presence softens interactions between bilayers.

Published
2002