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Your search keyword '"Kashin, Alexey S."' showing total 2 results
Start Over Author "Kashin, Alexey S." Publisher georg thieme verlag stuttgart
2 results on '"Kashin, Alexey S."'

2. Highly Selective Catalytic Synthesis of (E,E)-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine: A Versatile (E,E)-1,3-Diene Building Block in Cross-Coupling Reactions.

Author

Ananikov, Valentine P., Kashin, Alexey S., Hazipov, Oleg V., Beletskaya, Irina P., and Starikovad, Zoya A.

Subjects
*CATALYSTS, *ACETYLENE, *IODINE, *UNIT construction, *COUPLING agents (Chemistry)
Abstract

The first practical procedure is reported for the synthesis of (E,E)-1,4-diiodobuta-1,3-diene from very simple starting materials (acetylene and I2). A pure crystalline product was obtained in a green chemical procedure utilizing the key advantages of highly selective Pt-catalyzed transformation and 100% atom efficiency of the addition reaction. The Pt catalyst was recovered and re-used in the reaction without a noticeable loss of activity. [ABSTRACT FROM AUTHOR]

Published
2011
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