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Your search keyword '"Simona Samaritani"' showing total 2 results
Start Over Author "Simona Samaritani" Publisher georg thieme verlag kg
2 results on '"Simona Samaritani"'

1. Intramolecular Diels-Alder Strategy in a Synthetic Approach to the ­Eleutherobin Core

Author

Alain Tomas, Jacques Royer, Simona Samaritani, Hélène Bruyère, and Stéphanie Ballereau

Subjects
eleutherobin, intramolecular Diels–Alder reaction, antitumor agents, eleuthesides, sulfolene, sulfolene, Chemistry, Stereochemistry, Eleutherobin, fungi, Organic Chemistry, Total synthesis, intramolecular Diels–Alder reaction, antitumor agents, eleutherobin, Intramolecular force, Diels alder, eleuthesides
Abstract

An attractive intermediate in the total synthesis of eleutherobin has been synthesised. The key step of this synthesis is an intramolecular Diels-Alder reaction, which leads to intermediate possessing rings A and C of theeleutherobin skeleton.

Published
2005

2. Reinheckel Protocol Revisited: Synthesis of (E)-α,β-Unsaturated Sulfoxides

Author

Corrado Malanga, Menicagli Rita Menicagli Rita, Simona Samaritani, and Giovanni Signore

Subjects
chemistry.chemical_classification, sulfoxides, organometallic reagents, alk-1-enyl alanes, aluminum, Reinheckel reaction, Stereochemistry, Reinheckel reaction, Aryl, Organic Chemistry, sulfoxides, General Medicine, Catalysis, organometallic reagents, Solvent, chemistry.chemical_compound, chemistry, aluminum, Reagent, Organic chemistry, alk-1-enyl alanes, Protocol (object-oriented programming), Alkyl
Abstract

A new synthetic approach to aryl and alkyl α,β-unsaturated sulfoxides is reported. The reaction has been optimized with respect to solvent, temperature, and ratio of reagents. The described procedure allows the synthesis of the title compounds in good yields (71-82%) starting from readily available reagents, in a cost-effective procedure.

Published
2006

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