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1. Oxazoline Cyanocuprate: A NewApproach to β-Carboxymethyl Functionalization of Enones

Author

Giuliano C. Clososki, Fabio Simonelli, Alfredo R. M. de Oliveira, Paulo H. G. Zarbin, Francisco A. de Marques, and Alcindo A. Dos Santos

Subjects
chemistry.chemical_compound, chemistry, Organic Chemistry, Electrophile, Polymer chemistry, Michael reaction, Surface modification, chemistry.chemical_element, Cuprate, Lithium, Reactivity (chemistry), Oxazoline, Copper
Abstract

This paper describes the preparation of a series of oxazoline cuprates by reaction of an oxazoline lithium anion with copper(I) salts: CuBr.DMS, Cul and CuCN in THF solution. The oxazoline cyanocuprate showed the best reactivity using enones as electrophiles.

Published
2003
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