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Start Over Author "Evgeny V. Shulishov" Publisher georg thieme verlag kg
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1. Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane

Author

A. B. Kostitsyn, Oleg M. Nefedov, Yu. V. Tomilov, and Evgeny V. Shulishov

Subjects
Cyclopropanation, Diazomethane, Organic Chemistry, chemistry.chemical_element, Medicinal chemistry, Catalysis, chemistry.chemical_compound, Benzonitrile, chemistry, Organic chemistry, Allyl alcohol, Diethyl ether, Dichloromethane, Palladium
Abstract

(Alkoxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxy-ethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, alllylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethyl ether in the presence of bis(benzonitrile)palladium dichloride

Published
1990
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