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Start Over Author "Chuanle Zhu" Publisher georg thieme verlag kg
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1. Dual Roles of TBHP-Enabled Regioselective Hydroetherification of (Trifluoromethyl)alkenes with Boronic Acids: Access to α-Trifluoromethyl β-Aryloxy Tertiary Alcohols

Author

Chuanle Zhu and Hengyuan Li

Subjects
Trifluoromethyl, 010405 organic chemistry, Organic Chemistry, chemistry.chemical_element, Regioselectivity, Alcohol, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, Catalysis, 0104 chemical sciences, chemistry.chemical_compound, chemistry, Nucleophile, Fluorine, Tertiary alcohols, Boronic acid
Abstract

The three-starting materials four-component reaction of (trifluoromethyl)alkenes, TBHP, and boronic acids is reported, delivering various useful α-trifluoromethyl-β-aryloxy tertiary alcohols in high yields and in an exclusively regioselective hydroetherification manner. TBHP serves as both the oxidant and nucleophile in this reaction, as well as the O-source of the products.

Published
2021

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