Search

Hafnium Hf-176/Hf-177 isotope ratio variations in marine records are thought to reflect changes in continental weathering through time, but the behavior of Hf in rivers, and during weathering, is not well understood. Here, we present Hf-176/Hf-177 data for rivers, bedrock, soils, and leaching experiments for the Moselle basin, Vosges, France. These data strongly suggest that the Hf-176/Hf-177 composition of river waters is controlled by preferential dissolution of accessory phases (i.e., apatite, sphene) versus more resistant minerals (e.g., K-feldspar) and linked to the intensity of silicate weathering. Estimates for the global isotopic composition of riverine Hf suggest that the ocean Hf budget may be dominated by river input, and variations seen in marine records can be directly related to changes in silicate weathering intensity.

The Sulitjelma fold nappe represents part of a Caledonian marginal basin obducted during the closure of the Iapetus Ocean and collision between Laurentia and Baltica. Metamorphic pressure-temperature (P-T) paths indicate that various parts of the Sulitjelma fold nappe followed characteristic clockwise P-T paths involving prograde burial followed by prograde exhumation and then near-isothermal exhumation prior to cooling. Geochronological results indicate that foreland rocks followed this general P-T path before more hinterlandward rocks, such that foreland rocks underwent exhumation while hinterlandward rocks were still being buried. This is consistent with the fold nappe passing through a collisional orogen; burial and ultimately prograde metamorphism were terminated sequentially by exhumation as a given part of the fold nappe came into contact with the lower plate, basement ramp (Baltica) and was driven upward. Burial, heating, exhumation, and cooling were thus diachronous within a single tectonic unit.