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Emerging micropollutants, originating from diverse sources, including pharmaceutical, pesticides, and industrial effluents, are a serious environmental concern. Their presence in natural water bodies has negative effects on ecosystems and human health. To address this issue, the importance of a source-controlled approach has grown, highlighting the use of advanced technologies such as oxidation processes, membrane filtration, and adsorption to prevent micropollutants from entering the environment. Therefore, this review provides a comprehensive overview of emerging micropollutants, their analytical detection methods, and their environmental impacts, with a focus on aquatic ecosystems, human health, and terrestrial environments. It also highlights the importance of using a source-controlled approach and provides insights into the benefits and drawbacks of this strategy. The primary micropollutants identified in this review were erythromycin, ibuprofen, and triclocarban, originating from the pharmaceutical industries for their use as antibiotics, analgesic, and antibacterial drugs. The primary analytical methods used for detection involved hybrid techniques that integrate chromatography with spectroscopy. Thus, this review emphasizes the source-controlled approach's benefits and drawbacks, focusing on emerging micropollutants, their detection, and impacts on ecosystems and health., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Microcystins (MCs), frequently detected in freshwater ecosystems, have raised significant human health and ecological concerns. New approaches are being developed to control and remove MCs. In this study, we examined factors influencing the efficacy of electrochemical oxidation as a means of control. Anode material (Pt/Ti, Ta 2 O 5 -IrO 2 /Ti, SnO 2 -SbO 2 /Ti, boron-doped diamond (BDD/Si), anode surface area ratios and solution volumes, initial pollutant concentrations, and the co-existing antibiotic sulfamethoxazole (SMX) were investigated. MCs and SMX were dissolved in filtered Taihu Lake water to simulate the natural aquatic environment. The results showed that non-active anodes, lower initial concentration of MC, larger surface area ratio of cathode to anode, and smaller ratio of reaction solution volume to anode surface area could promote the degradation target pollutants. Under optimal conditions in this study, the degradation rates of MC-LR, MC-YR, MC-RR, and SMX each reached more than 90% within 6 h, and the removal efficiency of MC-YR was the highest among three congeners. The effect of SMX on the degradation of MC congeners depended mainly on their concentration differences, such that when the initial concentration of SMX was one to two orders of magnitude lower than microcystin, the presence of SMX would promote the degradation of MCs. In contrast, when the initial concentration of SMX was higher than that of microcystin by approximately an order of magnitude, sulfamethoxazole would inhibit the degradation of MCs by between 4.6% and 24.5%. Ultra-high-performance liquid chromatography tandem mass spectrometry analysis revealed that the three MC congeners were electrochemically degraded through aromatic ring oxidation, alkene oxidation, and bond cleavage on the ADDA (3-amino-9-methoxy-2,6,8-trimethyl-10-phenyldeca-4,6-dienoic acid) side chain. Notably, the removal of MCs was accompanied by a decline in the hardness of the reaction water. This study provided insights into electrochemical degradation of microcystins and antibiotics in natural water, offering suggestions for its practical application., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Nature iron is considered one of the promising catalysts in advanced oxidation processes (AOPs) that are utilized for soil remediation from polycyclic aromatic hydrocarbons (PAHs). However, the existence of anions, cations, and organic matter in soils considered impurities that restricted the utilization of iron that was harnessed naturally in the soil matrix and reduced the catalytic performance. In this regard, tropical soil naturally containing iron and relatively poor with impurities was artificially contaminated with 100 mg/50 g benzo[α]pyrene (B[α]P) and remediated using a slurry phase reactor supported with persulfate (PS). The results indicated that tropical soil containing iron and relatively poor with impurities capable of activating the oxidants and formation of radicals which successfully degraded B[α]P. The optimum removal result was 86% and obtained under the following conditions airflow = 260 mL/min, temperature 55 °C, pH 7, and [PS] 0  = 1.0 g/L, at the same experimental conditions soil organic matter (SOM) mineralization was 48%. After the remediation process, there was a significant reduction in iron and aluminum contents, which considered the drawbacks of this system. Experiments to scavenge reactive species highlighted O 2 •- and SO 4 •- as the main radicals that oxidized B[α]P. Additionally, monitoring of by-products post-remediation aimed to assess toxicity and elucidate degradation pathways. Mutagenicity tests yielded positive results for two B[α]P by-products. The toxicity tests considered were the lethal concentration of 50% (LC 50 96 h) for fat-head minnows revealed that all B[α]P by-products were less toxic than the parent pollutant itself. This research marks a significant advancement in soil remediation by advancing the use of the AOP method, removing the requirement for additional catalysts in the AOP system for the removal of B[α]P from soil., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Advanced oxidation processes based on persulfate activation by biochar have been widely used to remove antibiotics and antibiotic resistance genes (ARGs) from wastewater. In this study, we used a common continuous fixed-bed reactor based on a biochar/persulfate system to treat wastewater. The average apparent ARG-removal efficiency was 82.38% in the biochar/persulfate reactor. The results of continuous reactor activity suggested the presence of ARG residues in the biochar (the abundance of ARG in the biochar increased 10 3 -fold) and unstable removal of extracellular ARGs, raising concerns about a potential environmental burden. Kinetic experiments showed that the absolute abundance of intracellular ARGs (iARGs) rapidly decreased 98.3% within 30 min, but extracellular ARGs (eARGs) correspondingly increased 15-fold, suggesting that persulfate broke bacterial cells open and quickly released iARGs as eARGs. Moreover, the proportions of the three types of ARGs showed that ARG removal was attributed to about 70% degradation and 30% adsorption by the biochar/persulfate reactor. Further analysis revealed that biochar acts as a special shelter for ARGs. Release experiment of used biochar indicated that nearly half of absorbed ARGs could be released into new environment and causing potential risk. Overall, our findings provide a fundamental understanding of the fate of ARGs during treatment of antibiotic-contaminated wastewater and new insights into the multiple roles of biochar, which can potentially represent an additional burden on ecosystems and human health., Competing Interests: Declaration of competing interest There are no conflicts of interest in the submission of this manuscript. This manuscript is approved by all authors for publication. I would like to declare on behalf of my co-authors that the work described was original research that has not been published previously and not under consideration for publication elsewhere., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In the present study, we introduce a covalent organic triazine framework polymer (COTF-P) using 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) with triazine-based amine. The resulting dark red COTF-P illustrated potential behavior as a photocatalyst under visible light. Due to the inadequate solar energy capture and ultrafast charge recombination of the resulting COTF-P, the prepared COTF-P has been decorated with CQDs (N-CQD and N-S-CQD) to build a Z-scheme CQDs/COTF-P heterojunction photocatalyst and utilizes as photocatalyst for the breakdown of phenanthrene (PHE) exposed to visible light. The prepared COTF-P and CQDs/COTF-P were fully characterized, analyzing the textural (N 2 isotherms), structural (XRD and FTIR), chemical (EDX and XPS), morphological (FESEM and TEM), optical (DRS-UV-Vis and photoluminescence), and electrochemical properties (EIS impedance, transient photocurrent, and flat band potential). The prepared N-S-CQD/COTF-P heterojunction displayed optimum activity for the photocatalytic oxidation of PHE from water, owing to an enhanced separation of the photogenerated charges and lower bandgap value, 2.1 vs. 1.9 eV. The N-S-CQD/COTF-P heterojunction showed acceptable stability in terms of activity and structural properties after 5 cycles of reuse. The mechanism of activation highlights the importance played by superoxide radicals and hydroxyl radicals. This project sheds light on the potential use of CQDs for the decoration of polymers, extending the absorbance in the visible region and boosting the migration of charge, which boosts the activity of the resulting material., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Persulfates activation by various nanomaterials has been intensively reported for advanced oxidation processes (AOPs), and substantial progress has been made in understanding the mechanism. However, most of the published articles only present the unnormalized catalytic properties, which generated confusion to compare different catalysts and identify the active sites. Herein, we presented electrochemical surface area (ECSA) as a practical normalized method and confirmed the primary active sites in N-doped graphene. By controlling the aggregation state of graphene sheets to adjust the activity of doped graphite-N species, the active sites for peroxydisulfate (PDS) activation were accurately estimated. In further experiments, specific surface area (SSA, by N 2 -physisorption and methylene blue adsorption) and ECSA were adopted to conclude the normalized oxidation rate constant and graphitic-N was confirmed as the primary site in nitrogen-doped graphene for the carbocatalyst/PDS system. The normalized results revealed that SSA derived from inert gas on materials could not reflect the true active sites at solid-liquid interface, while ECSA considering the operated solid-liquid situation can be used for accurate estimation of the active sites. Therefore, this study suggests that ECSA integrates the properties of both kinetics and thermodynamics, which can be adopted as a useful methodology for analyzing nano-sized environmental catalysts performance., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Water pollution, stemming from various contaminants including organic and pharmaceutical pollutants, poses a significant global challenge. Amidst the array of methods available for pollutant mitigation, the three-dimensional electrochemical approach emerges as a standout solution due to its environmental compatibility, cost-effectiveness, and rapid efficiency. This study delves into the efficacy of three-dimensional electrochemical processes in purging organic and pharmaceutical pollutants from aqueous media. Existing research indicates that the three-dimensional electrochemical process, particularly when employing particle electrodes, exhibits notable success in degrading organic and pharmaceutical pollutants. This achievement is largely attributed to the ample specific surface area of particle electrodes and the shortened mass transfer distance, which collectively enhance efficiency in comparison to traditional two-dimensional electrochemical methods. Moreover, this approach is lauded for its environmental friendliness and cost-effectiveness. However, it is imperative to note that the efficacy of the process is subject to various factors including temperature, pH levels, and current intensity. While the addition of oxidants can augment process efficiency, it also carries the risk of generating intermediate compounds that impede the reaction. In conclusion, the three-dimensional electrochemical method proves to be a viable and practical approach, provided that process conditions are meticulously considered and adhered to. Offering advantages from both environmental and economic perspectives, this method presents a promising alternative to conventional water and wastewater treatment techniques., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Developing high-performance and durable catalysts presents a significant challenge for oxidizing toxic inorganic and pharmaceutical compounds in wastewater. Recently, there has been a surge in the development of new heterogeneous catalysts for degrading pharmaceutical compounds, driven by advancements in electrocatalysts and photoelectrocatalysts. In this study, a plasmonic Ag nanoparticles decorated CoFe 2 O 4 @TiO 2 heteronanostructures have been successfully designed to fabricate a high-performing photoelectrode for the oxidation of pharmaceutical compounds. The developed Ag-CoFe 2 O 4 @TiO 2 possessed a higher electrochemical stability and effectively harvested the UV to visible and NIR radiation in sunlight which generates the enormous photochemical reactive species that involved in the oxidation of ibuprofen in wastewater. Under direct sunlight irradiation, Ag-CoFe 2 O 4 @TiO 2 achieved complete oxidation of ibuprofen in wastewater at 0.8 V vs RHE. This indicates that metallic Ag nanoparticles are involved in the charge separation and transport of charge carriers from the photoactive sites of CoFe 2 O 4 @TiO 2 , promoting the generation of abundant hydroxy, oxy, and superoxide radicals that actively break the bonds of ibuprofen. Additionally, oxidation agents such as urea and H 2 O 2 were utilized to enhance the formation of superoxide ions and hydroxyl radicals, which rapidly participate in the oxidation of ibuprofen. Significantly, testing for recyclability confirmed the stability of the Ag-CoFe 2 O 4 @TiO 2 photoanode, ensuring its suitability for prolonged use in photoelectrochemical advanced oxidation processes. Integrating Ag-CoFe 2 O 4 @TiO 2 photoanodes into water purification systems could enhance economic feasibility, reduce energy consumption, and improve efficiency., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The contamination of water bodies by synthetic organic compounds coupled with climate change and the growing demand for water supply calls for new approaches to water management and treatment. To tackle the decontamination issue, the activation of peroxymonosulfate (PMS) using copper magnetic ferrite (CuMF) nanoparticles prepared under distinct synthesis conditions was assessed to oxidize imidacloprid (IMD) insecticide. After optimization of some operational variables, such as CuMF load (62.5-250 mg L -1 ), PMS concentration (250-1000 μM), and solution pH (3-10), IMD was completely oxidized in 2 h without interferences from leached metal ions. Such performance was also achieved when using tap water but was inhibited by a simulated municipal wastewater due to scavenging effects promoted by inorganic and organic species. Although there was evidence of the presence of sulfate radicals and singlet oxygen oxidizing species, only four intermediate compounds were detected by liquid chromatography coupled to mass spectrometry analysis, mainly due to hydroxyl addition reactions. Concerning the changes in surface properties of CuMF after use, no morphological or structural changes were observed except a small increase in the charge transfer resistance. Based on the changes of terminal surface groups, PMS activation occurred on Fe sites., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Tetramethylammonium hydroxide (TMAH), which is a chemical used in the electronic industry, is classified as a hazardous material (HAZMAT class 8) that threatens aquatic ecosystems and human health. Consequently, numerous studies have attempted to remove TMAH using various treatment methods, including advanced oxidation processes such as ozone, UV, or Fenton oxidation. However, prior research has indicated a low kinetic rate of TMAH removal. In this context, we proposed an alternative to TMAH degradation by combining a cold plasma (CP) process with periodate oxidation. As for the kinetics of TMAH removal, the kinetic constant was improved by 5 times (0.1661 and 0.0301 for 40.56 and 2.2 W, respectively) as the electric power of a CP system increased from 2.2 to 40.56 W. The kinetic constant of a 40.56 W CP system further increased by 54 times (1.6250) than a 2 W CP system when 4 mM periodate was used simultaneously. As a result, the integrated CP/periodate system represented 2 times higher TMAH removal efficiency (29.5%) than a 2 W CP system (14.4%). This excellent TMAH degradation capability of the integrated CP/periodate system became pronounced at pH 10 and 25 °C. Overall, the integrated CP/periodate system is expected to be a viable management option for effectively controlling hazardous TMAH chemicals., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

The peroxynitrite photocatalytic degradation system was considered a green, convenient, and efficient water treatment process, but not satisfying against some antibiotics, e.g. sulfonamides (SAs). To improve the photocatalytic degradation efficiency of SAs, sulfur was introduced to a magnetic Fe-MOF (Fe-metal organic framework) Prussian blue analog to achieve a heteroatomic material CuFeO@S, which was applied in heterogeneous visible light photo-assisted catalytic process with persulfate (PS) as an oxidant. The characterization results of CuFeO@S by XRD and XPS confirmed the presence of Fe 3 O 4 (for magnetic separation), Cu + (for activation of PS) and S 2- (for narrowing the energy band and prolonging the lifetime of photo-generated electronics). Through systematic optimization of reaction conditions in CuFeO@S + PS + hv system, efficient degradation of four tested SAs was achieved in 30 min (removal rate of 97-100% for the tested 4 SAs). Moreover, the material could be magnetically recycled and reused for over 7 cycles with a removal rate of >90% for sulfamerazine. Furthermore, the removal rate of sulfamerazine in pond water reached 99% at a mineralization rate of about 34% (decrease in total organic matter), demonstrating its potential in the treatment of antibiotic-containing wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Nanometric cobalt magnetic ferrite (CoFe 2 O 4 ) synthesized by distinct methods was used for in situ chemical activation of peroxymonosulfate (PMS) under neutral conditions to oxidize imidacloprid (IMD) insecticide. The effect of CoFe 2 O 4 load (0.125-1.0 g L -1 ) and PMS concentration (250-1000 μM) was investigated as well as the influence of phosphate buffer and Co(II) ions. PMS activation by Co(II) ions, including those leached from CoFe 2 O 4 (>50 μg L -1 ), exhibited a strong influence on IMD oxidation and, apparently, without substantial contributions from the solid phase. Within the prepared solid materials (i.e., using sol-gel and co-precipitation methods), high oxidation rates (ca. 0.5 min -1 ) of IMD were attained in ultrapure water. Phosphate buffer had no significant influence on the IMD oxidation rate and level, however, its use and solution pH have shown to be important parameters, since higher PMS consumption was observed in the presence of buffered solutions at pH 7. IMD byproducts resulting from hydroxylation reactions and rupture of the imidazolidine ring were detected by mass spectrometry. At optimum conditions (0.125 g L -1 of CoFe 2 O 4 and 500 μM of PMS), the CoFe 2 O 4 nanoparticles exhibited an increase in the charge transfer resistance and an enhancement in the surface hydroxylation after PMS activation, which led to radical (HO ● and SO 4 ●- ) and nonradical ( 1 O 2 ) species. The latter specie led to high levels of IMD oxidation, even in a complex water matrix, such as simulated municipal wastewater at the expense of one-order decrease in the IMD oxidation rate., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Microwave-induced plasmas generated at atmospheric pressure are very attractive for a great variety of applications since they have a relatively high electron density and can generate large amounts of reactive species. Argon plasmas can be sustained inside dielectric tubes but are radially contracted and exhibit filamentation effects when the diameter of the tube is not narrow enough (over 1.5 mm). In this work, we describe a new approach for creating microwave (2.45 GHz) plasmas under atmospheric pressure conditions by using a surfatron device and power from 10 W. This modified design of the reactor enables the sustenance of non-filamented argon plasmas. These new plasmas have a higher gas temperature and electron density than the plasma generated in the original surfatron configuration. The new design also allows for the maintenance of plasmas with relatively high proportions of water, resulting in the generation of larger quantities of excited hydroxyl radicals (·OH*). Thus, this novel configuration extends the applicability of microwave-induced plasmas by enabling operation under new conditions. Finally, the degradation of methylene blue (MB) in aqueous solutions has been assessed under different initial dye concentrations and argon flow conditions. The new plasma produces a substantial increase in hydrogen peroxide and nitrate concentrations in water and leads to a noteworthy enhancement in MB degradation efficiency. The introduction of water into the plasma produces a minor additional improvement., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Monochloramine (NH 2 Cl) is applied upstream of reverse osmosis (RO) membranes for biofouling control. Residual NH 2 Cl can undergo UV photolysis downstream, generating reactive species for an AOP to occur. At the bench-scale, NH 2 Cl is typically generated from combining sodium hypochlorite and ammonium chloride or sulfate. This study investigated the degradation of four compounds of interest - acetaminophen, caffeine, sucralose and 1,4-dioxane - in UV/NH 2 Cl at the bench scale to study their reactivity with reactive chlorine species (RCS) and reactive nitrogen species (RNS). With methanol acting as a scavenger of • OH radicals, the performance of UV/NH 2 Cl was compared to UV/H 2 O 2 and UV/HOCl. In UV/H 2 O 2 , dioxane was severely inhibited at 1-2 mg/L H 2 O 2 and comparable at 5 mg/L to UV/NH 2 Cl. When ammonium sulfate ((NH 4 ) 2 SO 4 ) was used as the ammonia source over ammonium chloride (NH 4 Cl), the overall degradation of micropollutants was higher and caffeine was exclusively degraded. At 1-2 mg/L NH 2 Cl, dioxane degraded by 16.2-17.8% and 2.92-5.29% from (NH 4 ) 2 SO 4 and NH 4 Cl respectively while caffeine degraded by 7.45-9.61% with NH 2 Cl ((NH 4 ) 2 SO 4 ), but not degrade with NH 2 Cl (NH 4 Cl). The higher concentration of chloride ions from NH 4 Cl significantly influenced the speciation of generated radicals and impacted micropollutant degradation. This suggests that the reactivity of more selective RCS (Cl 2 •- , • ClO, ClOH •- ) and RNS ( • NH 2 , • NO, • NO 2 , etc.) varies with micropollutants of interest. The presence of higher chloride concentration from the ammonia source inhibited the generation of • OH radicals with • OH consumed by RNS to form NO 3 - (μg/L levels), showing the impact of the choice of ammonia source and the water matrix on UV/NH 2 Cl performance., Competing Interests: Declaration of competing interest The authors declare that they do not have any known competing financial conflicts of interest or personal connections that could have given the impression of affecting the findings presented in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Micro/nanoplastics (MNPs) have been increasingly found in environments, food, and organisms, arousing wide public concerns. MNPs may enter food chains through water, posing a threat to human health. Therefore, efficient and environmentally friendly technologies are needed to remove MNPs from contaminated aqueous environments. Advanced oxidation processes (AOPs) produce a vast amount of active species, such as hydroxyl radicals (·OH), known for their strong oxidation capacity. As a result, an increasing number of researchers have focused on using AOPs to decompose and remove MNPs from water. This review summarizes the progress in researches on the removal of MNPs from water by AOPs, including ultraviolet photolysis, ozone oxidation, photocatalysis, Fenton oxidation, electrocatalysis, persulfate oxidation, and plasma oxidation, etc. The removal efficiencies of these AOPs for MNPs in water and the influencing factors are comprehensively analyzed, meanwhile, the oxidation mechanisms and reaction pathways are also discussed in detail. Most AOPs can achieve the degradation of MNPs, mainly manifest as the decrease of particle size and the increase of mass loss, but the mineralization rate is low, thus requiring further optimization for improved performance. Investigating various AOPs is crucial for achieving the complete decomposition of MNPs in water. AOPs will undoubtedly play a vital role in the future for the removal of MNPs from water., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this work, sixteen typical chlorinated and brominated aromatic disinfection by-products (DBPs) were selected as examples to investigate their different degradation mechanisms initiated by HO• and SO 4 • - . Addition reactions were the main mode of degradation of DBPs by HO•, while SO 4 • - dominated H-abstraction reactions and single electron transfer reactions. Chlorinated compounds had higher reactivity than brominated compounds. Furthermore, substituents with stronger electron-donating effects promoted the electrophilic reaction of DBPs with the two radicals. In addition, we developed a model based on the chemical properties LUMO, f max - , and hardness for predicting the average reaction energy barriers for the initial reactions of DBPs with HO• and SO 4 • - . The model had good predictive performance for the difficulty of degradation of different DPBs by HO• and SO 4 • - , with R 2 values of 0.85 and 0.87, respectively. Through the degradation efficiency simulation, we found that longer reaction times, higher oxidant concentrations and lower pollutant concentrations were more favorable for the removal of DBPs. The UV/PDS process showed better degradation of DBPs than the UV/H 2 O 2 process. In addition, most degradation products of DBPs exhibited less toxicity to aquatic organisms than their parent compounds. This study provided theoretical guidance for the degradation and removal of other aromatic DBPs at the molecular level., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Neutral low-molecular-weight organics such as methyl nitrate that can readily pass through reverse osmosis (RO) membranes employed in potable water reuse facilities attract interest owing to public health considerations. In this study, a novel determination method based on high-performance liquid chromatography, online photochemical conversion to peroxynitrite, and luminol chemiluminescence detection was developed for methyl nitrate measurement in treated water. The maximum photochemical conversion efficiency of methyl nitrate to peroxynitrite was found to be 6.5% using a 222-nm excimer lamp. The calibration curve for the developed method was linear between 1.0 × 10 -9 and 1.0 × 10 -7  M, and the limit of detection was 0.3 nM (0.03 μg/L) given an injection volume of 200 μL. The methyl nitrate concentrations in RO permeate from reclaimed wastewater and product water after subsequent treatment by a UV/H 2 O 2 advanced oxidation process (AOP) were 2.2 and 22.5 nM (0.17 and 1.7 μg/L), respectively. UV irradiation of RO permeate in the laboratory using a low-pressure Hg lamp confirmed the formation of methyl nitrate in the permeate in the absence of H 2 O 2 and residual chloramines. This chemiluminescent detection method for methyl nitrate will promote a greater understanding of the origin and formation of this treatment byproduct in reclaimed wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Combination of microbial fuel cell (MFC) and advanced oxidation process (AOP) is promising for pollutant removal. In this paper, Cu 0 -loaded carbon cloth cathode by electrodeposition (Cu@CC-PS-MFC) was applied to enhance 2,4-dichlorophenol (2,4-DCP) degradation based on persulfate (PS) activation in microbial fuel cell. Cu 0 exhibited a typical structure of face-centered cubic metal polyhedron on carbon cloth. The removal of 2,4-DCP by Cu@CC-PS-MFC (75.6%) was enhanced by more than 50% compared to CC-PS-MFC (49.2%) after 1 h of reaction. 30 mg/L 2,4-DCP in Cu@CC-PS-MFC was completely removed and achieved a high mineralization (80.6%) after 9 h of reaction under optimized condition with low dissolved copper ion concentration (0.615 mg/L). Meanwhile, more than 90% removal of 2,4-DCP was stably achieved with flow operation condition (hydraulic residence time of 7.2 h). The change of copper valent state Cu 0 /Cu 2 O/CuO was the main mechanism of PS activation with main reactive species of O•H and O 2 1. The bioanode of MFC enhanced the in-situ regeneration of ≡Cu + and ≡Cu 0 on the catalyst surface by transporting electrons, which was believed to contribute to good catalyst lifetime and excellent 2,4-DCP removal. Electrodeposited copper contributes to the enhanced degradation of 2,4-DCP with energy recovery at the same time which can further broaden the application MFC., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, cobalt copper-layered double hydroxides (CoCu-LDHs) were prepared by coprecipitation as catalysts to activate CaSO 3 for metronidazole (MNZ) degradation. This is the first report on layered double hydroxides activating sulfite for the degradation of organic pollutants. Meanwhile, to address the issue of self-quenching reactions readily occurring in conventional sulfite advanced oxidation systems and resulting in low oxidant efficiency, CaSO 3 with slightly soluble in water was used instead of commonly used Na 2 SO 3 , to improve the limitations of traditional systems. The results showed that in the CoCu-LDHs/CaSO 3 system, the degradation rate of MNZ reached 98.7% within 5 min, representing a 23.0% increase compared to the CoCu-LDHs/Na 2 SO 3 system. Owing to the excellent catalytic performance exhibited by CoCu-LDHs, characterizations including XRD, FTIR, SEM, TEM, BET and XPS were carried out to investigate this further. The results confirmed the successful synthesis of CoCu-LDH, and the activation mechanism study revealed that Co and Cu were considered to the main elements in activating CaSO 3 , demonstrating good synergistic effects. In addition, the oxygen vacancies on the catalyst surface also played a positive role in generating radicals and promoting electron transfer. Subsequently, the effects of Co/Cu ratio, catalyst dosage, oxidant concentration, pollutant concentration, pH and coexisting substances on MNZ degradation were investigated. Additionally, based on the LC-MS analysis of degradation products and toxicity tests, MNZ was transformed into different intermediates with low toxicity through four pathways, eventually mineralizing into inorganic small molecules. After six cycles, the MNZ degradation rate still reached 82.1%, exhibiting excellent stability and recyclability. In general, this study provides new ideas for activating sulfite, while providing theoretical support for subsequent research on sulfite advanced oxidation system., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Hydrothermal liquefaction of Kraft black liquor is a promising method for the production of valuable organic chemicals. However, the separation of the biochar and biocrude leaves a residual aqueous phase in large volumes, which needs to be properly managed to make the process profitable. In this work, the persulphate-based advanced oxidation was assessed, for the first time ever, as a pretreatment of this aqueous phase to reduce its content of phenolic compounds and alcohols, which hinder further valorisation strategies. Results revealed that the phenolic compounds and the alcohols were oxidised in presence of low persulphate anion concentrations (<50 mM), mainly to quinone-like compounds and organic acids. At higher oxidant concentrations, these intermediates were subsequently oxidised to valuable acetic acid. When Fe (II) was added as the catalyst, low concentrations (<9 mM) enhanced the degradation of both phenolic compounds and alcohols due to the increase of the sulphate radicals, consequently reducing persulphate requirements for their removal. Nevertheless, higher Fe (II) doses produced the sequestration of sulphate radicals, thus decreasing the oxidation performance and generating undesired parallel reactions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)

A Cu(II)/heat coactivated peracetic acid (PAA) system for enhancing diclofenac (DCF) degradation was proposed in this work. The superiority of this synergetic activation strategy for PAA, working reactive species, catalytic mechanism and effects of reaction parameters on DCF elimination in this system were simultaneously investigated. Based on our results, the DCF loss rate in Cu(II)-heat/PAA process at pH 8.0 was about 49.3 and 4.2 times of that in Cu(II)/PAA and heat/PAA processes, respectively. Increasing the reaction temperature to 60 о C not only motivated the conversion of Cu(II) to Cu(I) but also facilitated the one-electron transfer between Cu(I) and PAA, boosting the generation of radicals. Organic radicals (mainly CH 3 C(O)O• and CH 3 C(O)OO•) were evidenced to be the core oxidizing substances dominating in the destruction of DCF while hydroxyl radical (•OH) made a minor contribution in this system by electron paramagnetic resonance (EPR) method together with scavenging experiments. This study broads the eyes into enhanced PAA activation initiated by homogenous Cu(II), providing a simple but efficient tool to degrade micropollutants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Sulfate radical (SO 4 •- )-based advanced oxidation processes (AOPs) have become promising alternatives in environmental remediation due to the higher redox potential (2.6-3.1 V) and longer half-life period (30-40 μs) of sulfate radicals compared with many other radicals such as hydroxyl radicals (•OH). The generation and mechanisms of SO 4 •- and the applications of SO 4 •- -AOPs have been examined extensively, while those using sulfite as activation precursor and their comparisons among various activation precursors have rarely reviewed comprehensively. In this article, the latest progresses in SO 4 •- -AOPs were comprehensively reviewed and commented on. First of all, the generation of SO 4 •- was summarized via the two activation methods using various oxidant precursors, and the generation mechanisms were also presented, which provides a reference for guiding researchers to better select two precursors. Secondly, the reaction mechanisms of SO 4 •- were reviewed for organic pollutant degradation, and the reactivity was systematically compared between SO 4 •- and •OH. Thirdly, methods for SO 4 •- detection were reviewed which include quantitative and qualitative ones, over which current controversies were discussed. Fourthly, the applications of SO 4 •- -AOPs in various environmental remediation were summarized, and the advantages, challenges, and prospects were also commented. At last, future research needs for SO 4 •- -AOPs were also proposed consequently. This review could lead to better understanding and applications of SO 4 •- -AOPs in environmental remediations., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The structure especially the active site manipulation of Fenton-like catalysts was essential for the efficient removal of organic contaminants in the aquatic environment. In this study, the carbonized bacterial cellulose/FeMn oxide composite (CBC@FeMnO x ) were synthetized and modified by hydrogen (H 2 ) reduction to obtain the carbonized bacterial cellulose/FeMn composite (CBC@FeMn), with emphasis on the processes and mechanisms for atrazine (ATZ) attenuation. The results showed that H 2 reduction did not change the microscopic morphology of the composites but destroy the Fe-O and Mn-O structures. Compared with the CBC@FeMnO x composite, the H 2 reduction could promote the removal efficiency from 62% to 100% for CBC@FeMn, as well as the enhancement of degradation rate from 0.021 min -1 to 0.085 min -1 . The quenching experiments and electron paramagnetic resonance (EPR) displayed that the hydroxyl radicals (•OH) was the major contributor for ATZ degradation. The investigation for Fe and Mn species indicated that H 2 reduction could increase the content of Fe(II) and Mn(III) in the catalyst, thus improving the generation of •OH and accelerating the cycle process between Fe(III)/Fe(II). Owing to the excellent reusability and stability, it was indicated that the H 2 reduction can be considered as an efficient way to regulate the chemical valence of the catalyst, thus enhancing the removal efficiency of aquatic contaminants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Per- and polyfluoroalkyl substances (PFAS), one of the main categories of emerging contaminants, are a family of fluorinated organic compounds of anthropogenic origin. PFAS can endanger the environment and human health because of their wide application in industries, long-term persistence, unique properties, and bioaccumulation potential. This study sought to explain the accumulation of different PFAS in water bodies. In aquatic environments, PFAS concentrations range extensively from <0.03 (groundwater; Melbourne, Australia) to 51,000 ng/L (Groundwater, Sweden). Additionally, bioaccumulation of PFAS in fish and water biota has been stated to range from 0.2 (Burbot, Lake Vättern, Sweden) to 13,900 ng/g (Bluegill samples, U.S.). Recently, studies have focused on PFAS removal from aqueous solutions; one promising technique is advanced oxidation processes (AOPs), including microwaves, ultrasound, ozonation, photocatalysis, UV, electrochemical oxidation, the Fenton process, and hydrogen peroxide-based and sulfate radical-based systems. The removal efficiency of PFAS ranges from 3% (for MW) to 100% for UV/sulfate radical as a hybrid reactor. Therefore, a hybrid reactor can be used to efficiently degrade and remove PFAS. Developing novel, efficient, cost-effective, and sustainable AOPs for PFAS degradation in water treatment systems is a critical area of research., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. Amin Mojiri., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Polybrominated diphenyl ethers (PBDEs) as a typical brominated flame retardant (BFR) have attracted worldwide attention due to the high environmental risk and resistance to conventional remediation processes. In this study, thermally activated persulfate (TAP) process was applied to degrade 2,2',4,4'-tetrabromodiphenyl ether (BDE-47), which is the most toxic and representative PBDEs in e-waste dismantling sites. Impact factors such as PDS dosage, heating temperature, and initial pH were evaluated. Results showed that BDE-47 can be 100% degraded within 180 min under the condition of PDS:BDE-47 = 1000:1, 60 °C, and pH = 7. Quenching experiments combined with EPR analysis further proved the important role of SO 4 ·- in oxidating BDE-47. According to high-resolution mass spectrometry (HRMS) analysis, only one oxidation product of low toxicity was detected during the oxidation process. Theoretical calculations further revealed that the oxidation process mainly involved radical attack at C-Br bond, cleavage of C-Br bond, and fission of ether bond, and HSO 4 · may also play an important role in BDE-47 degradation in TAP system. In addition, TAP system exhibited universality as all selected PBDE congeners can be degraded, and the degradation rate of PBDEs was greatly affected by the number of substituted Br atoms in a negative trend. Overall, these findings indicate that TAP can be applied as an effective method for removal of PBDEs, and we provide a new insight for the practical application of TAP technology in BDE-47 degradation from experimental and theoretical aspects., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The application of sludge biochar (SC) materials as efficient catalysts for organic pollutants mineralization via advanced oxidation process meets the good strategy of "make waste profitable". The catalytic oxidations of methyl orange (MO) and pyrene by oxalic acid modified sludge biochar (SC-OA) with and without H 2 O 2 were carried out. The analysis of Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), electronic paramagnetic resonance spectrometer (EPR) and free radical quenching experiment were performed and the definite relationships between persistent free radicals (PFRs) type and specific reactive oxygen species (ROS) were made clear. It is suggested for the first time that carbon-centered type PFRs in SC-OA without H 2 O 2 could form O 2 • - and •OH from COOH groups, while oxygen-centered type PFRs induced H 2 O 2 to produce •OH. The degradation intermediates of MO and pyrene were identified and the transformation pathways were proposed. SC-OA, possessing good sustainable utilization and clean catalytic property, is expected to be popularized and applied in the mineralization of organic pollutants, especially in the in-situ remediation of contaminated soil where is no continuous supply of H 2 O 2 ., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

The presence of organic micro-pollutants (OMPs) in wastewater treatment effluents is becoming a major threat to the water safety for aquatic and human health. Photo-electrocatalytic based advanced oxidation process (AOP) is one of the emerging and effective techniques to degrade OMPs through oxidative mechanism. This study investigated the application of heterojunction based BiVO 4 /BiOI photoanode for acetaminophen (40 μg L -1 ) removal in demineralized water. Photoanodes were fabricated by electrodeposition of BiVO 4 and BiOI photocatalytic layers. Optical (UV-vis diffusive reflectance spectroscopy), structural (XRD, SEM, EDX) and opto-electronic (IPCE) characterization confirmed the successful formation of heterojunction for enhanced charge separation efficiency. The heterojunction photoanode showed incident photon to current conversion efficiency of 16% (λ max  = 390 nm) at an external voltage of 1 V under AM 1.5 standard illumination. The application of the BiVO 4 /BiOI photoanode in the removal of acetaminophen at 1 V (external bias) vs Ag/AgCl under simulated sunlight showed 87% removal efficiency within the first 120 min compared to 66% removal efficiency of the BiVO 4 photoanode. Similarly, combining BiVO 4 and BiOI exhibited 57% increase in first order removal rate coefficient compared to BiVO 4 . The photoanodes also showed moderate stability and reusability by showing 26% decrease in overall degradation efficiency after three cycles of each 5 h experiment. The results obtained in this study can be considered as a stepping stone towards the effective removal of acetaminophen as an OMP present in wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)

With development and urbanization, the amount of wastewater generated due to human activities drastically increases yearly, causing water pollution and intensifying the already worsened water crisis. Although convenient, conventional wastewater treatment methods such as activated sludge, stabilization ponds, and adsorption techniques cannot fully eradicate the complex and recalcitrant contaminants leading to toxic byproducts generation. Recent advancements in wastewater treatment techniques, specifically non-thermal plasma technology, have been extensively investigated for the degradation of complex pollutants in wastewater. Non-thermal plasma is an effective alternative for degrading and augmenting the biodegradability of recalcitrant pollutants due to its ability to generate reactive species in situ. This article critically reviews the non-thermal plasma technology, considering the plasma discharge configuration and reactor types. Furthermore, the influence of operational parameters on the efficiency of the plasma systems and the reactive species generated by the system during discharge has gained significant interest and hence been discussed. Also, the application of non-thermal plasma technology for the degradation of pharmaceuticals, pesticides, and dyes and the inactivation of microbial activities are outlined in this review article. Additionally, optimistic applications involving the combination of non-thermal plasma and catalysts and pilot and industrial-scale projects utilizing non-thermal plasma technology have been addressed. Concluding perceptions on the challenges and future perspectives of the non-thermal technology on wastewater treatment are accentuated. Overall, this review outlines a comprehensive understanding of the non-thermal plasma technology for recalcitrant pollutant degradation from a scientific perspective providing detailed instances for reference., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

A growing number of novel organic contaminants have escalated the demands and challenges for water treatment technology. Advanced oxidation processes based on ozone have the advantage of strong oxidative capacity and higher efficiency, which have promising application prospects in the treatment of refractory organic contaminants. Biochar has attracted a lot of interest in recent years in wastewater treatment owing to its porous structure, portable preparation and outstanding stability. Moreover, iron species are widely used in catalytic ozonation owing to their magnetic polarization, vast abundance and low price. Despite a plethora of research on Fe-based catalysts in ozonation process, the heterogeneous catalytic ozonation with Fe-loaded biochar lacks a comprehensive compendium. This review intends to introduce the research progress on Fe-based catalysts and Fe-loaded biochar in heterogeneous catalytic ozonation progress, summarize and further explore the mechanisms and detection techniques of various active components in catalytic ozonation, as well as providing fresh insights for future research., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The main scope of this study was to compare the efficacy of different advanced oxidation processes (AOPs) combined with adsorption for treating secondary treated effluent of municipal wastewater in a continuous-lab-scale reactor. The results revealed enhanced removal of biological oxygen demand (BOD: C 0 : 14.1 and C t : 0 mg L -1 (100%)), chemical oxygen demand (COD: C 0 : 40.5 and C t : 4 mg L -1 (≤90%)), and total organic carbon (TOC: C 0 : 15.2 and C t : 3.02-3.63 mg L -1 (∼80%)) by UV/PMS, O 3 /PMS, UV/O 3 /H 2 O 2 , and UV/O 3 /MnO 2 processes followed by glass packed bed reactor (GPBR). Complete inactivation of the bacterial count was observed for all the studied processes. The GPBR showed the additional advantage of termination in the regrowth of bacterial count on the filtering medium. The gas-chromatography and mass spectrometry (GC-MS) analysis showed that AOP followed by adsorption reduced the concentrations of the by-products in the treated effluent. Overall, the synergy between AOP and adsorption improved the effluent quality to meet various indirect potable reuse (IPR) applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Peroxymonosulfate (PMS) activation-based advanced oxidation technology possesses great potential for antibiotic-containing wastewater treatment. Herein, we developed an iron phosphide/carbon composite and verified its capability and superiority towards a model antibiotic pollutant (sulfathiazole, STZ) degradation through PMS activation. Benefiting from the chelating ability of phytic acid (PA) with metal ions and its abundance on phosphorous element, a PA-Fe 3+ complex was firstly formed and then served as sole precursor for iron phosphide formation by anoxic pyrolysis. Well crystalized FeP particle were found loading on the simultaneously formed thin layer carbon structure. Catalytic activity evaluation showed that FeP/carbon composite could remove over 99% of STZ (20 mg L -1 ) in 20 min adsorption and 30 min catalysis process under the reaction conditions of catalyst dosage 0.2 g L -1 , PMS loading 0.15 g L -1 . A pseudo-first-order reaction rate constant of 0.2193 min -1 was obtained, which was among the highest compared with reported studies. Further investigations indicated that the developed FeP/carbon composite worked well in a wide solution pH range of 3-9. Reaction mechanism study showed that reactive species of SO 4 - • and 1 O 2 generated from PMS activation played major roles for STZ degradation. Based on liquid chromatography-mass spectroscopy (LC-MS) analysis, a few STZ degradation intermediate products were identified, which facilitated the proposal of STZ degradation pathways. The possible ecological risk of STZ and related degradation intermediates were also considered by toxicity assessment using the Ecological Structure Activity Relationships (ECOSAR) Class Program. The obtained acute and chronic toxicity values implied the relatively low ecological risk of FeP/carbon-PMS reaction system for STZ treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

In this study, we demonstrated the application of electrochemical oxidation as a safer and cleaner technology for minimizing the impact of pharmaceuticals in wastewaters, simultaneously mediated by upcycled secondary waste materials (SWMs)-derived electrodes, to further reduce their environmental impact. The modularity, scalability, ease of operation and reliability make electrochemical oxidation an ideal process for the destruction of emerging persistent pollutants; however, their full-scale application is hindered by energy efficiency and the potential release of toxic by-products. Thus, the answer to these issues can be found in the design of tailored multifunctional electrode material. For the first time, SWMs derived from combustion and industrial processes have been employed with the simultaneous dual function of functional fillers, in a polyacrylonitrile fibrous matrix, and as a catalyst for the growth of carbon nanofeatures over the fiber surface, to increase the surface area and charge transfer. Next, the tailored composites were employed as anodes for the electrochemical oxidation of acetaminophen, both in phosphate buffer and in a real wastewater sample. The results suggest that SWMs can substitute costly engineered fillers in carbon-based electrodes and that the absence of reaction by-products (monitored by UHPLC-ESI-MS/MS), together with the low energy consumption, make the tailored fibrous composite electrodes good candidates for the development of safer and cleaner technologies with reduced environmental impact., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In the iron-based advanced oxidation processes (AOPs), direct use of Fe III can be more convenient than Fe II but the reduction of Fe III to Fe II is a rate-limiting step. Introducing co-catalysts with abundant reducing sites to Fe-based AOPs can be an efficient way to accelerate the Fe redox process. Herein, molybdenum disulfide (MoS 2 ) was used to enhance the catalytic performance of Fe 3+ /persulfate (PS) for phenol removal. In the Fe 3+ /MoS 2 /PS system, 99.6 ± 0.1% of phenol was removed in 60 min, comparable to that of the Fe 2+ /PS/MoS 2 system (99.1 ± 0.3%). With the help of MoS 2 , 99.3 ± 4.2% of Fe 3+ was transformed to Fe 2+ in 10 min, and the Fe 2+ /Fe ratio was able to be maintained at 70.0 ± 1.4% after 60 min. The rapid and complete reduction of Fe 3+ with MoS 2 made it possible to replace Fe 2+ by Fe 3+ , which is easier to store, transport, and use. The decrease in XPS peak area percentage of Mo(IV) and the lower valent S after reaction revealed that MoS 2 acted as an electron provider in the Fe redox cycle. Quenching experiment results indicated that the phenol removal was highly depended on the surface-bound radicals, including both SO 4 •- and • OH. Those results have demonstrated that ferric salts can be directly used in the Fe-based AOPs and the redox cycle could be sustained with the assistance of MoS 2 ., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Antibiotic contamination could cause serious risks of ecotoxicity and resistance gene induction. Advanced oxidation processes (AOPs) such as Fenton, photocatalysis, activated persulfate, electrochemistry and other AOPs technologies have been proven effective in the degradation of high-risk, refractory organic pollutants such as antibiotics. However, due to the limited mineralization ability, a large number of degradation intermediates will be produced in the oxidation process. The residual or undiscovered ecological risks of degradation products are potential safety hazards and problems necessitating comprehensive studies. In-depth investigations especially on the full assessments of ecotoxicity and resistance genes induction capability of antibiotic degradation products are important issues in reducing the environmental problems of antibiotics. Therefore, this review presents an overview of the current knowledge on the efficiency of different AOPs systems in reducing antibiotics toxicity and antibiotic resistance., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The presence of several contaminants in waterbodies raises global pollution and creates major risks to mankind, wildlife, as well as other living organisms. Development of an effective, feasible, cost-effective and eco-friendly approach for treating wastewater that is discharged from various industries is important for bringing down the deposition of contaminants into environment. Advanced oxidation process is an efficient technique for treating wastewater owing to its advantages such as high oxidation efficacy and does not produce any secondary pollutants. Advanced oxidation process can be performed through various methods such as ozone, Fenton, electrochemical, photolysis, sonolysis, etc. These methods have been widely utilized for degradation of emerging pollutants that cannot be destroyed using conventional approaches. This review focuses on wastewater treatment using advanced oxidation process. A brief discussion on mechanism involved is provided. In addition, various types of advanced oxidation process and their mechanism are explained in detail. Challenges faced during wastewater treatment process using oxidation, electrochemical, Fenton, photocatalysis and sonolysis are discussed elaborately. Advanced oxidation process can be viewed as potential approach for treating wastewater with certain modifications and solving challenges., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Considerable interest has been focusing on the activation of peroxydisulfate (PDS) by layered double hydroxide (LDH) for degradation of organic pollutants. However, understanding the structure and chemistry of LDH by which the activation of PDS could achieve a high degradation efficiency of organic compounds is an unsolved and fundamental question in advanced oxidation processes (AOPs), and one which, if harnessed, could enable the rational design of LDH with desired material properties. In this work, Mg/Al-LDH was synthesized with variable structures and compositions through doping different proportions of Mn 2+ . We advanced to understand this question of how LDH by these characteristics can affect the activation of PDS for degradation of organic pollutants. At a relatively low dosage of Mn (˂ 1%) in Mg/Al-LDH, the degradation rate of phenol by LDH activated PDS increased with the increase content of Mn, which was achieved by an increase of catalytic sites in Mg/Al-LDH interlayer. Rather, higher content of Mn (˃ 1%) significantly lowered the degradation performance of phenol as the decrease of interlayer space resulted in reduction of PDS intercalation in LDH and the formation of secondary Mn-related minerals (i.e., Mn 3 O 4 ) led to meaningless consumption of PDS. Finally, the degradation of phenol by LDH activated PDS followed a non-radical ( 1 O 2 ) mechanism. Our ability to quantify how the chemical and structural variability of LDH influence the activation of PDS for organic degradation could mark an important step toward synthesis strategies for advanced catalysts., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

In this study, a flow-through ozone-electrolysis (O 3 -electrolysis) process was developed by combining ozonation with an electrolysis using a porous reactive electrochemical membrane (REM) cathode. Due to the convection-enhanced mass transport and fast radial diffusion inside the small pores of REM cathodes, the rate of cathodic O 3 reduction to ozonide radicals (O 3 •- ) was significantly enhanced, while the further cathodic O 3 •- reduction to oxygen was inhibited during the flow-through O 3 -electrolysis process compared to the conventional mixed-tank O 3 -electrolysis process. Consequently, more hydroxyl radicals (•OH) were formed from O 3 •- decay in water during the flow-through O 3 -electrolysis process than the mixed-tank O 3 -electrolysis process. Corresponding to the higher •OH yields from cathodic O 3 reduction, the flow-through O 3 -electrolysis process substantially enhanced the abatement kinetics and efficiency of para-benzoic acid (pCBA, a model compound of ozone-resistant micropollutant) in a groundwater than conventional ozonation and the mixed-tank O 3 -electrolysis process. These results suggest that the flow-through O 3 -electrolysis process may provide a competitive treatment technology for micropollutant abatement in water treatment., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Ozone is formed at submicromolar concentrations from photolysis of many oxyanions and oxidants in water and contributes importantly to the degradation of emerging contaminants and inactivation of pathogenic microorganisms in the natural and engineered aquatic systems. In this study, we identified and discussed the critical limitations of the commonly-used protocols using cinnamic acid (CNA) as a probe compound to determine the submicromolar-level ozone and proposed a modified protocol that overcomes those limitations. Our experimental investigation demonstrated that the radicals (e.g., HO • ) formed from photolysis of oxyanions and oxidants, other than ozone, could also oxidize CNA and form benzaldehyde, resulting in the overestimation of ozone concentrations by using the commonly-used protocols. Moreover, the benzaldehyde formed from ozone-CNA reactions could be degraded by the radicals, leading to the underestimation of ozone concentrations by using the commonly-used protocols. A new protocol with high accuracy and precision was proposed and the rationales for each operational step of the new protocol were explained in detail and supported with justifications. The new protocol was compared with two commonly-used protocols in determining the concentration of ozone in the same water sample treated by the UV/chlorine process at three different UV wavelengths. The wavelength-dependent overestimation/underestimation of the ozone concentrations by using the two commonly-used protocols was well demonstrated and explained by the overlooked interferences of radicals in the protocols., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

This study investigated the degradation of methylene blue (MeB), methyl orange (MeO), and rhodamin B (RhB) by the UV/Persulfate (UV/PS) process. The dye degradation in the investigated UV-based Advanced Oxidation Processes (UV/AOPs) followed the first-order kinetic model. The second-order rate constant of the dyes with •OH, SO 4 •- , and CO 3 •- were calculated and found to be: k •OH,MeB  = 5.6 × 10 9  M -1  s -1 , [Formula: see text]  = 3.3 × 10 9  M -1  s -1 , [Formula: see text]  = 6.9 × 10 7  M -1  s -1 ; k •OH,MeO  = 3.2 × 10 9  M -1  s -1 , [Formula: see text]  = 13 × 10 9  M -1  s -1 , [Formula: see text]  = 4.4 × 10 6  M -1  s -1 ; k •OH,RhB  = 14.8 × 10 9  M -1  s -1 , [Formula: see text]  = 5 × 10 9  M -1  s -1 , [Formula: see text]  = 1 × 10 7  M -1  s -1 . The steady-state concentrations of •OH and SO 4 •- (including other reactive species) were determined using both chemical probes and modeling methods (Kintecus® V6.8). In the UV/PS, the dye degradation depends on the pH of the solution with the order: k dye (at pH of 7) > k dye (in acidic conditions) > k dye (in alkaline conditions). The presence of water matrices had different impacts on dye degradation: 1) The HCO 3 - and Cl - promoted the degradation efficiency of one dye, but also inhibited the degradation of other dyes; 2) Humic acid (HA) inhibited dye degradation as it scavenged both •OH and SO 4 •- . The degradation of the dyes by UV/PS was also compared with the UV/Chlorine (UV/HOCl) and UV/H 2 O 2 and it was established that: 1) In UV/PS and UV/HOCl, SO 4 •- and RCS contributed to dye degradation more than •OH, while •OH played a major role in dye degradation by UV/H 2 O 2 ; 2) The calculated toxicity in UV/PS was the lowest probably due to the low toxicity of by-products; 3) For MeO and RhB, the UV/PS process is more beneficial for the total organic carbon (TOC) removal compared to that of the UV/HOCl and UV/H 2 O 2 processes; 4) The UV/PS showed lower cost than the UV/HOCl and UV/H 2 O 2 systems for MeO, and RhB degradation but higher cost for MeB removal., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Graphitic carbon nitride (GCN), a polymeric metal free catalyst is widely used to degrade the toxic organic dye from the aqueous pollution. However, its catalytic efficiency and effective simultaneous reduction of mixed dye is still a challenge. Here, we have tuned the physiochemical properties of the GCN and melem derivatives by facilely tuning the degree of polycondensation and examined their catalytic activity towards the removal of cationic dye individually and together in solution. Catalysts were synthesized by thermal treatment of low-cost melamine and characterized by XRD, FTIR, RAMAN, FE-SEM, EDX, UV-DRS, and FL spectroscopy to confirm materials' structure, phase, morphology and optical properties. A suitable phase of the catalyst (M-450) exhibited superior removal capacity with a high-rate constant compared to others. The results demonstrate that M-450 has a maximum loading efficacy of 2.13 and 1.12 mg g -1 for methylene blue (MB) and Rhodamine B (RhB) dyes respectively in a single dye system. Attractively, when MB and RhB co-exist in the solution, the efficacy increased by 14% (2.44 mg g -1 ) and 27% (1.43 mg g -1 ) for MB and RhB respectively. The adsorption kinetics, stability, effect of pH and reusability of M-450 catalyst was testified. Further, radical scavenger experiments and terephthalic acid tests were carried out to explain the reaction mechanism involved in the degradation of textile dyes. Moreover, electron paramagnetic resonance (EPR) analysis validated the availability of hydroxyl radicals in the photocatalytic reaction. Excellent stability and reusability were attained even after five successive cycles, demonstrating a suitable photocatalyst for the efficient degradation of mixed dye., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

As an emerging class of organic contaminants, polyhalogenated carbazoles (PHCZs) have been increasingly detected all over the world since 1980s. Due to the environmental persistence, bioaccumulation, and dioxin-like toxicity, PHCZs have aroused widespread concerns in recent years. However, efficient approach for the degradation of PHCZs is quite limited so far. Therefore, in this study, an advanced oxidation process (AOP), sulfidated zero-valent iron/peroxymonosulfate (S-ZVI/PMS) system was used to degrade 3-chlorocarbazole (3-CCZ), which is one of the mostly detected PHCZs congeners. The degradation of 3-CCZ was systematically studied under different conditions by varying the molar ratio of S/Fe, the dosage of S-ZVI or PMS, pH and temperature. The results indicated that S-ZVI/PMS was an effective strategy for PHCZs treatment. The 20-min degradation efficiency of 3-CZZ was up to 96.6% with the pseudo-first-order rate constant of 0.168 min -1 under the conditions of 5 mg/L 3-CZZ, 0.3 g/L S-ZVI (S/Fe = 0.2), 1.0 mM PMS, pH 5.8 and 25 °C. HCO 3 - , Cl - and humic acid (HA) showed inhibitory effects to different degrees. Results of the electron paramagnetic resonance (EPR) and scavenging experiments clarified the dominant role of •OH, followed by 1 O 2 and SO 4 •─ . The product analysis and DFT calculation revealed three degradation pathways of 3-CCZ, namely hydroxylation, dechlorination and C-N bond cleavage, which largely alleviated the toxicity of the parent compound. This study showed the effectiveness of S-ZVI/PMS system in PHCZs treatment and provided a comprehensive investigation on the degradation behaviors of PHCZs in AOPs., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Advanced oxidation processes (AOPs) are widely used as efficient technologies to treat highly toxic and harmful substances in wastewater. Taking the most representative aromatic compounds (monosubstituted benzenes, substituted phenols and heterocyclic compounds) as examples, this paper firstly introduces their structures and the structural descriptors studied in AOPs before, and the influence of structural differences in AOPs with different reactive oxygen species (ROS) on the degradation rate was discussed in detail. The structure-activity relationship of pollutants has been previously analyzed through quantitative structure-activity relationship (QSAR) model, in which ROS is a very important influencing factor. When electrophilic oxidative species attacks pollutants, aromatic compounds with electron donating groups are more favorable for degradation than aromatic compounds with electron donating groups. While nucleophilic oxidative species comes to the opposite conclusion. The choice of advanced oxidation processes, the synergistic effect of various active oxygen species and the used catalysts will also change the degradation mechanism. This makes the structure-dependent activity relationship uncertain, and different conclusions are obtained under the influence of various experimental factors., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Odor problems are challenging issues in water treatment. Advanced oxidation has a significant degradation effect on these odors; however, some issues, such as oxidant residues and disinfection byproducts, exist in the use of advanced oxidation in actual water treatment. Because of the above issues, a combined advanced oxidation process has emerged-the UV/H 2 O 2 -biological activated carbon (BAC) process can play a strong oxidizing role in advanced oxidation and uses the physical adsorption and biological effects of activated carbon. However, there have been few studies on the odor degradation mechanism and characteristics of activated carbon biofilms in actual water treatment. This paper systematically studied the organic and odor substances removal effects and mechanism of a pilot combined UV/H 2 O 2 -BAC process. The results showed that UV/H 2 O 2 -BAC technology had a good removal effect on odor substances under long-term stable operation. The concentrations of geosmin (GSM) and 2-methylisoborneol (2-MIB) after systemic treatment were below 5 ng/L. The removal rates of DOC, UV 254 and H 2 O 2 by the combined process were 53.60%, 73.08% and 60.20%, respectively. The results of full-scan determination of GSM and 2-MIB degradation by gas chromatography-mass spectrometry (GC-MS) were consistent with those of front-track analysis. The diversity, richness and evenness of microorganisms in the lower activated carbon layer were higher than those in the middle and upper activated carbon layers. The greater the difference in the carbon layer height was, the greater the difference in the biological community structure., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Piezo-photocatalysis is a new concept of utilizing nanohybrids comprising piezoelectric and photocatalytic materials for enhancement in advanced oxidation process under the presence of light and mechanical energy. In this study, we explored the effectiveness of piezo-photocatalysis via examining their catalytic activity towards the degradation of azo dye (Rhodamine-B) and standard pollutant (Phenol) catalyzed by ferroelectric-semiconductor (BaTiO 3 -Ag 2 O) nanohybrids. Further, the enhancement in piezo-photocatalysis has been achieved via persulfate activation and the role of free radicals was examined by quenchers. A plausible mechanism for the improved piezo-photocatalysis of BaTiO 3 -Ag 2 O nanohybrid using persulfate activation has been discussed in detail. The removal mechanism of Rhodamine-B has been investigated using analytical techniques such as HPLC and EPR. Our experimental study demonstrated that the combination of piezo-photocatalysis with persulfate activation will provide higher reaction rate which will be beneficial towards the degradation of complex molecular pollutants derived from industrial sectors., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The degradation of organic contaminants is typically achieved by exposure of hydrogen peroxide (H 2 O 2 ) containing influent to ultraviolet (UV) lamps as the source of radiation that can convert H 2 O 2 to hydroxyl radicals (·OH), which oxidize organic pollutants. However, two factors prevent this process from being scaled down: the need to introduce H 2 O 2 , which requires special handling, and the use of bulky UV lamps, which have a high electric power consumption. In this work, an electrochemical cell was developed for the efficient in situ generation of H 2 O 2 from water and atmospheric oxygen in a process called a two-electron oxygen reduction reaction (2e-ORR), so that the external addition of H 2 O 2 is no longer needed. Moreover, the electrochemical cell was equipped with ultraviolet light-emitting diodes (UV-LEDs) to convert H 2 O 2 to ·OH. The reactor exhibited a current efficiency of ∼90% for the H 2 O 2 production at a flow rate of 50 mL min -1 . The degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) was studied at 277 nm based on different operational parameters, such as UV fluence rate, initial concentration, and initial pH. A high degradation of >70% was obtained at a UV output of 900 mW. Our approach, the first of its kind, has novel features applied, including: optimal radiation distribution in the reactor by applying a new UV source, UV-LEDs that offer much more control for the radiation profile in the reaction system compared to traditional UV lamps, controlled hydrodynamics by implementing special flow channels to provide a more uniform residence time and offer enhanced mixing, and integrating UV reactor and electrochemical cell in a single unit which could lead to superior performance and space efficiency of the device. These features make the device very suitable for point-of-use (POU) water treatment applications to eliminate both microbial and chemical contaminants., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Substrate concentration and relative humidity (RH) impact the photocatalytic efficiency of industrial aromatic hydrocarbons, but how they influence intermediate formation and degradation pathway remains unclear. With the help of oxygen isotope tracing method, the effects of these two environmental parameters on degradation mechanism of styrene were revealed at atomic level. Increasing styrene concentration favored product formation, which was however inhibited by RH elevation. Gaseous products were not directly formed in gaseous phase, but originated from desorption of interfacial intermediates. The volatile aldehydes and furans further exchanged their 16 O with 18 O in H 2 18 O. Increase of RH showed higher enhancement on 18 O distribution in all products and pathways than that of substrate concentration. Low RH preferred high generation of 16 O 2 •- and (16)1 O 2 , dominating reaction to form 1-phenyl-1,2-ethandiol, 2-hydroxy-1-phenyl-ethanon and phenylglyoxal monohydrate in sequence. Successive production of benzyl alcohol, benzaldehyde and benzoic acid through the reaction of styrene with promoted •18 OH by increasing RH became predominant. Hydration was firstly observed and confirmed as an important gaseous transformation step of aldehyde and furan products. Our findings provide a deep insight into photocatalytic degradation mechanism of aromatic hydrocarbons regulated by environmental parameters to further improve their industrial purification efficiency, and are helpful predicting environmental geochemistry fate of organics and preventing their negative impact on natural environment., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The textile industry is one of the most valuable industries, especially in developing countries, because it employs a large portion of the workforce. However, the development of the textile industry has led to increasing concern about environmental issues. Wastewater from the textile industry has a high COD and an undesirable color. Color is one of the problems with the wastewater due to its toxicity and low biodegradability. Color in textile wastewater mainly originates from the dyestuff used during the dyeing or printing process. Amongst all of available technology for color removal, advanced oxidation processes (AOPs) are considered one of the best and the most potential technology. However, the understanding of AOPs reaction mechanism to degrade dyestuff is still limited. In general, dyes degradation mechanism will vary and mainly depend on the chemical structure of the dyes itself. Some reaction pathway that seems less favorable thermodynamically can still happen during the process. Understanding the mechanism will be beneficial for future dyes improvement, especially on developing the moiety of the aromatic compound in order to produce easily degraded dyes while maintaining the fastness quality., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

In this study, the heterogeneous electro-Fenton method was used to remove Paclitaxel as an antineoplastic medicine. The cathode based on three-dimensional graphene (3DG) was applied as a gas diffusion electrode. The potential of five eco-friendly and recyclable iron minerals derived from nature (Magnetite, Siderite, Hematite, Limonite, and Pyrite) was investigated. Among the applied iron minerals, Pyrite showed the best, and Magnetite and Siderite showed good catalytic activity at pH 3.0. The current intensity of 300 mA, pH i 7.0, Paclitaxel concentration of 3 mg L -1 , amount of Pyrite 4.5 g L -1 , and time of 120 min was the optimum condition of the process with the removal efficiency of 99.13% in the presence of Pyrite. Repeating the experiments eight times revealed the reusability of the prepared 3DG as a cathode. Also, using radical scavengers indicated the principal role of the hydroxyl radicals (OH) in the treatment process. Analysis of total organic carbon reached 77.64% mineralization of 3 mg L -1 Paclitaxel at 360 min. Finally, ten by-products of small molecules were identified by gas chromatography-mass spectrometry device., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Chlorophenol is a widely used organic compound, and the environmental and health problems caused by it have being worsened in recent years. This study used 2,4,6-trichlorophenol (2,4,6-TCP) as the target pollutant, and employed ultrasound (US) enhanced zero-valent iron (Fe 0 )/EDTA/air system (FEA), namely US/FEA, to remove 2,4,6-TCP. The influence of single factor experimental conditions such as EDTA concentration, Fe 0 dosage, US power, pH and pollutant concentration on the removal efficiency of 2,4,6-TCP was investigated, and the optimal reaction conditions were determined. The mechanism of reactive oxygen species (ROS) produced by US/FEA was explored. The degradation process and removal mechanism of 2,4,6-TCP in the US/FEA were discussed through the determination and analysis of intermediate products. The results showed that US could continuously activate and renew the Fe 0 surface, accelerate its oxidation and corrosion process, and then continuously and stably produce sufficient amounts of Fe 2+ and Fe 3+ . Ultrasonic cavitation effect could reduce the difficulty of O 2 activation reaction, and promote the production of sufficient H 2 O 2 . The addition of EDTA made the system have a wide range of pH applications, and its performance under neutral and alkaline conditions was also superior. The ROS of US/FEA included ·OH, O 2 ·- and Fe(IV), where Fe(IV) was the main contributor to the removal of 2,4,6-TCP. In addition, the degradation of 2,4,6-TCP had two processes including dechlorination and benzene ring opening. First, 2,4,6-TCP was dechlorinated and degraded into phenol. And then, phenol was degraded into small molecular acids by ring-opening, and finally it was mineralized into CO 2 and H 2 O completely. US/FEA is a promising technology for high-efficiency degradation of organic matter and deep environmental purification., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Activating peroxides to produce active substances is the key to advanced oxidation processes (AOPs), but this usually requires energy or is accompanied by additional contaminants. In this study, diclofenac (DCF) was effectively removed by peracetic acid (PAA) in phosphate buffer (PBS). According to the results of radical scavenging experiments and electron paramagnetic resonance (EPR), hydroxyl radical (•OH) and organic radicals (i.e., CH 3 C(=O)OO• and CH 3 C(=O)O•) generated from PBS-activated PAA might be the dominant reactive species responsible for DCF degradation. At neutral pH, PBS/PAA system exhibited the best degradation efficiency on DCF. Presence of NO 3 - , SO 4 2- and Cl - had little effect on the removal of DCF, while HCO 3 - and natural organic matter (NOM) significantly inhibited DCF degradation in PBS/PAA system, resulting in the lower degradation efficiency of DCF in natural waters than that in ultrapure water. Finally, four possible degradation pathways, including hydroxylation, formylation, dehydrogenation and dechlorination, were proposed based on the detected reaction products. This study suggests that PBS used to control solution pH should be applied cautiously in PAA-based AOPs., (Copyright © 2021 Elsevier Ltd. All rights reserved.)