1. Assessment of nanoparticles release into the environment during drilling of carbon nanotubes/epoxy and carbon nanofibres/epoxy nanocomposites
- Author
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James Njuguna, Maria Blazquez, Ainhoa Egizabal, Jo Van Laer, Evelien Frijns, Cristina Elizextea, Kristof Starost, Nadimul Haque Faisal, and Inge Nelissen
- Subjects
Environmental Engineering ,Materials science ,Health, Toxicology and Mutagenesis ,Carbon nanotubes ,chemistry.chemical_element ,Nanotechnology ,02 engineering and technology ,Carbon nanotube ,010501 environmental sciences ,01 natural sciences ,law.invention ,Nanoparticle release ,Carbon nanofibers ,Scanning mobility particle sizer ,law ,Drilling emissions ,Environmental Chemistry ,Waste Management and Disposal ,0105 earth and related environmental sciences ,Nanocomposite ,Carbon nanofiber ,Epoxy ,021001 nanoscience & nanotechnology ,Pollution ,chemistry ,Chemical engineering ,visual_art ,visual_art.visual_art_medium ,Particle ,0210 nano-technology ,Particle counter ,Carbon - Abstract
The risk assessment, exposure and understanding of the release of embedded carbon nanotubes (CNTs) and carbon nanofibers (CNFs) from commercial high performance composites during machining processes are yet to be fully evaluated and quantified. In this study, CNTs and CNFs were dispersed in epoxy matrix through calendaring process to form nanocomposites. The automated drilling was carried out in a specially designed drilling chamber that allowed elimination of background noise from the measurements. Emission measurements were taken using condensed particle counter (CPC), scanning mobility particle sizer (SMPS) and DMS50 Fast Particulate Size Spectrometer. In comparison to the neat epoxy, the study results revealed that the nano-filled samples produced an increase of 102% and 227% for the EP/CNF and EP/CNT sample respectively in average particle number concentration emission. The particle mass concentration indicated that the EP/CNT and EP/CNF samples released demands a vital new perspective on CNTs and CNFs embedded within nanocomposite materials to be considered and evaluated for occupational exposure assessment. Importantly, the increased concentration observed at 10 nm aerosol particle sizes measurements strongly suggest that there are independent CNTs being released at this range. The work is funded by and part of the European Commission Life project named Simulation of the release of nanomaterials from consumer products for environmental exposure assessment (SIRENA, Pr. No. LIFE 11 ENV/ES/596). We are also thankful to the funding by QualityNano Project through Transnational Access (TA Application VITO-TAF-382 and VITO-TAF-500) under the European Commission, Grant Agreement No: INFRA-2010-262163 for the access and use of the facilities at the Flemish Institute for Technological Research (VITO). The authors would like to acknowledge K. Tirez and R. Persoons at Vito for their XRF and SEM support. Kristof Starost is also thankful for partial funding by the School of Engineering for his studentship.
- Published
- 2017