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The petrogenetic nature of A-type granites is a controversial problem. The Vinquis batholith in the Sierras Pampeanas of Argentina contains unusual F-rich and strongly peraluminous A-type monzogranites. A new LA-MC-ICP-MS U–Pb zircon crystallization age of 355 ± 7 Ma indicates emplacement in latest Devonian or earliest Carboniferous time, overlapping with extensive metaluminous A-type magmatism in the area. The monzogranites have a restricted range of SiO2 content (71.5–74.8 %), they are poor in Ca (0.54–1.4% CaO) and rich in FeOt, with relatively high FeOt/(FeOt+MgO) values ranging from 0.77 to 0.86 (average = 0.80) Both [FeOt/ (FeOt+MgO)] vs. SiO2 and [(Na2O+K2O)−CaO] vs. SiO2 plots indicate ferroan and alkali-calcic signatures typical of A-type granitoids. The samples have MgO/TiO2 > 1.2 and are moderately enriched in total alkalis (average 8.18%), with high K2O/Na2O values of 1.40–2.24. The granites are strongly peraluminous, with ASI (molar Al2O3/[CaO + Na2O + K2O]) values of 1.2 to 1.3. The high P2O5 content (0.23–0.37%) is distinctive and close to values reported for other Paleozoic F-rich peraluminous A-type granites in the Sierras Pampeanas. They have moderate contents of high field strength elements (e.g., Zr, Nb, Th, Y, etc.) and moderately fractionated to flat REE patterns [(La/Yb)N in the range 4.8–19.6] showing significant negative Eu anomalies (Eu/Eu* = 0.41). Biotite has a distinctive composition, with relatively high Fe2 +/(Fe2 + + Mg) ratios (0.61–0.74) and high F (0.55–1.42 wt.%) content. Together with the whole-rock chemistry this may be useful in identifying strongly peraluminous A-type granites. In addition, the Rb/Sr vs. Th + Zr + Ce diagram may be an appropriate discriminant between metaluminous and peralkaline A-type granites, strongly peraluminous A-type granites and strongly peraluminous orogenic granites. The geochemical evidence indicates that differentiation of the granitic rocks occurred by mineral fractionation from a F-rich peraluminous parental magma, dominant of plagioclase, K-feldspar, biotite, and accessory minerals such as zircon, monazite, xenotime, and oxides. The peraluminous composition and isotope data (εHf,355 and εNd,355 ranging from − 9.5 to − 1.5 and − 6.1 to − 7.8, respectively), together with abundant inherited Ordovician and Cambrian zircon, strongly suggest a dominantly metasedimentary source. The whole-rock and biotite compositions indicate that the Vinquis batholith crystallized under mainly oxidizing conditions, whereas Early Carboniferous metaluminous to weakly peraluminous A-type granites of the Sierras Pampeanas crystallized under dominantly reduced conditions. Fil: Morales Camera, Matías Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina Fil: Dahlquist, Juan Andrés. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina Fil: Stipp Basei, Miguel Angelo. Universidade de Sao Paulo; Brasil Fil: Galindo, Carmen. Universidad Complutense de Madrid; España Fil: Campos Neto, Mario da Costa. Universidade de Sao Paulo; Brasil Fil: Facetti, Julio Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro de Investigaciones y Transferencia de Jujuy. Universidad Nacional de Jujuy. Centro de Investigaciones y Transferencia de Jujuy; Argentina. Comision Nacional de Energia Atomica. Regional Noroeste; Argentina

Fil: Meira, Vinícius Tieppo. Instituto de Geociências, Universidade de São Paulo; Brasil. Fil: Campos Neto, Mario da Costa. Instituto de Geociências, Universidade de São Paulo; Brasil. Fil: González, Pablo Diego. CONICET - Centro de Investigaciones Geológicas, Universidad Nacional de La Plata; Argentina. Fil: Stipp Basei, Miguel Ângelo. Instituto de Geociências, Universidade de São Paulo; Brasil. Fil: Varela, Ricardo. CONICET - Centro de Investigaciones Geológicas, Universidad Nacional de La Plata; Argentina. The basement rock of the Pampean flat-slab (Sierras Pampeanas) in the Central Andes was uplifted and rotated in the Cenozoic era. The Western Sierras Pampeanas are characterised by meta-igneous rocks of Grenvillian Mesoproterozoic age and metasedimentary units metamorphosed in the Ordovician period. These rocks, known as the northern Cuyania composite terrane, were derived from Laurentia and accreted towardWestern Gondwana during the Early Paleozoic. The Sierra de Umango is the westernmost range of the Western Sierras Pampeanas. This range is bounded by the Devonian sedimentary rocks of the Precordillera on the western side and Tertiary rocks from the Sierra de Maz and Sierra del Espinal on the eastern side and contains igneous and sedimentary rocks outcroppings from the Famatina System on the far eastern side. The Sierra de Umango evolved during a period of polyphase tectonic activity, including an Ordovician collisional event, a Devonian compressional deformation, Late Paleozoic and Mesozoic extensional faulting and sedimentation (Paganzo and Ischigualasto basins) and compressional deformation of the Andean foreland during the Cenozoic. A Nappe System and an important shear zone, La PuntillaeLa Falda Shear Zone (PFSZ), characterise the Ordovician collisional event, which was related to the accretion of Cuyania Terrane to the proto-Andean margin of Gondwana. Three continuous deformational phases are recognised for this event: the D1 phase is distinguished by relics of S1 preserved as internal foliation within interkinematic staurolite porphyroblasts and likely represents the progressive metamorphic stage; the D2 phase exhibits P-T conditions close to the metamorphic peak that were recorded in an S2 transposition or a mylonitic foliation and determine the main structure of Umango; and the D3 phase is described as a set of tight to recumbent folds with S3 axial plane foliation, often related to thrust faults, indicating the retrogressive metamorphic stage. The Nappe System shows a top-to-the S/SW sense direction of movement, and the PFSZ served as a right lateral ramp in the exhumation process. This structural pattern is indicative of an oblique collision, with the Cuyania Terrane subducting under the proto-Andean margin of Gondwana in the NE direction. This continental subduction and exhumation lasted at least 30 million years, nearly the entire Ordovician period, and produced metamorphic conditions of upper amphibolite-to-granulite facies in medium- to high-pressure regimes. At least two later events deformed the earlier structures: D4 and D5 deformational phases. The D4 deformational phase corresponds to upright folding, with wavelengths of approximately 10 km and a general NeS orientation. These folds modified the S2 surface in an approximately cylindrical manner and are associated with exposed, discrete shear zones in the Silurian Guandacolinos Granite. The cylindrical pattern and subhorizontal axis of the D4 folds indicates that the S2 surface was originally flat-lying. The D4 folds are responsible for preserving the basement unit Juchi Orthogneiss synformal klippen. This deformation corresponds to the Chanica Tectonic during the interval between the Devonian and Carboniferous periods. The D5 deformational phase comprehends cuspate-lobate shaped open plunging folds with EeW high-angle axes (D5 folds) and sub-vertical spaced cleavage. The D5 folds and related spaced cleavage deformed the previous structures and could be associated with uplifting during the Andean Cycle