1. Selective electrochemical etching of epitaxial aluminum nitride thin film
- Author
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Rak-Jun Choi, Jihyun Kim, and Yongha Choi
- Subjects
Materials science ,General Physics and Astronomy ,macromolecular substances ,02 engineering and technology ,Nitride ,010402 general chemistry ,Epitaxy ,01 natural sciences ,stomatognathic system ,Etching (microfabrication) ,Thin film ,business.industry ,fungi ,technology, industry, and agriculture ,Hexagonal pyramid ,Surfaces and Interfaces ,General Chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Isotropic etching ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electrode ,Optoelectronics ,Dry etching ,0210 nano-technology ,business - Abstract
Aluminum nitride (AlN) has an ultra-wide bandgap energy of 6.2 eV and is resistant to chemical etching owing to its high chemical stability, making it intractable in the device fabrication process. We developed a facile method of electrochemical (EC) etching of a high-quality AlN epitaxial layer, where both spatial selectivity and a controllable etch rate were achieved. Underneath porous metal electrodes, the lateral etch rate increased with the increasing external anodic bias, from 400 nm/min at 5 V to 700 nm/min at 15 V. Nonporous metal electrodes protected the AlN from etching in hot H3PO4, enabling the spatial selectivity. The high EC etch rate is attributed to the enhanced hole-assisted oxidation at the interface between the AlN and the etchant. The etch pit formed by EC etching exhibited an inverse hexagonal pyramid structure with {1 0 –1 −1} face. As an alternative to dry etching, our method can be applied to the low-damage patterning of AlN with a controllable etch rate.
- Published
- 2020
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