1. Hierarchical ZnO/Si nanowire arrays as an effective substrate for surface-enhanced Raman scattering application
- Author
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Imran Khan, Shengli Huang, Shuping Li, Mengyao Gao, Bing He, Jiayuan Wang, Jinshen Lan, Xiaolan Yan, and Junyong Kang
- Subjects
Materials science ,Silicon ,Nanowire ,chemistry.chemical_element ,02 engineering and technology ,Substrate (electronics) ,010402 general chemistry ,01 natural sciences ,Crystal ,symbols.namesake ,Materials Chemistry ,Electrical and Electronic Engineering ,Thin film ,Surface plasmon resonance ,Instrumentation ,business.industry ,Metals and Alloys ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry ,symbols ,Optoelectronics ,0210 nano-technology ,business ,Raman spectroscopy ,Raman scattering - Abstract
Hierarchical arrays of ZnO/Si nanowires were prepared through very convenient two-step solution method on silicon substrates. The tree-like nanowire structures showed high crystal quality, where well aligned Si nanowires were grown vertical to the substrate surface, whereas uniform assembly of branched ZnO nanowires was grown normal to the Si nanowires (backbones). Raman analysis indicated that among all the specimens having identical chemical compositions and dimensions but different forms (thin films or nanowires), Ag-decorated hierarchical arrays of ZnO/Si nanowires possessed the highest intensity peak in surface enhanced Raman scattering spectra. Such arrays demonstrated exceptional ability of detecting Rhodamine 6 G, limiting to a value as low as 1×10โ8 mol/L and an enhancement factor up to 1.5 × 104. Both, experimental designing and band structure analysis indicated that electromagnetic effect of the localized surface plasmon resonance of Ag nanoparticles caused eight times enhancement, whereas chemical effect of hierarchical arrays of ZnO/Si nanowires played a more critical role in the high Raman sensitivity. Our results would be helpful to better understand the enhancement mechanisms and meanwhile, could be extended for further potential applications of hierarchical semiconducting nanowires.
- Published
- 2018